2-溴十三酸 | 95658-34-7

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 2-溴十三酸
• 中文别名: 2-溴十三烷酸
• 英文名称: 2-bromotridecanoic acid
• 英文别名: 2-Brom-tridecansaeure
• CAS: 95658-34-7
• 化学式: C₁₃H₂₅BrO₂
• 分子量: 293.244
• InChiKey: OYAABNNKUCAHEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2915900090

反应信息

• 作为反应物：
  描述：

  2-溴十三酸 在 氨 作用下， 生成 (+/-)-2-aminotridecenoic acid
  参考文献：
  名称：

  Zeelen; Havinga, Recueil des Travaux Chimiques des Pays-Bas, 1958, vol. 77, p. 267,271

  摘要：

  DOI：
• 作为产物：
  描述：

  十三酸 在 磷化氢 、 溴 作用下， 生成 2-溴十三酸
  参考文献：
  名称：

  Le Sueur, Journal of the Chemical Society, 1905, vol. 87, p. 1901

  摘要：

  DOI：

文献信息

• Two‐Dimensional Detergent Expansion Strategy for Membrane Protein Studies
  作者：Fei Zhao、Zhihao Zhu、Linshan Xie、Feng Luo、Huixia Wang、Yanli Qiu、Weiling Luo、Fang Zhou、Dongxiang Xue、Zhihui Zhang、Tian Hua、Dong Wu、Zhi‐Jie Liu、Zhiping Le、Houchao Tao

  DOI：10.1002/chem.202201388

  日期：2022.8.4

  Detergents are the most frequently applied reagents in membrane protein (MP) studies. The limited diversity of one-head-one-tailed traditional detergents, however, is far from sufficient for structurally distinct MPs. Expansion of detergent repertoire has a continuous momentum. In line with the speculation that detergent pre-assembly exerts superiority, herein we report for the first time cross-conjugation

  去污剂是膜蛋白 (MP) 研究中最常用的试剂。然而，一头一尾传统洗涤剂的有限多样性对于结构不同的 MP 来说还远远不够。洗涤剂品种的扩张势头不断。与去污剂预组装发挥优势的推测一致，本文首次报道了两个系列单体去污剂的交叉共轭，用于构建二聚去污剂的二维库。最佳去污剂在个体 MP 的系统评估中具有独特的偏好。此外，前所未有的混合去污剂 14M8G 和 14M9G 分别实现了转运蛋白 MsbA 的高质量 EM 研究和 G 蛋白偶联受体 A2A AR 的 NMR 研究。鉴于交叉偶联化学物质的丰富性，
• Phenolic thioethers, their production and use
  申请人：SHIONOGI SEIYAKU KABUSHIKI KAISHA trading under the name of SHIONOGI & CO. LTD.

  公开号：EP0348203A1

  公开（公告）日：1989-12-27

  Phenolic thioethers of the formula: wherein R is a hydrogen atom or a protective group for carboxyl, X is a straight or branched C₄-C₁₅ alkylene group, a straight or branched C₁-C₁₅ alkylene group having a phenylene group or a straight or branched C₂-C₁₅ alkenylene group, and their salts, which inhibit the denaturation of low density lipoproteins (LDL) and the incorporation of LDL by macrophages and are useful as anti-arteriosclerosis agents.

  式中的酚硫醚： 其中 R 是氢原子或羧基的保护基团，X 是直链或支链 C₄-C₁₅ 亚烷基、直链或支链 C₁-C₁₅ 亚烷基（具有亚苯基）或直链或支链 C₂-C₁₅ 烯基、及其盐类，可抑制低密度脂蛋白（LDL）的变性和巨噬细胞对 LDL 的结合，可用作抗动脉硬化剂。
• Iminyl Radicals from α-Azido <i>o</i>-Iodoanilides via 1,5-H Transfer Reactions of Aryl Radicals: New Transformation of α-Azido Acids to Decarboxylated Nitriles
  作者：Giorgio Bencivenni、Tommaso Lanza、Rino Leardini、Matteo Minozzi、Daniele Nanni、Piero Spagnolo、Giuseppe Zanardi

  DOI：10.1021/jo800453z

  日期：2008.6.1

  The radical reaction of tributyltin hydride with o-iodo-N-methylanilides derived from alpha-azido acids provides an excellent access to alpha-(aminocarbonyl)iminyl radicals through 1,5-hydrogen transfer reaction of initially formed aryl radicals followed by beta-elimination of dinitrogen from ensuing alpha-azido-alpha-(aminocarbonyl)alkyl radicals. The outcoming iminyls display a peculiar tendency to form corresponding nitriles by beta-elimination of aminocarbonyl radicals.
• COMPOSITIONS AND RELATED METHODS FOR AGRICULTURE
  申请人：Flagship Pioneering Innovations V, Inc.

  公开号：US20210289794A1

  公开（公告）日：2021-09-23

  The invention comprises methods for decreasing colonization by a bacterium of a gut of a stink bug, the method comprising providing a composition comprising vanillin or an analog thereof; and delivering said composition to an egg from which the stink bug will hatch, whereby colonization by the bacterium within the gut of the stink bug hatched from the egg treated with the composition is decreased relative to a stink bug hatched from an untreated egg. In some embodiments, the decrease in colonization by the bacterium decreases the fitness of the stink bug, e.g., decreases reproductive ability, survival, rate of development, number of eggs, number of hatched eggs, adult emergence rate, body length, body width, body mass, or cuticle thickness. In some embodiments of the methods herein, the bacterial colonization-disrupting agent is an inhibitor of bacterial metabolism. In some embodiments, the bacterial colonization-disrupting agent is a polyhydroxyalkanoate (PHA) synthesis inhibitor.
• US8466291B2
  申请人：——

  公开号：US8466291B2

  公开（公告）日：2013-06-18