(η(6)-p-cymene)RuCl2(3-phenylpropyldiphenylphosphine) | 209625-69-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (η(6)-p-cymene)RuCl2(3-phenylpropyldiphenylphosphine)
• 英文别名: [RuCl2(η6-p-cumene)((3-phenylpropyl)diphenylphosphine)]；dichlororuthenium;diphenyl(3-phenylpropyl)phosphane;1-methyl-4-propan-2-ylbenzene
• CAS: 209625-69-4
• 化学式: C₃₁H₃₅Cl₂PRu
• 分子量: 610.569
• InChiKey: HQGZJRARCWMTJP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η(6)-p-cymene)RuCl2(3-phenylpropyldiphenylphosphine) 以 氯苯 为溶剂， 以50%的产率得到RuCl2(PPh2(CH2)3-η(6)-C6H5)
  参考文献：
  名称：

  Synthesis and structure of a chelating arene–ruthenium complex [RuCl2(PPh2(CH2)3-η6-C6H5)]

  摘要：

  The synthesis of an arene-phosphine ligand, Ph2P(CH2)(3)Ph, has provided a route into a new chelating arene-phosphine-ruthenium complex, [RuCl2(PPh2(CH2)(3)-eta(6)-C6H5)] which has been structurally characterized. This complex can be made by thermolysis of [(eta(6)-MeC6H4CHMe2)RuCl2(PPh2(CH2)(3)Ph)] or electrochemically utilizing the formation of the labile seventeen-electron ruthenium(III) species [(eta(6)-MeC6H4CHMe2)RuCl2(PPh2(CH2)(3)Ph)](+) which can be converted in good yield into [RuCl2(PPh2(CH2)(3)-eta(6)-C6H5)]. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00750-x
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 (3-苯基丙基)二苯基膦 以 二氯甲烷 为溶剂， 以83%的产率得到(η(6)-p-cymene)RuCl2(3-phenylpropyldiphenylphosphine)
  参考文献：
  名称：

  Synthesis and structure of a chelating arene–ruthenium complex [RuCl2(PPh2(CH2)3-η6-C6H5)]

  摘要：

  The synthesis of an arene-phosphine ligand, Ph2P(CH2)(3)Ph, has provided a route into a new chelating arene-phosphine-ruthenium complex, [RuCl2(PPh2(CH2)(3)-eta(6)-C6H5)] which has been structurally characterized. This complex can be made by thermolysis of [(eta(6)-MeC6H4CHMe2)RuCl2(PPh2(CH2)(3)Ph)] or electrochemically utilizing the formation of the labile seventeen-electron ruthenium(III) species [(eta(6)-MeC6H4CHMe2)RuCl2(PPh2(CH2)(3)Ph)](+) which can be converted in good yield into [RuCl2(PPh2(CH2)(3)-eta(6)-C6H5)]. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00750-x

文献信息

• Synthesis, structure and redox behaviour of tethered arene–ruthenium(II) complexes
  作者：Martin A. Bennett、Alison J. Edwards、Joanne R. Harper、Tetyana Khimyak、Anthony C. Willis

  DOI：10.1016/s0022-328x(01)00801-4

  日期：2001.6

  Tethered arene-ruthenium complexes [RuCl2eta (1):eta (6)-Me2P(CH2)(3)C6H5}], [RuCl2eta (1):eta (6)-Ph2PCH2SiMe2C6H5}] and [RuCl2eta (1):eta (6)-Ph2P(CH2)(3)(aryl)}] (aryl = 2,4,6-C6H2Me3 C6Me5) have been prepared by thermal displacement of methyl o-toluate from the appropriate P-donor derivatives of [RuCl2(eta (6)-1,2-MeC6H4CO2Me)](2) and their structures determined by X-ray studies. The tethered complexes undergo reversible one-electron oxidation by cyclic voltammetry; the half-wave potentials are in the range 1.10-1.34 V versus Ag / AgCl and decrease with increasing methyl substitution on the arene. (C) 2001 Elsevier Science B.V. All rights reserved.