[(N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine)Nd(NO3)3] | 1161750-60-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: [(N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine)Nd(NO3)3]
• CAS: 1161750-60-2
• 化学式: C₁₉H₂₂N₅NdO₁₃
• 分子量: 672.649
• InChiKey: QOLVINBUFZADLD-SGNWKFFVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine)Nd(NO3)3] 、 copper(II) acetate monohydrate 、 丙酮 以 甲醇 、 水 、 丙酮 为溶剂， 以85%的产率得到[(N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine-2H)Cu(Me2CO)Nd(NO3)3]
  参考文献：
  名称：

  N,N′-Bis(3-methoxysalicylidene)propane-1,2-diamine mononuclear 4f and heterodinuclear Cu-4f complexes: Synthesis, crystal structure and electrochemical properties

  摘要：

  Reactions of H2L [H2L = N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine] and Ln(NO3)(3) center dot 6H(2)O give rise to two different mononuclear 4f complexes, namely, {[(H2L)La(NO3)(3)(MeOH)] center dot H2O}(n) (1) and [(H2L)Nd(NO3)(3)] (2). Further additions of Cu(Ac)(2) center dot H2O to the mononuclear 4f complexes yield expected heterodinuclear Cu-4f complexes [LCu(Me2CO)Ln(NO3)(3)] (3, Ln = Nd; 4, Ln = Eu; 5, Ln = Dy). Complex 1 is a unique 1D polymeric chain structure, and 2 is one of the few structurally characterized discrete hexadentate salen-type mononuclear 4f complexes. Complexes 3-5 are similar to their analogues. However, they are prepared by a reversed synthetic route in contrast to their isomorphic complexes. Electrochemical behavior of heterodinuclear Cu-4f complexes 3-5 has been examined by cyclic voltammetry in acetonitrile. The redox potential of heterodinuclear Cu-4f complexes 3-5 shows significant anodic shift comparing to that of mononuclear copper complex (LCu). A tendency of anodic shift was observed in a sequence of 3 < 4 < 5. This results from the modulating effect of coordination geometry around Cu(II) ion on redox potential. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.08.016
• 作为产物：
  描述：

  neodymium(III) nitrate hexahydrate 、 N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine 以 甲醇 为溶剂， 以90%的产率得到[(N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine)Nd(NO3)3]
  参考文献：
  名称：

  N,N′-Bis(3-methoxysalicylidene)propane-1,2-diamine mononuclear 4f and heterodinuclear Cu-4f complexes: Synthesis, crystal structure and electrochemical properties

  摘要：

  Reactions of H2L [H2L = N,N'-bis(3-methoxysalicylidene)propane-1,2-diamine] and Ln(NO3)(3) center dot 6H(2)O give rise to two different mononuclear 4f complexes, namely, {[(H2L)La(NO3)(3)(MeOH)] center dot H2O}(n) (1) and [(H2L)Nd(NO3)(3)] (2). Further additions of Cu(Ac)(2) center dot H2O to the mononuclear 4f complexes yield expected heterodinuclear Cu-4f complexes [LCu(Me2CO)Ln(NO3)(3)] (3, Ln = Nd; 4, Ln = Eu; 5, Ln = Dy). Complex 1 is a unique 1D polymeric chain structure, and 2 is one of the few structurally characterized discrete hexadentate salen-type mononuclear 4f complexes. Complexes 3-5 are similar to their analogues. However, they are prepared by a reversed synthetic route in contrast to their isomorphic complexes. Electrochemical behavior of heterodinuclear Cu-4f complexes 3-5 has been examined by cyclic voltammetry in acetonitrile. The redox potential of heterodinuclear Cu-4f complexes 3-5 shows significant anodic shift comparing to that of mononuclear copper complex (LCu). A tendency of anodic shift was observed in a sequence of 3 < 4 < 5. This results from the modulating effect of coordination geometry around Cu(II) ion on redox potential. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.08.016