6-methylene-p-mentha-2,8-diene | 670220-33-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 6-methylene-p-mentha-2,8-diene
• 英文别名: 3-Methyl-4-methylidene-6-(prop-1-en-2-yl)cyclohex-1-ene；3-methyl-4-methylidene-6-prop-1-en-2-ylcyclohexene
• CAS: 670220-33-4
• 化学式: C₁₁H₁₆
• 分子量: 148.248
• InChiKey: ADALHAXVDKJJGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  6-allyloxymethyl-2,8-p-menthadiene 在 氢氧化钾 、 二甲基亚砜 作用下， 反应 12.0h， 生成 1-isopropenyl-4-methyl-3-methylene-4-cyclohexene 、 6-methylene-p-mentha-2,8-diene
  参考文献：
  名称：

  摘要：

  Conversions of alkyl allyl and terpenoid allyl ethers in a superbasic medium (dimethyl sulfoxide-potassium hydroxide) are studied. The ethers with an unbranched alkyl substituent isomerize into propenyl ethers, the ethers with a branched unsaturated substituent decompose to give a hydrocarbon, and diallyl ethers isomerize into allyl vinyl ethers whose Claisen rearrangement gives rise to aldehydes.

  DOI：

  10.1023/a:1026309019727

文献信息

• ——
  作者：O. G. Vyglazov、V. A. Chuiko、L. V. Izotova

  DOI：10.1023/a:1026309019727

  日期：——

  Conversions of alkyl allyl and terpenoid allyl ethers in a superbasic medium (dimethyl sulfoxide-potassium hydroxide) are studied. The ethers with an unbranched alkyl substituent isomerize into propenyl ethers, the ethers with a branched unsaturated substituent decompose to give a hydrocarbon, and diallyl ethers isomerize into allyl vinyl ethers whose Claisen rearrangement gives rise to aldehydes.