二苯并[a,c]吖啶 | 215-62-3

• 物质功能分类: 分析化学 - 标准品 - 挥发性有机化合物(VOCs)
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: 二苯并[a,c]吖啶
• 中文别名: 二苯并[A,C]吖啶
• 英文名称: dibenzo[a,c]acridine
• 英文别名: 1,2,3,4-dibenzacridine；dibenzoacridine；Dibenz-acridin；Dibenz[a,c]acridine；phenanthro[9,10-b]quinoline
• CAS: 215-62-3
• 化学式: C₂₁H₁₃N
• 分子量: 279.341
• InChiKey: GUZBPGZOTDAWBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2933990090

反应信息

• 作为产物：
  描述：

  10-(methoxyimino)phenanthren-9-one 在 lithium hydroxide 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 312.0h， 生成 二苯并[a,c]吖啶
  参考文献：
  名称：

  Nicolaides, Demetrios N.; Litinas, Konstantinos E.; Papageorgiou, Georgios K., Journal of Heterocyclic Chemistry, 1991, vol. 28, # 1, p. 139 - 143

  摘要：

  DOI：

文献信息

• Cobalt-Catalyzed Electrophilic Aminations with Anthranils: An Expedient Route to Condensed Quinolines
  作者：Jie Li、Eric Tan、Niklas Keller、Yi-Hung Chen、Peter M. Zehetmaier、Andreas C. Jakowetz、Thomas Bein、Paul Knochel

  DOI：10.1021/jacs.8b11466

  日期：2019.1.9

  The reaction of various organozinc pivalates with anthranils provides anilines derivatives, which cyclize under acidic conditions providing condensed quinolines. Using alkenylzinc pivalates, electron-rich arylzinc pivalates or heterocyclic zinc pivalates produces directly the condensed quinolines of which several structures belong to new heterocyclic scaffolds. These N-heterocycles are of particular

  各种有机锌新戊酸酯与邻氨基苯甲酸酯的反应提供苯胺衍生物，其在酸性条件下环化提供缩合喹啉。使用烯基新戊酸锌、富电子芳基新戊酸锌或杂环新戊酸锌直接产生稠合喹啉，其中几种结构属于新的杂环支架。由于具有最佳的空穴能带排列和大的带隙，这些 N-杂环特别适用于有机发光二极管，因为它们具有高光致发光量子产率和长激子寿命，以及甲基铵碘化铅钙钛矿太阳能电池中的空穴传输材料.
• [EN] ORGANIC ELECTRONIC DEVICE COMPRISING AN ORGANIC SEMICONDUCTOR LAYER<br/>[FR] DISPOSITIF ÉLECTRONIQUE ORGANIQUE COMPRENANT UNE COUCHE SEMI-CONDUCTRICE ORGANIQUE
  申请人：NOVALED GMBH

  公开号：WO2018215348A1

  公开（公告）日：2018-11-29

  The present invention relates to a compound of formula 1 and an organic electronic device comprising an organic semiconductor layer, wherein at least one organic semiconductor layer comprises a compound of formula (1), wherein L1 has the formula (2) and L2 has the formula (3), wherein L1 and L2 are bonded at "*" via a single bond independently to the same or different arylene groups or heteroarylenes group of Ar1; and wherein X1, X2 are independently selected from O, S and Se; Ar1 is selected from substituted or unsubstituted C20 to C52 arylene or C14 to C64 heteroarylene, wherein the substituent of the substituted C20 to C52 arylene or C14 to C64 heteroarylene are independently selected from C1 to C12 alkyl, C1 to C12 alkoxy, CN, halogen, OH, C6 to C25 aryl and C2 to C21 heteroaryl; R1, R2 are independently selected from substituted or unsubstituted C1 to C16 alkyl, wherein the substituent of substituted C1 to C16 alkyl is selected from C6 to C18 arylene or C2 to C12 heteroarylene; R3, R4 are independently selected from substituted or unsubstituted C1 to C16 alkyl, substituted or unsubstituted C6 to C18 arylene, C2 to C20 heteroarylene, wherein the substituent of substituted C1 to C16 alkyl, the substituent of the substituted C6 to C18 arylene, C2 to C20 heteroarylene are independently selected from C6 to C18 arylene or C2 to C12 heteroarylene; n is selected from 1 to 5, wherein n is an integer number.

  本发明涉及一种化合物的化学式1和包括有机半导体层的有机电子器件，其中至少一个有机半导体层包括一个化合物的化学式（1），其中L1具有化学式（2），L2具有化学式（3），其中L1和L2通过单键独立地与Ar1的相同或不同的芳基或杂芳基通过“*”键合；其中X1、X2独立选择自O、S和Se；Ar1选择自取代或未取代的C20至C52芳基或C14至C64杂芳基，其中取代的C20至C52芳基或C14至C64杂芳基的取代基独立选择自C1至C12烷基、C1至C12烷氧基、CN、卤素、OH、C6至C25芳基和C2至C21杂芳基；R1、R2独立选择自取代或未取代的C1至C16烷基，其中取代的C1至C16烷基的取代基选择自C6至C18芳基或C2至C12杂芳基；R3、R4独立选择自取代或未取代的C1至C16烷基，取代或未取代的C6至C18芳基，C2至C20杂芳基，其中取代的C1至C16烷基、取代的C6至C18芳基、C2至C20杂芳基的取代基独立选择自C6至C18芳基或C2至C12杂芳基；n选择自1至5，其中n为整数。
• METHOD FOR PRODUCING CYCLOMETALATED IRIDIUM COMPLEX
  申请人：TANAKA KIKINZOKU KOGYO K.K.

  公开号：US20180362565A1

  公开（公告）日：2018-12-20

  The present invention provides a method for producing a cyclometalated iridium complex by use of a non-chlorine iridium raw material. The method for producing a cyclometalated iridium complex includes producing a cyclometalated iridium complex by reacting a raw material including an iridium compound with an aromatic heterocyclic bidentate ligand capable of forming an iridium-carbon bond, the raw material being non-halogenated iridium having a conjugated base of a strong acid as a ligand. Here, the non-halogenated iridium is preferably one containing a conjugated base of a strong acid having a pKa of 3 or less as a ligand.

  本发明提供了一种利用非氯化铱原料生产环金属化铱配合物的方法。生产环金属化铱配合物的方法包括通过将包含铱化合物的原料与能够形成铱-碳键的芳香杂环双齿配体反应来生产环金属化铱配合物，所述原料是非卤化铱，其具有强酸的共轭碱作为配体。在这里，非卤化铱最好是含有pKa值为3或更低的强酸的共轭碱作为配体的铱。
• Selective Synthesis of 2-Indolyl-3-oxoindolines or 2-(2-Aminophenyl)quinolines through Cu(II)- or Bi(III)-Catalyzed Tunable Dimerizations of 2-Alkynylanilines
  作者：Ruixue Jia、Bin Li、Xinying Zhang、Xuesen Fan

  DOI：10.1021/acs.orglett.0c02323

  日期：2020.9.4

  intermolecular N-nucleophilic addition between two 2-alkynylaniline molecules to give an enamine intermediate followed by its intramolecular C-nucleophilic addition/annulation. Notable features of these new methods include easily obtainable substrates, economical catalysts and oxidant, controllable selectivity, and high versatility toward diverse products.

  通过2-炔基苯胺的可调二聚作用，提出了2-吲哚基-3-氧代吲哚啉或2-（2-氨基苯基）喹啉的新颖和选择性合成。从机理上讲，2-吲哚基-3-氧代吲哚啉的形成涉及Cu（OAc）2 / O 2促进的2-炔基苯胺分子内环化反应，以产生所需的吲哚和3 H-吲哚-3-酮中间体，然后进行二氢吲哚基化。 3 H-吲哚-3-一。另一方面，据信2-（2-氨基苯基）喹啉的形成通过Bi（OTf）3 / MesCO 2进行。在两个2-炔基苯胺分子之间进行H催化的分子间N-亲核加成，生成烯胺中间体，然后进行分子内C-亲核加成/环化反应。这些新方法的显着特征包括易于获得的底物，经济的催化剂和氧化剂，可控的选择性以及对多种产品的高度通用性。
• Site-selective synthesis of functionalized dibenzo[<i>f</i>,<i>h</i>]quinolines and their derivatives involving cyclic diaryliodonium salts <i>via</i> a decarboxylative annulation strategy
  作者：Shuai Yang、Wenkai Hua、Yanqi Wu、Tao Hu、Feng Wang、Xingxian Zhang、Fengzhi Zhang

  DOI：10.1039/c8cc00300a

  日期：——

  report a site-selective synthesis of functionalized dibenzo[f,h]quinolines and their derivatives, which could be used as OLED materials. The key step is the double cross coupling reaction between the 2-chloropyridinyl acids and the cyclic diaryliodonium salts, where the carboxylic acid was unprecedentedly employed as both a traceless directing group and a functional handle in a one-pot atom- and step-economical

  在这里我们报告功能化的二苯并[ f，h ]喹啉及其衍生物的位点选择性合成，可以用作OLED材料。关键步骤是2-氯吡啶基酸与环状二芳基碘鎓盐之间的双交叉偶联反应，其中羧酸在单锅原子经济和一步经济的工艺中被前所未有地用作无痕导向基团和功能性手柄。