ethyl phytyl ether | 66432-65-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: ethyl phytyl ether
• 英文别名: (E)-1-ethoxy-3,7,11,15-tetramethylhexadec-2-ene
• CAS: 66432-65-3
• 化学式: C₂₂H₄₄O
• 分子量: 324.591
• InChiKey: ADGZSLVXSZYLLW-OQKWZONESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  23
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  ethyl phytyl ether 在 二甲基硫 、 rose bengal 作用下， 生成 植酮 、 ethyl 2-hydroxy-3-methylidene-7,11,15-trimethylhexadecanyl ether 、 trans-3,7,11,15-tetramethyl-2,3-epoxyhexadecanal diethyl acetal 、 cis-3,7,11,15-tetramethyl-2,3-epoxyhexadecanal diethyl acetal
  参考文献：
  名称：

  Photosensitized oxygenation reactions of phytol and its derivatives

  摘要：

  DOI：

  10.1021/jo00357a043

文献信息

• METHODS FOR PRODUCING HYDROCARBON PRODUCTS FROM ALGAL BIOMASS
  申请人：Lupton Francis S.

  公开号：US20110287503A1

  公开（公告）日：2011-11-24

  Methods for producing hydrocarbon oils from algal biomass are provided. The algal biomass is hydrogenolysed under reaction conditions sufficient to produce a partially deoxygenated lipid-based oil. The algal biomass may be whole algal biomass, residual algal biomass, or both. The algal biomass is hydrogenolysed by liquefying the algal biomass in the presence of a hydrogenolytic catalyst in a hydrogen atmosphere at an elevated temperature and pressure to produce an organic phase containing the partially deoxygenated lipid-based oil, an aqueous phase, and a solid phase. The aqueous and solid phases may be removed from the partially deoxygenated lipid-based oil. The partially deoxygenated lipid-based oil is then substantially deoxygenated using a hydroprocessing catalyst to produce the hydrocarbon oil.
• Photosensitized oxygenation reactions of phytol and its derivatives
  作者：Satoru Mihara、Hideki Tateba

  DOI：10.1021/jo00357a043

  日期：1986.4