2,2,3,3-Tetramethylcyclopent-4-en-1-on | 22748-18-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,2,3,3-Tetramethylcyclopent-4-en-1-on
• 英文别名: 4,4,5,5-Tetramethylcyclopentenon；4,4,5,5-Tetramethyl-cyclopenten-(2)-on；Tetramethyl cyclopentenone；4,4,5,5-tetramethylcyclopent-2-en-1-one
• CAS: 22748-18-1
• 化学式: C₉H₁₄O
• 分子量: 138.21
• InChiKey: FOMWRSGYNRQRAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,2,3,4-四氢喹啉 、 正丁基锂 、 二氧化碳 、 叔丁基锂 、 、 2,2,3,3-Tetramethylcyclopent-4-en-1-on 在 氮 作用下， 以 四氢呋喃 、 正戊烷 为溶剂， 反应 6.5h， 以to obtain a white crystalline powder (41%)的产率得到5-(Tetramethyl-1,3-cyclopentadienyl)-1,2,3,4-tetrahydroquinoline
  参考文献：
  名称：

  Transition metal complex, catalyst composition including the same and olefin polymer using catalyst composition

  摘要：

  提供一种新型的过渡金属配合物，其中单环戊二烯基配体引入了氨基基团进行配位，还提供了包括该配合物的催化剂组合物以及使用该催化剂组合物的烯烃聚合物。该过渡金属配合物具有五边形环结构，其中通过苯基桥连接的氨基基团在金属位点附近形成了稳定的键，因此，具有立体位阻的单体可以轻松接近过渡金属配合物。通过使用包括该过渡金属配合物的催化剂组合物，可以在具有大立体位阻的单体聚合中生产具有高分子量的线性低密度聚烯烃共聚物和密度为0.910 g/cc或更低的超低密度聚烯烃共聚物。此外，对于具有大立体位阻的烯烃单体的反应性能也非常优异。

  公开号：

  US08039671B2

文献信息

• Transition Metal Complex, Catalyst Composition Including the Same and Olefin Polymer Using Catalyst Composition
  申请人：Lee Choong Hoon

  公开号：US20070225158A1

  公开（公告）日：2007-09-27

  Provided are a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a catalyst composition including the same, and an olefin polymer using the catalyst composition. The transition metal complex has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, a sterically hindered monomer can easily approach the transition metal complex. By using a catalyst composition including the transition metal complex, a linear low density polyolefin copolymer having a high molecular weight and a very low density polyolefin copolymer having a density of 0.910 g/cc or less can be produced in a polymerization of monomers having large steric hindrance. Further, the reactivity for the olefin monomer having large steric hindrance is excellent.

  提供了一种新型的过渡金属配合物，其中包括一个引入了氨基基团的单环戊二烯基配体，以及使用该催化剂组合物制备的烯烃聚合物。该过渡金属配合物具有一个五边形环结构，其中一个氨基基团通过苯基桥连接，在金属位点附近形成了稳定的键，因此，具有空间位阻的单体可以很容易地接近该过渡金属配合物。通过使用包含该过渡金属配合物的催化剂组合物，可以在大空间位阻单体的聚合中制备具有高分子量的线性低密度聚烯烃共聚物和密度为0.910 g/cc或更低的超低密度聚烯烃共聚物。此外，对于具有大空间位阻的烯烃单体的反应性能也非常优异。
• TRANSITION METAL COMPLEX, CATALYST COMPOSITION INCLUDING THE SAME AND OLEFIN POLYMER USING CATALYST COMPOSITION
  申请人：LEE Choong Hoon

  公开号：US20110152529A1

  公开（公告）日：2011-06-23

  Provided are a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a catalyst composition including the same, and an olefin polymer using the catalyst composition. The transition metal complex has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, a sterically hindered monomer can easily approach the transition metal complex. By using a catalyst composition including the transition metal complex, a linear low density polyolefin copolymer having a high molecular weight and a very low density polyolefin copolymer having a density of 0.910 g/cc or less can be produced in a polymerization of monomers having large steric hindrance. Further, the reactivity for the olefin monomer having large steric hindrance is excellent.

  提供了一种新型的过渡金属配合物，其中包括引入了氨基基团的单环戊二烯基配体，以及包含该配合物的催化剂组合物和使用该催化剂组合物的烯烃聚合物。该过渡金属配合物具有五边形环结构，其中通过苯基桥连接的氨基基团在金属位点附近形成稳定的键，因此，具有立体位阻的单体可以轻易地接近该过渡金属配合物。通过使用包含该过渡金属配合物的催化剂组合物，可以在具有大立体位阻的单体聚合中生产高分子量的线性低密度聚烯烃共聚物和密度小于0.910 g/cc的超低密度聚烯烃共聚物。此外，对于具有大立体位阻的烯烃单体的反应性能也非常优秀。
• OLEFIN BLOCK COPOLYMER
  申请人：Lee Yong-Ho

  公开号：US20130296519A1

  公开（公告）日：2013-11-07

  The present description relates to an olefin block copolymer with enhanced processability as well as excellences in elasticity and heat resistance, and a preparation method for the same. The olefin block copolymer includes first and second segments, each containing an ethylene or propylene repeating unit and an α-olefin repeating unit at different mole fractions, where the second segment is dispersed in the form of a closed curve as a dispersed phase on the first segment according to a TEM (Transmission Electron Microscope) image.

  本说明涉及一种具有增强加工性、优异弹性和耐热性的烯烃嵌段共聚物，以及其制备方法。该烯烃嵌段共聚物包括第一和第二段，每个段都含有乙烯或丙烯重复单元和α-烯烃重复单元，不同摩尔分数，其中第二段以TEM（透射电子显微镜）图像为基础，以封闭曲线的形式作为分散相分散在第一段上。
• Olefin block copolymer
  申请人：Lee Yong-Ho

  公开号：US09056939B2

  公开（公告）日：2015-06-16

  The present description relates to an olefin block copolymer with enhanced processability as well as excellences in elasticity and heat resistance, and a preparation method for the same. The olefin block copolymer includes first and second segments, each containing an ethylene or propylene repeating unit and an α-olefin repeating unit at different mole fractions, where the second segment is dispersed in the form of a closed curve as a dispersed phase on the first segment according to a TEM (Transmission Electron Microscope) image.

  本说明涉及一种具有增强可加工性以及优异的弹性和耐热性的烯烃嵌段共聚物以及其制备方法。该烯烃嵌段共聚物包括第一和第二嵌段，每个嵌段包含不同摩尔分数的乙烯或丙烯重复单元和α-烯烃重复单元，其中第二嵌段按TEM（透射电子显微镜）图像以闭合曲线形式分散在第一嵌段上。