neopentyl glycol-bis-(4-methyl-3-cyclohexenecarboxylate) | 744910-27-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: neopentyl glycol-bis-(4-methyl-3-cyclohexenecarboxylate)
• 英文别名: 2,2-dimethyl-propane-1,3-diol bis(4-methyl-3-cyclohexenecarboxylate)；[2,2-Dimethyl-3-(4-methylcyclohex-3-ene-1-carbonyl)oxypropyl] 4-methylcyclohex-3-ene-1-carboxylate
• CAS: 744910-27-8
• 化学式: C₂₁H₃₂O₄
• 分子量: 348.483
• InChiKey: DXSKESATVUJVHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  25
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  neopentyl glycol-bis-(4-methyl-3-cyclohexenecarboxylate) 在 过氧乙酸 作用下， 以 丙酮 为溶剂， 以70%的产率得到neopentyl glycol-bis-(4-methyl-3,4-epoxy-cyclohexanecarboxylate)
  参考文献：
  名称：

  Active ray curable ink-jet composition, image forming method using the same, ink-jet recording apparatus, and triarylsulfonium salt compound

  摘要：

  一种活性紫外光固化喷墨墨水组合物，包括含有不在活性紫外光辐射下生成苯的光诱导酸发生剂的盐类和含有分子中含有氧杂环戊烷环的光聚合化合物。

  公开号：

  US20040244641A1
• 作为产物：
  描述：

  甲基4-甲基-3-环己烯-1-羧酸酯 、 2,2-二甲基-1,3-丙二醇 在 对甲苯磺酸 作用下， 反应 12.0h， 以86%的产率得到neopentyl glycol-bis-(4-methyl-3-cyclohexenecarboxylate)
  参考文献：
  名称：

  Active ray curable ink-jet composition, image forming method using the same, ink-jet recording apparatus, and triarylsulfonium salt compound

  摘要：

  一种活性紫外光固化喷墨墨水组合物，包括含有不在活性紫外光辐射下生成苯的光诱导酸发生剂的盐类和含有分子中含有氧杂环戊烷环的光聚合化合物。

  公开号：

  US20040244641A1

文献信息

• Cycloaliphatic polyepoxy compounds and preparation thereof
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1873149A1

  公开（公告）日：2008-01-02

  Is disclosed a cycloaliphatic polyepoxy compound represented by following Formula (1): wherein Y represents a linkage group or a single bond; and HAS each represent hydrogen atom at the junction between cyclohexane ring and oxirane ring, and the cyclohexane rings may each further have one or more substituents in addition to the groups shown in the formula. The cycloaliphatic polyepoxy compound contains stereoisomers in such proportions as to have a ratio A/B of 1.8 or more, wherein "A" and "B" are integrated intensities of signals of protons at the junction between cyclohexane ring and oxirane ring as determined by 1H-NMR spectroscopy of the compound, in which "A" represents the integrated intensity of a signal observed at a lower magnetic field, and "B" represents the integrated intensity of a signal observed at a higher magnetic field.

  公开了一种由下式（1）表示的环状脂肪族多环氧化合物：其中，Y表示连接基团或单键；HAS分别表示在环己烷环和环氧环之间的连接处的氢原子，环己烷环除了式中所示的基团外，还可以有一个或多个取代基。所述环状脂肪族多环氧化合物包含立体异构体，其比例为A/B≥1.8，其中“A”和“B”是化合物的1H-NMR光谱测定下在环己烷环和环氧环之间的连接处的质子信号的积分强度，“A”表示在较低磁场下观察到的信号的积分强度，“B”表示在较高磁场下观察到的信号的积分强度。
• Active energy ray curable composition
  申请人：Konica Minolta Holdings, Inc.

  公开号：US20040167315A1

  公开（公告）日：2004-08-26

  An active energy ray curable composition containing an epoxy compound having at least one oxirane ring having substituents at positions &agr; and &bgr; of the oxirane ring.

  一种活性能量射线可固化组合物，其中包含至少具有一个环氧环的氧化环己烷化合物，其在环氧环的α和β位置具有取代基。
• ACTIVE ENERGY RAY CURABLE COMPOSITION
  申请人：SASA Nobumasa

  公开号：US20060264529A1

  公开（公告）日：2006-11-23

  An active energy ray curable composition containing an epoxy compound having at least one oxirane ring having substituents at positions α and β of the oxirane ring.

  一种活性能量射线可固化的组合物，包含至少具有一个环氧基团的环氧化合物，其在环氧基团的α和β位置具有取代基。
• RECOVERY METHOD AND REUSE METHOD OF OXO ACID CATALYST
  申请人：DAICEL CORPORATION

  公开号：US20160074856A1

  公开（公告）日：2016-03-17

  Provided is a method for easily and efficiently recovering an oxoacid catalyst without deterioration in reaction product yield and catalytic activity, where the oxoacid catalyst has been used in a reaction for oxidizing an organic compound with hydrogen peroxide, also provided is a method for producing an oxide in which an organic compound is oxidized with hydrogen peroxide using the oxoacid catalyst recovered by the method, to yield the corresponding oxide. A method according to the present invention recovers an oxoacid catalyst used in a reaction for oxidizing an organic compound with hydrogen peroxide in an aqueous/organic solvent two-phase system. The method includes Step 1 in which the pH in the reaction system is adjusted to 5.0 or higher so as to transfer the oxoacid catalyst to the aqueous phase, and the organic phase is removed.

  提供了一种方法，可以轻松高效地回收氧酸催化剂，而不会降低反应产物收率和催化活性。该氧酸催化剂已用于氧化有机化合物的反应中，使用过氧化氢。同时提供了一种方法，使用通过该方法回收的氧酸催化剂，将有机化合物与过氧化氢氧化，以产生相应的氧化物。本发明提供的方法在水/有机溶剂两相体系中回收用于氧化有机化合物的氧酸催化剂。该方法包括步骤1，将反应体系中的pH调整至5.0或更高，以将氧酸催化剂转移至水相，并去除有机相。
• Cycloaliphatic polyepoxy compounds and prepartation thereof
  申请人：Kubo Takashi

  公开号：US20080004425A1

  公开（公告）日：2008-01-03

  Is disclosed a cycloaliphatic polyepoxy compound represented by following Formula (1): wherein Y represents a linkage group or a single bond; and H A s each represent hydrogen atom at the junction between cyclohexane ring and oxirane ring, and the cyclohexane rings may each further have one or more substituents in addition to the groups shown in the formula. The cycloaliphatic polyepoxy compound contains stereoisomers in such proportions as to have a ratio A/B of 1.8 or more, wherein “A” and “B” are integrated intensities of signals of protons at the junction between cyclohexane ring and oxirane ring as determined by 1 H-NMR spectroscopy of the compound, in which “A” represents the integrated intensity of a signal observed at a lower magnetic field, and “B” represents the integrated intensity of a signal observed at a higher magnetic field.