methyl 2,6,10-trimethyltridecanoate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: methyl 2,6,10-trimethyltridecanoate
• 化学式: C₁₇H₃₄O₂
• 分子量: 270.456
• InChiKey: AJQKJNYTUWSMBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  19
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-甲基-1-戊醇 在 platinum(IV) oxide chromium(VI) oxide 、 叔丁基过氧化氢 、 sodium tetrahydroborate 、 selenium(IV) oxide 、 溴 、 magnesium 、 三苯基膦 、 水杨酸 作用下， 以 四氢呋喃 、 甲醇 、 乙醚 、 正己烷 、 二氯甲烷 、 丙酮 为溶剂， -5.0~20.0 ℃ 、172.37 kPa 条件下， 反应 38.25h， 生成 methyl 2,6,10-trimethyltridecanoate
  参考文献：
  名称：

  摘要：

  Methyl 2,6,10-trimethyltridecanoate (1) and methyl 2,6,10-trimethyldodecanoate (2) have been identified as male-produced sex pheromones of the Brazilian soybean stink bugs Euschistus heros (F.) and Piezodorus guildinii (Westwood). In order to establish a defined attractive blend for both species, compounds 1 and 2 were synthesized as mixtures of stereoisomers to be employed in behavior bioassays. (+/-)-Citronellol (3) was utilized as starting material. and the syntheses was carried out in six steps with good overall yield. When tested alone, synthetic compounds 1 and 2 proved to be active in a two-choice olfactometer: however, a 20:1 mixture of 1 and 2 was much more attractive to E. heros females. A similar blend had been found among the headspace volatiles of males.

  DOI：

  10.1023/a:1026433608967

文献信息

• Mori, Kenji; Murata, Noriaki, Liebigs Annalen der Chemie, 1994, # 6, p. 637 - 640
  作者：Mori, Kenji、Murata, Noriaki

  DOI：——

  日期：——
• METHOD FOR MANAGING RESISTANCE TO INSECTICIDAL TRAITS AND CHEMICALS USING PHEROMONES
  申请人：Provivi, Inc.

  公开号：US20190082685A1

  公开（公告）日：2019-03-21

  Systems and methods for managing resistance to insecticidal traits and chemicals are provided. In one aspect, systems and methods are provided that: 1) delay the development of resistance to transgenic insecticidal crops and/or chemical insecticides (preemptive strategies), and 2) rescue one or more pests' susceptibility to transgenic insecticidal crops and/or chemical insecticides once pest resistance has developed (responsive strategies).
• IMPROVED INSECT CONTROL STRATEGIES UTILIZING PHEROMONES AND RNAI
  申请人：Provivi, Inc.

  公开号：US20190343122A1

  公开（公告）日：2019-11-14

  Systems and methods of preventing or reducing crop damage from pests are provided. In one embodiment, the method comprises: a) applying a mating disruption tactic to a field plot; and b) disrupting expression of one or more target genes in one or more pests, wherein crop damage is reduced in the field plot. In another embodiment, the method comprises applying an attract-and-kill tactic to a field plot, wherein said attract-and-kill tactic comprises: a) applying one or more semiochemicals or factors; and b) disrupting expression of one or more target genes in one or more pests, wherein said disruption is capable of killing the one or more pests, wherein crop damage is reduced in the field plot.
• INSECT CONTROL STRATEGIES UTILITIZING PHEROMONES AND RNAI
  申请人：Provivi, Inc.

  公开号：US20220151237A1

  公开（公告）日：2022-05-19

  Systems and methods of preventing or reducing crop damage from pests are provided. In one embodiment, the method comprises: a) applying a mating disruption tactic to a field plot; and b) disrupting expression of one or more target genes in one or more pests, wherein crop damage is reduced in the field plot. In another embodiment, the method comprises applying an attract-and-kill tactic to a field plot, wherein said attract-and-kill tactic comprises: a) applying one or more semiochemicals or factors; and b) disrupting expression of one or more target genes in one or more pests, wherein said disruption is capable of killing the one or more pests, wherein crop damage is reduced in the field plot.
• [EN] METHOD FOR MANAGING RESISTANCE TO INSECTICIDAL TRAITS AND CHEMICALS USING PHEROMONES<br/>[FR] PROCÉDÉ DE GESTION DE LA RÉSISTANCE AUX GÈNES DE RÉSISTANCE AUX INSECTES ET AUX PRODUITS CHIMIQUES INSECTICIDES UTILISANT DES PHÉROMONES
  申请人：PROVIVI INC

  公开号：WO2017112887A1

  公开（公告）日：2017-06-29

  Systems and methods for managing resistance to insecticidal traits and chemicals are provided. In one aspect, systems and methods are provided that: 1) delay the development of resistance to transgenic insecticidal crops and/or chemical insecticides (preemptive strategies), and 2) rescue one or more pests' susceptibility to transgenic insecticidal crops and/or chemical insecticides once pest resistance has developed (responsive strategies).