2-(1-methylcyclohexyl)-6,6-dimethylfulvene | 132380-72-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-(1-methylcyclohexyl)-6,6-dimethylfulvene
• 英文别名: 3-(1-methyl-l-cyclohexyl)-6,6-dimethylfulvene；3-(1-Methyl-1-cyclohexyl)-6,6-dimethylfulvene；1-methyl-1-(3-propan-2-ylidenecyclopenta-1,4-dien-1-yl)cyclohexane
• CAS: 132380-72-4
• 化学式: C₁₅H₂₂
• 分子量: 202.34
• InChiKey: FSYWBVYXZAJYLX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  四氰基乙烯 、 2-(1-methylcyclohexyl)-6,6-dimethylfulvene 以 丙酮 为溶剂， 反应 3.0h， 以59%的产率得到7-Isopropylidene-5-(1-methyl-cyclohexyl)-bicyclo[2.2.1]hept-5-ene-2,2,3,3-tetracarbonitrile
  参考文献：
  名称：

  空间拥挤的环戊二烯及其过渡金属配合物的合成与性能

  摘要：

  1,3-二烷基取代的环戊二烯，C 5 H 4 RR'，Cp'H（Va–g）（其中R和R'为叔丁基，异丙基，新戊基，环己基或1-甲基环己基）。这些是通过将甲基或氢化物阴离子亲核加成到相应的2-烷基-6,6-二烷基富勒烯（IIIa–f）中，然后水解而合成的。这些取代的1,3-环戊二烯已转化为有机金属衍生物例如[CP'Fe（CO）2 ] 2，[CP'M（CO）3本人]（MMo或W）和CP' 22Fe。为了研究取代的环戊二烯基配体的空间和电子性质，已经研究了所选配合物的光谱和电化学性质。

  DOI：

  10.1016/0022-328x(93)83365-3
• 作为产物：
  描述：

  四氢吡咯 、 1-(1-methylcyclohexyl)cyclopenta-1,3-diene 以 甲醇 、 水 、 丙酮 为溶剂， 以87%的产率得到2-(1-methylcyclohexyl)-6,6-dimethylfulvene
  参考文献：
  名称：

  Metallocenes, their preparation, olefin polymerisation catalysts and a process for producing polyolefins

  摘要：

  公开号：

  EP1138687B1

文献信息

• Metallocene compound, process for preparing metallocene compund, olefin polymerization catalyst, process for preparing polyolefin, and polyolefin
  申请人：Kawai Koji

  公开号：US20050228155A1

  公开（公告）日：2005-10-13

  The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method. The process for preparing a polyolefin according to the invention is intended to prepare a polyolefin having excellent impact resistance and transparency, and this process comprises homopolymerizing an α-olefin of 3 to 8 carbon-atoms or copolymerizing an olefin of 3 to 8 carbon atoms and another α-olefin in the presence of an olefin polymerization catalyst containing the above-mentioned metallocene compound.

  本发明的金属茂化合物和含有该化合物的烯烃聚合催化剂旨在生产一个能够制备具有高聚合活性的等规聚物的催化剂。该金属茂化合物含有一个取代环戊二烯基和一个(取代)芴基，并且具有这些基团被碳氢基团或类似物桥接的结构。本发明的制备金属茂化合物的方法旨在选择性地制备特定的金属茂化合物，以避免产生异构体，在该过程中通过特定的方法合成中间产物。本发明的制备聚烯烃的方法旨在制备具有优异的冲击强度和透明度的聚烯烃，该方法包括在上述含有金属茂化合物的烯烃聚合催化剂的存在下，同聚合3到8个碳原子的α-烯烃或共聚合3到8个碳原子的烯烃和另一个α-烯烃。
• Metallocene compound, process for producing metallocene compound, olefin polymerization catalyst, process for producing polyolefin, and polyolefin
  申请人：Kawai Koji

  公开号：US06939928B1

  公开（公告）日：2005-09-06

  The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method. The process for preparing a polyolefin according to the invention is intended to prepare a polyolefin having excellent impact resistance and transparency, and this process comprises homopolymerizing an α-olefin of 3 to 8 carbon atoms or copolymerizing an olefin of 3 to 8 carbon atoms and another α-olefin in the presence of an olefin polymerization catalyst containing the above-mentioned metallocene compound.

  本发明的金属茂化合物和含有该化合物的烯烃聚合催化剂旨在生产一种能够制备高聚合活性的等规聚合物的催化剂。该金属茂化合物含有取代环戊二烯基基团和（取代）芴基团，并且具有这些基团由碳氢化合物桥接或类似物桥接的结构。本发明的制备金属茂化合物的方法旨在有选择地制备特定的金属茂化合物，以避免产生异构体，在该过程中，通过特定方法合成中间产物。本发明的制备聚烯烃的方法旨在制备具有优异的冲击强度和透明度的聚烯烃，该方法包括在上述含有金属茂化合物的烯烃聚合催化剂的存在下，同聚合3至8个碳原子的α-烯烃或共聚合3至8个碳原子的烯烃和另一种α-烯烃。
• Metallocene compound, process for preparing metallocene compound, olefin polymerization catalyst, process for preparing polyolefin, and polyolefin
  申请人：Mitsui Chemicals, Inc.

  公开号：US07449533B2

  公开（公告）日：2008-11-11

  The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method. The process for preparing a polyolefin according to the invention is intended to prepare a polyolefin having excellent impact resistance and transparency, and this process comprises homopolymerizing an α-olefin of 3 to 8 carbon-atoms or copolymerizing an olefin of 3 to 8 carbon atoms and another α-olefin in the presence of an olefin polymerization catalyst containing the above-mentioned metallocene compound.

  本发明的金属茂化合物和含有该化合物的烯烃聚合催化剂旨在生产能够制备高聚合活性的同形聚合物的催化剂。该金属茂化合物含有取代环戊二烯基和（取代）芴基，并且具有这些基团由碳氢化合物等桥接的结构。本发明的制备金属茂化合物的方法旨在有选择地制备特定的金属茂化合物，以避免产生异构体，在此过程中，通过特定方法合成了中间产物。本发明的制备聚烯烃的方法旨在制备具有优异的冲击强度和透明度的聚烯烃，该方法包括在上述含有金属茂化合物的烯烃聚合催化剂的存在下，同聚合3至8个碳原子的α-烯烃或共聚合3至8个碳原子的烯烃和另一种α-烯烃。
• CLARK, T. JEFFREY;NILE, TERENCE A., SYNLETT.,(1990) N0, C. 589-590
  作者：CLARK, T. JEFFREY、NILE, TERENCE A.

  DOI：——

  日期：——
• Metallocenes, their preparation, olefin polymerisation catalysts and a process for producing polyolefins
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1138687B1

  公开（公告）日：2007-04-11