bixlozone | 81777-95-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bixlozone
• 英文别名: 2-(2,4-dichlorophenyl)methyl-4,4-dimethyl-3-isoxazolidinone；2-(2,4-dichlorophenyl)methyl-4,4-dimethyl-3-isoxazolidone；2-[(2,4-dichlorophenyl)methyl]-4,4-dimethyl-isoxazolidin-3-one；2-[(2,4-dichlorophenyl)methyl]-4,4-dimethyl-1,2-oxazolidin-3-one
• CAS: 81777-95-9
• 化学式: C₁₂H₁₃Cl₂NO₂
• 分子量: 274.147
• InChiKey: FHUKASKVKWSLCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,4-二氯苯甲醛肟 在 吡啶 、 盐酸 、 三甲基氯硅烷 、 1-ethyl-2-[3-(1-ethylnaphtho[1,2-d]thiazole-2(1H)-ylidene)-2-methyl-1-propen-1-yl]-naphtho[1,2-d]thiazolium bromide 、 sodium cyanoborohydride 、 potassium hydroxide 作用下， 以 甲醇 为溶剂， 反应 38.5h， 生成 bixlozone
  参考文献：
  名称：

  HIGH-PURITY THERMOSTABLE CRYSTAL FORM OF SUBSTITUTED 3-ISOXAZOLIDINONE COMPOUND, PREPARATION METHOD THEREFOR AND APPLICATION THEREOF

  摘要：

  该应用程序提供了一种替代3-异噁唑烷酮化合物的高纯度热稳定晶型，以及其制备方法和应用。该高纯度热稳定晶型是通过本技术的特定方法制备的，并通过单晶X射线衍射确定为正交晶体，具有P212121空间群和晶格参数a=9.2301(2) Å，b=11.0751(3) Å，c=12.7554(3) Å，α=90°，β=90°和γ=90°。该正交晶体可以方便地用于制备农药配方，如悬浮浓缩液和水分散颗粒，制备的新配方具有更好的除草活性和作物安全性。

  公开号：

  US20220089553A1

文献信息

• HERBICIDALLY ACTIVE 3-PHENYLISOXAZOLINE-5-CARBOXAMIDES OF TETRAHYDRO- AND DIHYDROFURANCARBOXAMIDES
  申请人：BAYER AKTIENGESELLSCHAFT

  公开号：US20200216403A1

  公开（公告）日：2020-07-09

  The invention relates to 3-phenylisoxazoline-5-carboxamides of tetrahydro and dihydrofuran carboxamides of general formula (I) and to their agrochemically compatible salts (I) as well as to the use thereof in the field of plant protection.

  这项发明涉及一般式(I)的3-苯基异噁唑啉-5-羧酰胺以及其农药兼容盐(I)，以及它们在植物保护领域中的应用。
• Herbicidal 3-isoxazolidinones and hydroxamic acids
  申请人：FMC Corporation

  公开号：US04405357A1

  公开（公告）日：1983-09-20

  Novel 3-isoxazolidinone compounds and novel hydroxamic acid intermediates from which they are prepared exhibit herbicidal activity to grassy and broad-leaf plant species while leaving legumes, especially soybeans, unaffected. The preparation and herbicidal activity of the compounds is exemplified.

  新型3-异噁唑烷酮化合物和新型羟羧酸中间体表现出对禾本科和阔叶植物种类的除草活性，同时不影响豆科植物，特别是大豆。这些化合物的制备和除草活性得到了示范。
• SUBSTITUTED 3-HETEROARYLOXY-1H-PYRAZOLES AND SALTS THEREOF AND THEIR USE AS HERBICIDAL ACTIVE SUBSTANCES
  申请人：BAYER CROPSCIENCE AKTIENGESELLSCHAFT

  公开号：US20200181117A1

  公开（公告）日：2020-06-11

  A substituted 3-heteroaryloxy-1H-pyrazole of the general formula (I) or salt thereof Substituted 3-heteroaryloxy-1H-pyrazoles of the general formula (I) are described, as is their use as herbicides, in particular for controlling broad-leaved weeds and/or weed grasses in crops of useful plants and/or as plant growth regulators for influencing the growth of crops of useful plants described. The present invention also relates to herbicidal and/or plant growth-regulating compositions comprising one or more compounds of the general formula (I).

  通用式（I）的取代3-杂环氧基-1H-吡唑或其盐已被描述。 通用式（I）的取代3-杂环氧基-1H-吡唑被描述， 以及它们作为除草剂的用途，特别是用于控制作物中的阔叶杂草和/或杂草草，以及作为植物生长调节剂，影响作物生长的用途。 本发明还涉及包含一个或多个通用式（I）化合物的除草剂和/或植物生长调节剂组合物。
• SUBSTITUTED 2-HETEROARYLOXYPYRIDINES AND SALTS THEREOF AND THEIR USE AS HERBICIDAL AGENTS
  申请人：Bayer Aktiengesellschaft

  公开号：US20210276974A1

  公开（公告）日：2021-09-09

  Substituted 2-heteroaryloxypyridines and salts thereof and use thereof as herbicidal active substances Substituted 2-heteroaryloxypyridines of the general formula (I) are described, and their use as herbicides, in particular for controlling broad-leaved weeds and/or weed grasses in crops of useful plants and/or as plant growth regulators for influencing the growth of crops of useful plants. The present invention further relates to herbicidal and/or plant growth-regulating compositions comprising one or more compounds of the general formula (I).

  2-杂环氧基吡啶及其盐的替代物及其作为除草活性物质的用途被描述，一般式(I)的2-杂环氧基吡啶的替代物被描述，并且它们作为除草剂的用途，特别是用于控制作物中的阔叶杂草和/或杂草草本植物，或者作为植物生长调节剂，以影响作物的生长。本发明还涉及包含一种或多种一般式(I)化合物的除草剂和/或植物生长调节剂组合物。
• [EN] BENZAMIDE COMPOUNDS AND THEIR USE AS HERBICIDES II<br/>[FR] COMPOSÉS DE BENZAMIDE ET LEUR UTILISATION EN TANT QU'HERBICIDES II
  申请人：BASF SE

  公开号：WO2018219936A1

  公开（公告）日：2018-12-06

  The invention relates to benzamides of formula (I), wherein Q is Q1 or Q2 or Q3 or Q4, and their use as herbicides. In said formula (I), R2 is R2cR2dNC(O)NR2n-Z2, R5 is hydrogen, R1, R3, R4 and R6 represent groups such as hydrogen, halogen or organic groups such as alkyl or phenyl.The invention further refers to a composition comprising such compound and to the use thereof for controlling unwanted vegetation.

  该发明涉及式(I)的苯甲酰胺，其中Q是Q1或Q2或Q3或Q4，并且它们作为除草剂的用途。在所述的式(I)中，R2是R2cR2dNC(O)NR2n-Z2，R5是氢，R1、R3、R4和R6代表氢、卤素或有机基团，如烷基或苯基。该发明还涉及包含这种化合物的组合物以及将其用于控制不受欢迎的植被的用途。