(+)-3'-azido-abscisic acid methyl ester | 371762-50-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (+)-3'-azido-abscisic acid methyl ester
• 英文别名: methyl (2Z,4E)-5-[(1S)-3-azido-1-hydroxy-2,6,6-trimethyl-4-oxocyclohex-2-en-1-yl]-3-methylpenta-2,4-dienoate
• CAS: 371762-50-4
• 化学式: C₁₆H₂₁N₃O₄
• 分子量: 319.36
• InChiKey: HZGMCRZTWORCSM-FSXOEFLGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  78
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  (+)-3'-azido-abscisic acid methyl ester 在 porcine liver esterase 、 potassium phosphate buffer 作用下， 以 甲醇 为溶剂， 生成 (+)-3'-azido-abscisic acid
  参考文献：
  名称：

  3′-Azidoabscisic acid as a photoaffinity reagent for abscisic acid binding proteins

  摘要：

  3 ' -Azidoabscisic acid was synthesized as a potential photoaffinity rea-gent for abscisic acid binding proteins. This compound was stable in organic and aqueous solutions in the dark, but was decomposed by UV irradiation. Its biological activity was equivalent to that of abscisic acid, suggesting that it may be an effective photoaffinity reagent. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0960-894x(01)00431-0
• 作为产物：
  描述：

  (±)顺,反-脱落酸甲酯 在 sodium azide 、 CHIRALCEL OD 、 四丁基氟化铵 、 双氧水 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 (+)-3'-azido-abscisic acid methyl ester
  参考文献：
  名称：

  3′-Azidoabscisic acid as a photoaffinity reagent for abscisic acid binding proteins

  摘要：

  3 ' -Azidoabscisic acid was synthesized as a potential photoaffinity rea-gent for abscisic acid binding proteins. This compound was stable in organic and aqueous solutions in the dark, but was decomposed by UV irradiation. Its biological activity was equivalent to that of abscisic acid, suggesting that it may be an effective photoaffinity reagent. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0960-894x(01)00431-0

文献信息

• 3′-Azidoabscisic acid as a photoaffinity reagent for abscisic acid binding proteins
  作者：Yasushi Todoroki、Takahiro Tanaka、Masayuki Kisamori、Nobuhiro Hirai

  DOI：10.1016/s0960-894x(01)00431-0

  日期：2001.9

  3 ' -Azidoabscisic acid was synthesized as a potential photoaffinity rea-gent for abscisic acid binding proteins. This compound was stable in organic and aqueous solutions in the dark, but was decomposed by UV irradiation. Its biological activity was equivalent to that of abscisic acid, suggesting that it may be an effective photoaffinity reagent. (C) 2001 Elsevier Science Ltd. All rights reserved.