9,13-dimethyl-7-(1,1,5-trimethyl-5-cyclohexen-6-yl)-9,11-heptadien-13-one | 51077-54-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 9,13-dimethyl-7-(1,1,5-trimethyl-5-cyclohexen-6-yl)-9,11-heptadien-13-one
• 英文别名: 9-methyl-7-(1,1,5-trimethyl-5-cyclohexen-6-yl)-9E,11E-octadien-13-one；9-methyl-7-(1,1,5-trimethyl-5-cyclohexen-6-yl)-9,11-octadien-13-one；6-methyl-8-(2,6,6-trimethylcyclohex-1-enyl)-octa-3,5-dien-2-one；6-methyl-8-(2,6,6-trimethyl-1-cyclohexenyl)-3,5-octadien-2-one；6-methyl-8-(2,6,6-trimethylcyclohex-1-en-1-yl)octa-3,5-dien-2-one；7,8-Dihydro-β-ionylidenaethylidenaceton；(3E,5E)-6-methyl-8-(2,6,6-trimethylcyclohexen-1-yl)octa-3,5-dien-2-one
• CAS: 51077-54-4
• 化学式: C₁₈H₂₈O
• 分子量: 260.42
• InChiKey: YFIKBFNWYFWUPD-FGEXGLGOSA-N

物化性质

• 沸点：
  365.6±31.0 °C(Predicted)
• 密度：
  0.893±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9,13-dimethyl-7-(1,1,5-trimethyl-5-cyclohexen-6-yl)-9,11-heptadien-13-one 在 喹啉 、 Lindlar's catalyst 氢气 、 calcium 作用下， 以 吡啶 、 乙醚 、 氨 、 Petroleum ether 为溶剂， 反应 123.0h， 生成 13-acetoxy-9,13-dimethyl-7-(1,1,5-trimethyl-5-cyclohexen-6-yl)-9,11,14-nonatriene
  参考文献：
  名称：

  Tutorskaya, O. O.; Miropol'skaya, M. A.; Brodskii, A. V., Journal of Organic Chemistry USSR (English Translation), 1985, vol. 21, p. 1682 - 1687

  摘要：

  DOI：

文献信息

• An efficient method for the phosphonation of C=X compounds
  作者：A. O. Kolodyazhnaya、O. O. Kolodyazhnaya、O. I. Kolodyazhnyi

  DOI：10.1134/s1070363210040055

  日期：2010.4

  (aldehydes, ketones, ketophosphonates, aldimines, ketimines, isocyanates, isothiocyanates, and activated olefins) in the presence of amines and anilines hydrohalides was studied. We found that pyridine hydrohalides effectively activate the reaction of tralkyl phosphites with various C=X electrophiles: aldehydes, ketones, ketophosphonates, aldimines, ketimines, isocyanates, isothiocyanates, and activated

  在胺和苯胺​​氢卤化物存在下，研究了亚磷酸三烷基酯与C = X亲电试剂（醛，酮，酮膦酸酯，醛亚胺，酮亚胺，异氰酸酯，异硫氰酸酯和活化烯烃）的反应。我们发现吡啶氢卤化物有效地激活了亚磷酸三烷基酯与各种C = X亲电试剂的反应：醛，酮，酮膦酸酯，醛亚胺，酮亚胺，异氰酸酯，异硫氰酸酯和活化的烯烃。特别高的活性显示出吡啶氢碘化物。该反应是合成羟基膦酸酯，氨基膦酸酯，氨基甲酰基膦酸酯，氨基甲酰基硫代膦酸酯和亚甲基双膦酸酯的便利方法。
• Agents for use on skin and/or hair containing quadruply substituted cyclohexene compounds
  申请人：Wolber Rainer

  公开号：US20070189984A1

  公开（公告）日：2007-08-16

  The invention relates to agents for use on skin or hair, particularly for increasing skin tanning and the synthesis of melanin in skin or hair. The invention contains, in particular, cosmetic or dermatological preparations containing quadruply substituted cyclohexene compounds. The use of the preparations leads to the induction and intensification of the tanning mechanisms of skin, the intensification of hair color and thus also to an intensification of the skin's and hair's intrinsic protection.

  该发明涉及用于皮肤或头发的药剂，特别是用于增加皮肤晒黑和促进皮肤或头发中黑色素合成的药剂。该发明包含特别是含有四次取代环己烯化合物的化妆品或皮肤科制剂。使用这些制剂可以诱导和加强皮肤晒黑机制，加强头发颜色，从而也加强皮肤和头发的固有保护。
• ——
  作者：E. A. Dikusar、N. G. Kozlov、K. L. Moiseichuk、A. P. Yuvchenko

  DOI：10.1023/a:1013175911137

  日期：——

  A method was developed for preparation of alkynyl peroxides from terpene and steroid aldehydes and ketones by reaction of lithium peroxyacetylides with the corresponding aldehydes and ketones followed by treating the intermediate lithium alcoholates with acyl chlorides.
• Tutorskaya, O. O.; Miropol'skaya, M. A.; Samokhvalov, G. I., Journal of Organic Chemistry USSR (English Translation), 1991, vol. 27, # 7.1, p. 1237 - 1240
  作者：Tutorskaya, O. O.、Miropol'skaya, M. A.、Samokhvalov, G. I.

  DOI：——

  日期：——
• Tutorskaya, O. O.; Miropol'skaya, M. A.; Filippova, T. M., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 467 - 471
  作者：Tutorskaya, O. O.、Miropol'skaya, M. A.、Filippova, T. M.、Samokhvalov, G. I.

  DOI：——

  日期：——