(5,7,7,12,14,14-hexamethyl-1,4,8,11-tetra-azacyclotetradecane)nickel(2+) | 102629-51-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (5,7,7,12,14,14-hexamethyl-1,4,8,11-tetra-azacyclotetradecane)nickel(2+)
• 英文别名: [Ni(II)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)]²⁺；[Ni(II)(hmc)]²⁺
• CAS: 102629-51-6；102629-53-8；116500-89-1；116500-90-4；142394-58-9；18444-42-3；47105-35-1；51371-72-3；51371-74-5；51372-00-0；52553-44-3；53176-63-9；57456-80-1；630403-73-5；80531-85-7；80531-87-9；80531-89-1；80531-91-5；80531-93-7；80531-95-9
• 化学式: C₁₆H₃₆N₄Ni
• 分子量: 343.179
• InChiKey: VMWNWMCIAHUHLC-KAECKJJSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氰离子 、 (5,7,7,12,14,14-hexamethyl-1,4,8,11-tetra-azacyclotetradecane)nickel(2+) 在 氢氰酸 、 hydroxide 作用下， 以 水 为溶剂， 生成 tetracyanonickelate(2-)
  参考文献：
  名称：

  Ferranti, Francesco, Gazzetta Chimica Italiana, 1985, vol. 115, # 7, p. 369 - 374

  摘要：

  DOI：
• 作为产物：
  描述：

  (5,7,7,12,14,14-hexamethyl-1,4,8,11-tetra-azacyclotetradecane)nickel(3+) 在 双氧水 作用下， 以 水 为溶剂， 生成 (5,7,7,12,14,14-hexamethyl-1,4,8,11-tetra-azacyclotetradecane)nickel(2+)
  参考文献：
  名称：

  Radical oxidation of nickel(II) complexes of tetra-azamacrocyclic ligands and the reactions of the resulting nickel(III) complexes: a pulse-radiolysis and flash-photolysis study

  摘要：

  DOI：

  10.1039/dt9790000139
• 作为试剂：
  描述：

  溴代叔丁烷 、 丙烯腈 在 (5,7,7,12,14,14-hexamethyl-1,4,8,11-tetra-azacyclotetradecane)nickel(2+) 作用下， 生成 4,4-dimethylvaleronitrile
  参考文献：
  名称：

  The chemistry of electrogenerated transition metals species - the insertion of olefins into a nickelcarbon bond

  摘要：

  DOI：

  10.1016/s0022-328x(00)80916-x

文献信息

• McAuley, A.; Oswald, T.; Haines, R. I., Canadian Journal of Chemistry, 1983, vol. 61, p. 1120 - 1125
  作者：McAuley, A.、Oswald, T.、Haines, R. I.

  DOI：——

  日期：——
• Rates of incorporation of nickel(II) into linear and macrocyclic tetra-amines in acetonitrile solvent, and comments on the macrocyclic effect
  作者：Robert W. Hay、Paul R. Norman

  DOI：10.1016/s0020-1693(00)80125-5

  日期：1980.1
• Ngai, Raymond; Wang, Yueh-Hwa L.; Reed, James L., Inorganic Chemistry, 1985, vol. 24, # 23, p. 3802 - 3807
  作者：Ngai, Raymond、Wang, Yueh-Hwa L.、Reed, James L.

  DOI：——

  日期：——
• Synthesis, structural characterization and magnetic behaviour of two new (μ1,3-N3)2 dinuclear nickel compounds: study of the magnetic transition at 235 K for the cis-(μ1,3-N3)2[Ni(dl-cth)]2(ClO4)2 compound
  作者：Albert Escuer、Ramon Vicente、M. Salah El Fallah、Xavier Solans、Mercé Font-Bardia

  DOI：10.1016/s0020-1693(97)06172-0

  日期：1998.8

  The dinuclear compounds cis-(mu(1,3)-N-3)(2)[Ni(dl-cth)](2)(ClO4)(2) (1a) and cis-(mu(1,3)-N-3)(2)[Ni(dl-cth)](2)(PF6)(2) . (CH3)(2)NCHO (2), in which dl-cth is the dl isomer of 5,5,7,12,12,14-hexamethyltetraazacyclotetradecane, were synthesized by reaction of the [Ni(dl-cth)](2+) cation with azido ligand in aqueous medium. Compound 1a crystallizes in the orthorhombic system, group Pbca, a = 14.784(2), b = 15.371(2), c = 19.954(3) Angstrom, V = 4534.4(1) Angstrom(3), Z = 4, R = 0.039 and shows a magnetic and structural transition centred at 235 K, giving an amorphous compound 1b. Complex 2 crystallizes in the monoclinic system, group P21/c, a = 12.215(4), b = 9.675(2), c = 24.221(4) Angstrom, beta = 99.46(2)degrees, V = 2823.5(1) Angstrom(3), Z = 4, R = 0.054, Magnetic measurements show very strong antiferromagnetic coupling for 1a (J = -113 cm(-1)) and moderate coupling for 1b and 2 (J = -64.5 and -75.1 cm(-1)). The magnetic data are discussed on the basis of the structural parameters, which suggest a distortion from a planar, eight-membered Ni-2(mu(1,3)-N-3)(2) ring for 1a to a chair conformation for 1b. (C) 1998 Elsevier Science S.A. All rights reserved.
• Röper, Jürgen R.; Elias, Horst, Inorganic Chemistry, <hi>1992</hi>, vol. 31, # 7, p. 1210 - 1214
  作者：Röper, Jürgen R.、Elias, Horst

  DOI：——

  日期：——