2Z,7E-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,7-nonadiene-4-yne-1,6-diol | 50895-68-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2Z,7E-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,7-nonadiene-4-yne-1,6-diol
• 英文别名: 2Z,7E-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,7-nonadien-4-yne-1,6-diol；3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-nona-2Z,7E-dien-4-yne-1,6-diol；oxenine；2Z,7E-3,7-Dimethyl-9-(2,6,6-trimethyl-1-cyclohexenyl)-2,7-nonadien-4-in-1,6-diol (β-C(20)13Z-Diolin)；9,13-Dimethyl-7-<1,1,5-trimethyl-cyclohex-5-en-6-yl>-nona-8,13-dien-11-in-10,15-diol；9,13-Dimethyl-7-(1,1,5-trimethyl-cyclohex-5-en-6-yl)-nona-8,13-dien-11-in-10,15-diol；(2Z,7E)-3,7-dimethyl-9-(2,6,6-trimethylcyclohexen-1-yl)nona-2,7-dien-4-yne-1,6-diol
• CAS: 50895-68-6
• 化学式: C₂₀H₃₀O₂
• 分子量: 302.457
• InChiKey: DYJPCHNUVWLJST-ZCWJWGKDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  22
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2Z,7E-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,7-nonadiene-4-yne-1,6-diol 生成 11,12-Didehydro-[7t,9t,13c]retinol
  参考文献：
  名称：

  Khristoforov,V.L. et al., Journal of Organic Chemistry USSR (English Translation), 1973, vol. 9, p. 1868 - 1872

  摘要：

  DOI：
• 作为产物：
  描述：

  (Z)-3-甲基戊-2-烯-4-炔-1-醇 、 (E)-2-methyl-4-(2,6,6-trimethyl-1-cyclohexenyl)-2-butenal 生成 2Z,7E-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,7-nonadiene-4-yne-1,6-diol
  参考文献：
  名称：

  Khristoforov,V.L. et al., Journal of Organic Chemistry USSR (English Translation), 1973, vol. 9, p. 1868 - 1872

  摘要：

  DOI：

文献信息

• [EN] PROCESS OF PRODUCTION OF 3,7-DIMETHYL-9-(2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-YL)-NONA-2Z,7E-DIEN-4-YNE-1,6-DIOL<br/>[FR] PROCÉDÉ DE PRODUCTION DE 3,7-DIMÉTHYL-9-(2,6,6-TRIMÉTHYL-1-CYCLOHEXÈN-1-YL)-NONA-2Z,7E-DIEN-4-YNE-1,6-DIOL
  申请人：DSM IP ASSETS BV

  公开号：WO2019016315A1

  公开（公告）日：2019-01-24

  The present invention relates to an improved method for producing 3,7-dimethyl- 9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-nona-2Z,7E-dien-4-yne-1,6-diol.

  本发明涉及一种改进的生产3,7-二甲基-9-(2,6,6-三甲基-1-环己烯-1-基)-诺纳-2Z,7E-二烯-4-炔-1,6-二醇的方法。
• [EN] PDIN ALLOY CATALYST, PREPARATION METHOD THEREFOR AND APPLICATION THEREOF<br/>[FR] CATALYSEUR EN ALLIAGE PDIN, PROCÉDÉ DE PRÉPARATION, ET APPLICATION ASSOCIÉE<br/>[ZH] PdIn合金催化剂及其制备方法、应用
  申请人：ZHEJIANG NHU CO LTD

  公开号：WO2020042524A1

  公开（公告）日：2020-03-05

  本发明提供一种PdIn合金催化剂，所述PdIn合金催化剂包含载体以及负载于所述载体的Pd金属，所述载体为具有多个孔道的氮掺杂多孔碳复合材料，所述氮掺杂多孔碳复合材料包含氮掺杂多孔碳材料、氧化铟以及通过该孔道而暴露的金属In，所述氧化铟均匀分布于所述氮掺杂多孔碳材料中，所述Pd金属的边角位选择性地被金属In占据。本发明还提供一种PdIn合金催化剂的制备方法及其应用。
• PROCESS OF PRODUCTION OF 3,7-DIMETHYL-9-(2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-YL)-NONA-2Z,7E-DIEN-4-YNE-1,6-DIOL
  申请人：DSM IP Assets B.V.

  公开号：EP3655391A1

  公开（公告）日：2020-05-27
• [EN] PROCESS FOR THE SELECTIVE ACYLATION OF PRIMARY HYDROXY GROUPS IN THE PRESENCE OF SECONDARY HYDROXY GROUPS AND CATALYST THEREFOR<br/>[FR] PROCÉDÉ D'ACYLATION SÉLECTIVE DE GROUPES HYDROXY PRIMAIRES EN PRÉSENCE DE GROUPES HYDROXY SECONDAIRES ET CATALYSEUR ASSOCIÉ
  申请人：DSM IP ASSETS BV

  公开号：WO2020007856A1

  公开（公告）日：2020-01-09

  The present invention is directed towards a process for the selective acylation of a primary hydroxy group in a compound that may optionally further comprise at least one secondary hydroxy group and/or one tertiary hydroxy group comprising the step of reacting the compound with an acylating agent in the presence of a solid base catalyst, whereby the solid base catalyst is a hydrotalcite-like compound or a mixed metal oxide derived by activation thereof. The present invention is also directed towards a mixed metal oxide derived by activation of a hydrotalcite-like compound characterized by a BET surface area in the range of from 50 to 300 m2/g and a pore volume in the range of from 0.15 to 0.8 cm3/g, which has been thermally activated in air at a temperature in the range of from 70°C to 1010°C, and which contains magnesium and aluminium with a Mg/Al ratio in the range of from 0.5:1 to 10:1, and exchangeable anions such as e.g. CO3 2-, NO3-and OH-, as well as to its manufacture and its use as catalyst for the acylation of primary hydroxy groups, preferably for the acylation of primary hydroxy groups in compounds that may optionally further comprise at least one secondary hydroxy group and/or one tertiary hydroxy group.
• Khristoforov,V.L. et al., Journal of Organic Chemistry USSR (English Translation), 1973, vol. 9, p. 1868 - 1872
  作者：Khristoforov,V.L. et al.

  DOI：——

  日期：——