1-Thianonane, 1,1,1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-heptadecafluoro-9-iodo- | 334543-98-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 英文名称: 1-Thianonane, 1,1,1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-heptadecafluoro-9-iodo-
• 英文别名: (1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-8-iodooctyl)-pentafluoro-λ6-sulfane
• CAS: 334543-98-5
• 化学式: C₈H₄F₁₇IS
• 分子量: 582.063
• InChiKey: FFZASJFPJXVMPT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  1-Thianonane, 1,1,1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-heptadecafluoro-9-iodo- 在 lithium aluminium tetrahydride 、 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 1.08h， 生成 3,3,4,4,5,5,6,6,7,7,8,8-Dodecafluoro-8-(pentafluorothio)-1-mercaptooctane
  参考文献：
  名称：

  New SF5-long chain carbon systems

  摘要：

  A new SF5-terminated perfluoroalkyl thiol - SF5(CF2)(6)CH2CH2SH - and a symmetric SF5-terminated dialkyl disulfide - [SF5CHCH(CH2)(8)S](2) - were synthesized from the corresponding SF5-terminated precursors. The chemistry employed in the preparation of the disulfide encompasses high yield pathways for the preparation of new SF5-long chain derivatives. (C) 2001 Elsevier science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(00)00340-7
• 作为产物：
  描述：

  乙烯 、 (6-iodododecafluorohexyl)pentafluorosulfur(VI) 在 二叔丁基过氧化物 作用下， 反应 22.0h， 以28%的产率得到1-Thianonane, 1,1,1,1,1,2,2,3,3,4,4,5,5,6,6,7,7-heptadecafluoro-9-iodo-
  参考文献：
  名称：

  Perfluorinated polymer surfaces comprising SF5-terminated long-chain perfluoroacrylate

  摘要：

  A new perfluorinated acrylate monomer containing the SF5(CF2)(6)-perfluorinated side chain was synthesized and polymerized into films. Bulk monomer characterization is consistent with the molecular structure based on FTIR, mass spectrometry and NMR analyses, The surface properties of polymer coatings were studied with aqueous wetting (contact angle) and X-ray photoelectron spectroscopy (XPS) methods. The surface composition is shown to be highly enriched in the terminal side chain SF5-chemistry and exhibits properties consistent with a highly apolar, non-wetting perfluorinated polymer surface. Depth-dependent XPS studies using angular-re solved methods (ADXPS) confirmed a non-stoichiometric enrichment of sulfur and fluorine at the film ambient interface, consistent with a surface presence of the terminal SF5-group and possibly film structural anisotropy in the surface zone. Time-of-flight (TOF) secondary ion mass spectrometry (SIMS) analysis supplements the XPS data by showing the presence of all expected SF5-acrylate chemistry components in the outer 15 A of the film surface. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(02)00008-8

文献信息

• New SF5-long chain carbon systems
  作者：R Winter、P.G Nixon、G.L Gard、D.H Radford、N.R Holcomb、D.W Grainger

  DOI：10.1016/s0022-1139(00)00340-7

  日期：2001.1

  A new SF5-terminated perfluoroalkyl thiol - SF5(CF2)(6)CH2CH2SH - and a symmetric SF5-terminated dialkyl disulfide - [SF5CHCH(CH2)(8)S](2) - were synthesized from the corresponding SF5-terminated precursors. The chemistry employed in the preparation of the disulfide encompasses high yield pathways for the preparation of new SF5-long chain derivatives. (C) 2001 Elsevier science B.V. All rights reserved.
• Perfluorinated polymer surfaces comprising SF5-terminated long-chain perfluoroacrylate
  作者：R. Winter、P.G. Nixon、R.J. Terjeson、J. Mohtasham、N.R. Holcomb、D.W. Grainger、D. Graham、D.G. Castner、G.L. Gard

  DOI：10.1016/s0022-1139(02)00008-8

  日期：2002.6

  A new perfluorinated acrylate monomer containing the SF5(CF2)(6)-perfluorinated side chain was synthesized and polymerized into films. Bulk monomer characterization is consistent with the molecular structure based on FTIR, mass spectrometry and NMR analyses, The surface properties of polymer coatings were studied with aqueous wetting (contact angle) and X-ray photoelectron spectroscopy (XPS) methods. The surface composition is shown to be highly enriched in the terminal side chain SF5-chemistry and exhibits properties consistent with a highly apolar, non-wetting perfluorinated polymer surface. Depth-dependent XPS studies using angular-re solved methods (ADXPS) confirmed a non-stoichiometric enrichment of sulfur and fluorine at the film ambient interface, consistent with a surface presence of the terminal SF5-group and possibly film structural anisotropy in the surface zone. Time-of-flight (TOF) secondary ion mass spectrometry (SIMS) analysis supplements the XPS data by showing the presence of all expected SF5-acrylate chemistry components in the outer 15 A of the film surface. (C) 2002 Elsevier Science B.V. All rights reserved.