1-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-butan-1-ol | 606099-28-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-butan-1-ol
• 英文别名: (2,2-Dimethyl-[1,3]-dioxolan-4-yl)-butanol；1-(2,2-dimethyl-1,3-dioxolan-4-yl)butan-1-ol
• CAS: 606099-28-9
• 化学式: C₉H₁₈O₃
• 分子量: 174.24
• InChiKey: MWVMMIHDRKFKQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-butan-1-ol 在 lead(IV) acetate 、 jones' reagent 、 硫酸 、 一水合肼 、 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 四氢呋喃 、 甲醇 、 乙醇 、 丙酮 、 苯 为溶剂， 反应 45.5h， 生成 D-正缬氨酸
  参考文献：
  名称：

  General and practical synthesis of (R)-phthalimido aldehydes and D-.alpha.-amino acids from D-mannitol

  摘要：

  DOI：

  10.1021/jo00376a046
• 作为产物：
  描述：

  2,2-Dimethyl-alpha-2-propenyl-1,3-dioxolane-4-methanol 在 palladium on activated charcoal 氢气 作用下， 以 甲醇 为溶剂， 以95%的产率得到1-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-butan-1-ol
  参考文献：
  名称：

  General and practical synthesis of (R)-phthalimido aldehydes and D-.alpha.-amino acids from D-mannitol

  摘要：

  DOI：

  10.1021/jo00376a046

文献信息

• Process for producing a deprotected alkoxylated polyol
  申请人：ARCO Chemical Technology, L.P.

  公开号：EP0506424A1

  公开（公告）日：1992-09-30

  An improved process for the hydrolysis and purification of an alkoxylated polyol containing a ketal protective functionality, and which may be employed to prepare reduced calorie esterified alkoxylated polyol fat mimetics useful in cooking and in food compositions, comprises contacting an aqueous mixture of the protected alkoxylated polyol with an acid to hydrolyse and thus deprotect the alkoxylated polyol,adding a base to neutralise the acid and cause the mixture to form a first phase containing the deprotected alkoxylated polyol and a second phase containing predominantly water, and separating the phases. The protected alkoxylated polyol may be formed by alkoxylating a protected polyol. The deprotected alkoxylated polyol may subsequently be esterified.

  一种改进的工艺用于水解和纯化含有酮缩保护官能基的烷氧基聚醇，可用于制备在烹饪和食品组合中有用的低热量酯化烷氧基聚醇脂肪模拟物，包括将受保护的烷氧基聚醇的水混合物与酸接触以水解和去保护烷氧基聚醇，添加碱以中和酸并使混合物形成含有去保护的烷氧基聚醇的第一相和主要含水的第二相，并分离相。受保护的烷氧基聚醇可以通过烷氧基化受保护的聚醇形成。然后可以对去保护的烷氧基聚醇进行酯化处理。
• NOVEL ENERGETIC POLYPHOSPHAZENES
  申请人：GOLDING Peter

  公开号：US20120053356A1

  公开（公告）日：2012-03-01

  This invention describes the synthesis and use of novel energetic poly(phosphazene) materials suitable for binding high explosives. These materials may also be used as explosives in their own right. The materials possess high energy density and are highly amenable to chemical modification thereby allowing for modification to the physical properties of the material. In particular the tacky and rubbery nature of these materials makes them ideal for use as binder and co-binder materials.

  这项发明描述了合成和使用新型高能聚(磷氮酸酯)材料，适用于绑定高爆炸物。这些材料也可以作为独立的爆炸物使用。这些材料具有高能量密度，并且极易进行化学修改，从而可以修改材料的物理性质。特别是这些材料粘性和橡胶状的特性使它们非常适合用作粘结剂和共粘剂材料。
• Novel Energetic Polyphosphazenes
  申请人：Golding Peter

  公开号：US20080108784A1

  公开（公告）日：2008-05-08

  This invention describes the synthesis and use of novel energetic poly(phosphazene) materials suitable for binding high explosives. These materials may also be used as explosives in their own right. The materials possess high energy density and are highly amenable to chemical modification thereby allowing for modification to the physical properties of the material. In particular the tacky and rubbery nature of these materials makes them ideal for use as binder and co-binder materials.

  这项发明描述了合成和使用新型高能聚（磷氮）材料，适用于绑定高爆炸物。这些材料也可以作为自身的爆炸物使用。这些材料具有高能量密度，并且高度适应化学修饰，因此可以修改材料的物理性质。特别是这些材料的黏性和橡胶质感使它们非常适合用作粘合剂和共粘剂材料。
• Energetic polyphosphazenes
  申请人：The Secretary of State for Defense

  公开号：US08268959B2

  公开（公告）日：2012-09-18

  This invention describes the synthesis and use of novel energetic poly(phosphazene) materials suitable for binding high explosives. These materials may also be used as explosives in their own right. The materials possess high energy density and are highly amenable to chemical modification thereby allowing for modification to the physical properties of the material. In particular the tacky and rubbery nature of these materials makes them ideal for use as binder and co-binder materials.

  本发明描述了合成和使用新型高能聚(磷氮)材料，适用于绑定高爆材料。这些材料也可作为自身的爆炸物使用。这些材料具有高能量密度，并且高度适合化学修饰，从而允许对材料的物理性质进行修改。特别是这些材料的黏性和橡胶性质使它们非常适合用作粘合剂和共粘合剂材料。
• Novel energetic polyphosphazenes
  申请人：The Secretary of State For Defence

  公开号：EP2460842A2

  公开（公告）日：2012-06-06

  This invention describes the synthesis and use of novel energetic poly(phosphazene) materials suitable for binding high explosives, consisting of homopolymer compounds comprising n units of structure (iii): where R2 = R3 and are each alkyl, alkyl ether or carbohydrate based side chains which contain energetic functionalities including nitro, nitramine, nitrate ester, or azide, and 3 ≤ n ≤ 10000. These materials may also be used as explosives in their own right. The materials possess high energy density and are highly amenable to chemical modification thereby allowing for modification to the physical properties of the material. In particular the tacky and rubbery nature of these materials makes them ideal for shaping co-binder materials.

  本发明描述了适用于结合烈性炸药的新型高能聚（磷苯）材料的合成和使用，该材料由包含 n 个结构(iii)单元的均聚物化合物组成： 其中 R2 = R3 和 R3 分别为烷基、烷基醚或碳水化合物基侧链，这些侧链含有高能官能团，包括硝基、硝胺、硝酸酯或叠氮化物，且 3 ≤ n ≤ 10000。 这些材料本身也可用作炸药。这些材料具有很高的能量密度，非常容易进行化学改性，因此可以改变材料的物理特性。特别是这些材料的粘性和橡胶性质，使其成为塑造共粘合剂材料的理想材料。