4,4'-bis(2-[1,10]-phenanthrolinyl)biphenyl | 176853-52-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 4,4'-bis(2-[1,10]-phenanthrolinyl)biphenyl
• 英文别名: 4,4'-di(1,10-phenanthrolin-2-yl)biphenyl；4,4'-Di(1,10-phenanthrolin-2-yl)-1,1'-biphenyl；2-[4-[4-(1,10-phenanthrolin-2-yl)phenyl]phenyl]-1,10-phenanthroline
• CAS: 176853-52-4
• 化学式: C₃₆H₂₂N₄
• 分子量: 510.597
• InChiKey: BBHFRDNLNCAAHR-UHFFFAOYSA-N

物化性质

• 沸点：
  812.1±60.0 °C(Predicted)
• 密度：
  1.293±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  40
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 cis-[bis(D8-2,2'-bipyridine)dichlororuthenium(II)] dihydrate 、 4,4'-bis(2-[1,10]-phenanthrolinyl)biphenyl 以 乙醇 、 水 为溶剂， 以41%的产率得到[Ru(2,2'-bipyridine-d8)2(4,4'-bis(2-[1,10]-phenanthrolinyl)biphenyl)Ru(2,2'-bipyridine-d8)2](PF6)4
  参考文献：
  名称：

  Wu, Feiyue, Inorganic Chemistry, 1999, vol. 38, # 24, p. 5620 - 5628

  摘要：

  DOI：
• 作为产物：
  描述：

  7-甲基-8-硝基喹啉 在 盐酸 、 氢氧化钾 、 sodium periodate 、 铁粉 作用下， 以 四氢呋喃 、 乙醇 、 水 、 溶剂黄146 、 N,N-二甲基甲酰胺 为溶剂， 反应 41.67h， 生成 4,4'-bis(2-[1,10]-phenanthrolinyl)biphenyl
  参考文献：
  名称：

  弗里德兰德方法学引入苯并[h]喹啉和1,10-菲咯啉亚基。

  摘要：

  已经开发了改进的8-氨基-7-喹啉甲醛的制备方法。通过先用二甲基甲酰胺二甲基乙缩醛，然后用高碘酸钠处理，可以将7-甲基-8-硝基喹啉的甲基氧化为醛。用铁还原得到氨基醛。类似的序列得到1-氨基-2-萘甲醛。喹啉衍生物与一系列乙酰基芳烃的弗里德兰德缩合反应提供了相应的2-芳基-1,10-菲咯啉。氨基醛与1,3-二乙酰基苯或2,6-二乙酰基吡啶的缩合可提供预期的Friedländer产品。对于氨基醛与1,4-二乙酰基苯，4,4'-二乙酰基联苯，1,5-二乙酰基蒽，1,2,3,4,5,6,7,8-八氢ac啶-1的反应描述了相似的化学方法8-dione和四环[6.3.0.0。（4,11）0（5，

  DOI：

  10.1021/jo952164h

文献信息

• Material for Light Emitting Device and Light Emitting Device
  申请人：Kitazawa Daisuke

  公开号：US20070267958A1

  公开（公告）日：2007-11-22

  The invention provides a light emitting device having a low driving voltage and excellent durability by a material for a light emitting device expressed by the general formula (1): where in each of R 1 , R 2 , R 3 , R 4 , R 5 and R 6 may be the same or different and is selected from hydrogen, an alkyl group, and an aryl group, A represents an n-valent aromatic hydrocarbon group, B represents an alkyl group or an aryl group, X represents carbon or nitrogen, n represents a natural number from 2 to 6, and n substituents having a phenanthroline skeleton or a benzoquinoline skeleton may be the same or different.

  本发明提供了一种具有低驱动电压和优异耐久性的发光装置，其使用的发光装置材料由通式（1）表示，其中R1、R2、R3、R4、R5和R6中的每一个可以相同也可以不同，并且被选择为氢、烷基或芳基，A代表n价芳香族碳氢化合物基团，B代表烷基或芳基，X代表碳或氮，n代表从2到6的自然数，n个具有菲咯啉骨架或苯并喹啉骨架的取代基可以相同也可以不同。
• LIGHT EMITTING ELEMENT
  申请人：Toray Industries, Inc.

  公开号：EP2595208A1

  公开（公告）日：2013-05-22

  Provided is an organic thin film light emitting element which has achieved all of improved luminous efficiency, improved driving voltage and improved durability life. Specifically provided is a light emitting element which comprises a hole transport layer and an electron transport layer between a positive electrode and a negative electrode and emits light by means of electrical energy. The light emitting element is characterized in that: the hole transport layer of the light emitting element contains a compound represented by general formula (1); the electron transport layer contains a donor compound; and the donor compound is an alkali metal, an inorganic salt containing an alkali metal, a complex of an alkali metal and an organic substance, an alkaline earth metal, an inorganic salt containing an alkaline earth metal, or a complex of an alkaline earth metal and an organic substance. (In the formula, R1-R20 each represents one group selected from the group consisting of hydrogen, deuterium, an alkyl group, a cycloalkyl group, an amino group, an aryl group, a heterocyclic group, a heteroaryl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, analkoxy group, an alkylthio group, an arylether group, an arylthioethergroup, a halogen, a cyano group, a -P(=O)R24R25 group and a silyl group;R24 and R25 each represents an aryl group or a heteroaryl group; and these substituents may be further substituted, or adjacent two substituents may combine together to form a ring. Meanwhile, R21-R23 may be the same or different and each represents one group selected from the group consisting of an alkyl group, a cycloalkyl group, an aryl group and a heteroaryl group; and these substituents maybe further substituted.)

  本发明提供了一种有机薄膜发光元件，它实现了发光效率的提高、驱动电压的提高和耐用寿命的提高。具体地说，本发明提供了一种发光元件，它包括位于正极和负极之间的空穴传输层和电子传输层，并通过电能发光。该发光元件的特征在于：发光元件的空穴传输层含有通式（1）表示的化合物；电子传输层含有供体化合物；供体化合物是碱金属、含碱金属的无机盐、碱金属和有机物的复合物、碱土金属、含碱土金属的无机盐或碱土金属和有机物的复合物。(式中，R1-R20 各代表一个选自氢、氘、烷基、环烷基、氨基、芳基、杂环基、杂芳基、烯基、环烯基、炔基、烷氧基、烷硫基、芳醚基、芳硫醚基、卤素、氰基、-P(=O)R24R25 基和硅烷基的基团；R24 和 R25 分别代表芳基或杂芳基；这些取代基可以进一步被取代，或者相邻的两个取代基可以结合在一起形成一个环。同时，R21-R23 可以相同或不同，各自代表一个选自烷基、环烷基、芳基和杂芳基的基团；这些取代基可能被进一步取代）。
• Non-crystallizable pi-conjugated molecular glass mixtures, charge transporting molecular glass mixtures, luminescent molecular glass mixtures, or combinations thereof for organic light emitting diodes and other organic electronics and photonics applications
  申请人：MOLECULAR GLASSES, INC.

  公开号：US10240084B2

  公开（公告）日：2019-03-26

  The present invention provides charge transporting molecular glass mixtures, luminescent molecular glass mixtures, or combinations thereof comprising at least two nonpolymeric compounds each independently corresponding to the structure (R1Y1)p[(Z1Y2)mR2Y3]nZ2Y4R3 wherein m is zero or one; n is zero up to an integer at which said compound starts to become a polymer; p is an integer of from one to eight; each R1 and R3 is independently a monovalent aliphatic or cycloaliphatic hydrocarbon group having 1 to 20 carbon atoms, an aromatic group or a multicyclic aromatic nucleus; R2, Z1, and Z2 each independently represent multivalent aliphatic or cycloaliphatic hydrocarbon groups having 1 to 20 carbon atoms or an aromatic group; and Y1, Y2, Y3 and Y4 each independently represent a triple bond, a double bond, or a single bond link.

  本发明提供电荷传输分子玻璃混合物、发光分子玻璃混合物或其组合，其包含至少两种各自独立对应于结构 (R1Y1)p[(Z1Y2)mR2Y3]nZ2Y4R3的非聚合物化合物 其中m为0或1；n为0直至所述化合物开始成为聚合物时的整数；p为1至8的整数；R1和R3各自独立地代表具有1至20个碳原子的一价脂肪族或环脂肪族烃基、芳香族基团或多环芳香族核；R2、Z1和Z2各自独立地代表具有1至20个碳原子的多价脂肪族或环脂肪族烃基或芳香族基团；以及Y1、Y2、Y3和Y4各自独立地代表三键、双键或单键连接。
• Organic electroluminescence element
  申请人：Ise Toshihiro

  公开号：US10428268B2

  公开（公告）日：2019-10-01

  A light emitting organic thin film including at least one compound represented by Formula (PQ-1) and at least one compound represented by Formula (BN-1). In Formula (PQ-1), each of Ra, Rb and Rc independently represents a hydrogen atom or an alkyl group, wherein any one of Ra, Rb and Rc represents a hydrogen atom and the remaining two represent an alkyl group. Each of R1 to R5 independently represents a hydrogen atom, an alkyl group, an aryl group, a fluorine atom or a cyano group. Each of Rx and Ry independently represents an alkyl group or a phenyl group. In Formula (BN-1), Ar1 represents an arylene group that may have a substituent Z. Ar2 represents a condensed hydrocarbyl group that may have a substituent Z. Each of R101 to R113 independently represents a phenyl group, or the like.

  一种发光有机薄膜，包括至少一种由式（PQ-1）代表的化合物和至少一种由式（BN-1）代表的化合物。 在式（PQ-1）中，Ra、Rb 和 Rc 各自独立地代表氢原子或烷基，其中 Ra、Rb 和 Rc 中的任意一个代表氢原子，其余两个代表烷基。R1 至 R5 各自独立地代表氢原子、烷基、芳基、氟原子或氰基。Rx 和 Ry 各自独立地代表一个烷基或一个苯基。在式（BN-1）中，Ar1 代表芳烯基，可带有取代基 Z；Ar2 代表缩合烃基，可带有取代基 Z；R101 至 R113 各自独立地代表苯基或类似基团。
• Light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US11088335B2

  公开（公告）日：2021-08-10

  Provided is a novel light-emitting element, a light-emitting element with a long lifetime, or a light-emitting element with high emission efficiency. The light-emitting element includes an EL layer between a pair of electrodes. The EL layer includes at least a light-emitting layer containing a fluorescent substance and a host material, a first electron-transport layer containing a first electron-transport material, and a second electron-transport layer containing a second electron-transport material, which are in contact with each other and in this order. The LUMO level of each of the host material and the second electron-transport material is higher than the LUMO level of the first electron-transport material.

  本文提供了一种新型发光元件、一种寿命长的发光元件或一种发射效率高的发光元件。该发光元件包括位于一对电极之间的 EL 层。EL 层至少包括一个包含荧光物质和宿主材料的发光层、一个包含第一电子传输材料的第一电子传输层和一个包含第二电子传输材料的第二电子传输层，它们依次相互接触。宿主材料和第二电子传输材料的LUMO电平均高于第一电子传输材料的LUMO电平。