(1R)-4-ethyl-3,5,5-trimethylcyclohex-3-en-1-ol | 1027062-81-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (1R)-4-ethyl-3,5,5-trimethylcyclohex-3-en-1-ol
• CAS: 1027062-81-2
• 化学式: C₁₁H₂₀O
• 分子量: 168.279
• InChiKey: VGBHQQGCQYJFAE-SECBINFHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (1R)-4-ethyl-3,5,5-trimethylcyclohex-3-en-1-ol 在 吡啶 、 间氯过氧苯甲酸 作用下， 生成 [(1S,3S,6R)-6-ethyl-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl] acetate
  参考文献：
  名称：

  Stereoselective rearrangement of 5,6-epoxy carotenoid model compounds

  摘要：

  通过路易斯酸促进的 5,6-epoxy 类胡萝卜素环氧化物端基的立体选择性重排，获得了具有新型无环四取代烯烃和环戊基端基的类胡萝卜素。

  DOI：

  10.1039/p19960001337
• 作为产物：
  描述：

  Acetic acid (1R,5R)-3,3,5-trimethyl-4-[2-oxo-eth-(Z)-ylidene]-cyclohexyl ester 在 吡啶 、 sodium tetrahydroborate 、 lithium aluminium tetrahydride 、 hydroxy(triphenyl)silane,oxovanadium 、 苯甲酸 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 、 xylene 为溶剂， 反应 13.0h， 生成 (1R)-4-ethyl-3,5,5-trimethylcyclohex-3-en-1-ol
  参考文献：
  名称：

  Yamano, Yumiko; Tode, Chisato; Ito, Masayoshi, Journal of the Chemical Society. Perkin transactions I, 1998, # 16, p. 2569 - 2581

  摘要：

  DOI：

文献信息

• Plant growth promoters and methods of using them
  申请人：KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

  公开号：US10888090B2

  公开（公告）日：2021-01-12

  New plant growth regulators, including compounds and compositions, and methods of use including for promoting root growth. The compounds are carotenoid oxidation products, and a preferred example is 3-OH-β-apo-13-Carotenone. A method comprising promoting the growth of at least one plant with use of an effective amount of at least one composition comprising an effective amount of at least one compound which is represented by A-B-C, wherein B is a bivalent polyene moiety, A is a monovalent moiety linked to B by a six-membered carbon ring, wherein the ring has at least one substituent linked to the ring by an oxygen atom, and C is a monovalent moiety linked to B by a carbonyl group. Synergistic effects can be used with combinations of compounds.

  新型植物生长调节剂，包括用于促进根系生长的化合物和组合物以及使用方法。这些化合物是类胡萝卜素的氧化产物，一个优选的例子是 3-OH-β-apo-13-Carotenone 。一种方法，包括使用有效量的至少一种组合物促进至少一种植物的生长，该组合物包含有效量的至少一种化合物，该化合物由 A-B-C 表示，其中 B 是二价多烯分子，A 是通过六元碳环与 B 连接的一价分子，其中该环具有至少一个通过氧原子与该环连接的取代基，C 是通过羰基与 B 连接的一价分子。化合物组合可产生协同效应。
• PLANT GROWTH PROMOTERS AND METHODS OF USING THEM
  申请人：KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

  公开号：US20180184651A1

  公开（公告）日：2018-07-05

  New plant growth regulators, including compounds and compositions, and methods of use including for promoting root growth. The compounds are carotenoid oxidation products, and a preferred example is 3-OH-β-apo-13-Carotenone. A method comprising promoting the growth of at least one plant with use of an effective amount of at least one composition comprising an effective amount of at least one compound which is represented by A-B-C, wherein B is a bivalent polyene moiety, A is a monovalent moiety linked to B by a six-membered carbon ring, wherein the ring has at least one substituent linked to the ring by an oxygen atom, and C is a monovalent moiety linked to B by a carbonyl group. Synergistic effects can be used with combinations of compounds.