benzenesulfinic anhydride | 13086-77-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzenesulfinic anhydride
• 英文别名: benzenesulfinic acid-anhydride；Benzolsulfinsaeure-anhydrid；benzenesulfinyl benzenesulfinate
• CAS: 13086-77-6
• 化学式: C₁₂H₁₀O₃S₂
• 分子量: 266.342
• InChiKey: LPKIXYAMGCOWED-UHFFFAOYSA-N

物化性质

• 熔点：
  66-67 °C
• 沸点：
  464.1±28.0 °C(Predicted)
• 密度：
  1.49±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  81.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  benzenesulfinic anhydride 生成 二苯基亚砜 、 苯磺酸
  参考文献：
  名称：

  Knoevenagel; Polack, Chemische Berichte, 1908, vol. 41, p. 3330

  摘要：

  DOI：
• 作为产物：
  描述：

  乙酸酐 、 溶剂黄146 、 苯亚磺酸 在 硫酸 作用下， 生成 benzenesulfinic anhydride
  参考文献：
  名称：

  Knoevenagel; Polack, Chemische Berichte, 1908, vol. 41, p. 3330

  摘要：

  DOI：
• 作为试剂：
  描述：

  (2S)-N-[[(1R,2S,10R,12R,13S)-12-cyano-19-hydroxy-7,18-dimethoxy-6,17,21-trimethyl-5,8-dioxo-11,21-diazapentacyclo[11.7.1.02,11.04,9.015,20]henicosa-4(9),6,15(20),16,18-pentaen-10-yl]methyl]-2-(phenylcarbamothioylamino)propanamide 在 4-二甲氨基吡啶 、 三甲基氯硅烷 、 三氟甲磺酸酐 、 palladium 10% on activated carbon 、 benzenesulfinic anhydride 、 氢气 、 对甲苯磺酸 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 、 N,N-二异丙基乙胺 、 lithium hydroxide 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 、 水 、 二甲基亚砜 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， -10.0~100.0 ℃ 、1.0 MPa 条件下， 反应 48.34h， 生成 ET594
  参考文献：
  名称：

  一种曲贝替定的制备方法及其中间体

  摘要：

  本发明提供了一种曲贝替定的新的制备方法，该方法由蕃红菌素(safracin B)为起始原料经过一系列反应合成曲贝替定，该方法原料易得，合成步骤少，并且不使用剧毒的有机锡试剂，安全，低廉，具有较大的工业化应用价值。

  公开号：

  CN107522698B

文献信息

• PHTHALOCYANINE CRYSTAL, ELECTROPHOTOGRAPHIC PHOTORECEPTOR UTILIZING THE SAME, ELECTROPHOTOGRAPHIC PHOTORECEPTOR CARTRIDGE AND IMAGE FORMING APPARATUS
  申请人：Mitsubishi Chemical Corporation

  公开号：EP1997857A1

  公开（公告）日：2008-12-03

  Provided is an excellent phthalocyanine crystal having high sensitivity and little fluctuation in sensitivity for a humidity change in a use environment and applicable to the martial for solar battery, electronic paper, electrophotographic photoreceptor, etc. Namely, phthalocyanine crystal obtained by bringing a phthalocyanine crystal precursor into contact with an aromatic aldehyde compound to convert the crystal form. Also, provided is an electrophotographic photoreceptor that not only exhibits high sensitivity but also has little fluctuation in sensitivity for a humidity change in a use environment. Further, provided is an electrophotographic photoreceptor cartridge and an image-forming device, both of which can produce a stable quality images for a humidity change in a use environment by using the electrophotographic photoreceptor.

  本发明提供了一种优异的酞菁晶体，其灵敏度高，对使用环境中的湿度变化灵敏度波动小，适用于太阳能电池、电子纸、电子照相感光元件等武材。酞菁晶体是通过将酞菁晶体前体与芳香醛化合物接触转换晶体形式而获得的。此外，还提供了一种电致发光感光元件，它不仅具有高灵敏度，而且在使用环境湿度变化时灵敏度波动很小。此外，还提供了一种电致发光感光器盒和一种图像形成装置，这两种装置均可通过使用该电致发光感光器在使用环境湿度变化时生成质量稳定的图像。
• Phthalocyanine crystal, and electrophotographic photoreceptor, electrophotographic photoreceptor cartridge and image-forming device using the same
  申请人：Mitsubishi Chemical Corporation

  公开号：US10095135B2

  公开（公告）日：2018-10-09

  Provided is an excellent phthalocyanine crystal having high sensitivity and little fluctuation in sensitivity for a humidity change in a use environment and applicable to the martial for solar battery, electronic paper, electrophotographic photoreceptor, etc. Namely, phthalocyanine crystal obtained by bringing a phthalocyanine crystal precursor into contact with an aromatic aldehyde compound to convert the crystal form. Also, provided is an electrophotographic photoreceptor that not only exhibits high sensitivity but also has little fluctuation in sensitivity for a humidity change in a use environment. Further, provided is an electrophotographic photoreceptor cartridge and an image-forming device, both of which can produce a stable quality images for a humidity change in a use environment by using the electrophotographic photoreceptor.

  本发明提供了一种优异的酞菁晶体，其灵敏度高，对使用环境中的湿度变化灵敏度波动小，适用于太阳能电池、电子纸、电子照相感光元件等武材。酞菁晶体是通过将酞菁晶体前体与芳香醛化合物接触转换晶体形式而获得的。此外，还提供了一种电致发光感光元件，它不仅具有高灵敏度，而且在使用环境湿度变化时灵敏度波动很小。此外，还提供了一种电致发光感光器盒和一种图像形成装置，这两种装置均可通过使用该电致发光感光器在使用环境湿度变化时生成质量稳定的图像。
• La transformation d'indolines en indoles et d'autres reactions apparentees
  作者：Derek H.R Barton、Xavier Lusinchi、Pierre Milliet

  DOI：10.1016/s0040-4039(00)85756-1

  日期：1982.1
• PHTHALOCYANINE CRYSTAL, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR, ELECTROPHOTOGRAPHIC PHOTORECEPTOR CARTRIDGE AND IMAGE-FORMING DEVICE USING THE SAME
  申请人：Wada Mitsuo

  公开号：US20100232830A1

  公开（公告）日：2010-09-16

  Provided is an excellent phthalocyanine crystal having high sensitivity and little fluctuation in sensitivity for a humidity change in a use environment and applicable to the martial for solar battery, electronic paper, electrophotographic photoreceptor, etc. Namely, phthalocyanine crystal obtained by bringing a phthalocyanine crystal precursor into contact with an aromatic aldehyde compound to convert the crystal form. Also, provided is an electrophotographic photoreceptor that not only exhibits high sensitivity but also has little fluctuation in sensitivity for a humidity change in a use environment. Further, provided is an electrophotographic photoreceptor cartridge and an image-forming device, both of which can produce a stable quality images for a humidity change in a use environment by using the electrophotographic photoreceptor.
• PHTHALOCYANINE CRYSTAL, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR, ELECTROPHOTOGRAPHIC PHOTORECEPTOR CARTRIDGE AND IMAGE-FORMING DEVICE USING THE SAME
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20160109816A1

  公开（公告）日：2016-04-21

  Provided is an excellent phthalocyanine crystal having high sensitivity and little fluctuation in sensitivity for a humidity change in a use environment and applicable to the martial for solar battery, electronic paper, electrophotographic photoreceptor, etc. Namely, phthalocyanine crystal obtained by bringing a phthalocyanine crystal precursor into contact with an aromatic aldehyde compound to convert the crystal form. Also, provided is an electrophotographic photoreceptor that not only exhibits high sensitivity but also has little fluctuation in sensitivity for a humidity change in a use environment. Further, provided is an electrophotographic photoreceptor cartridge and an image-forming device, both of which can produce a stable quality images for a humidity change in a use environment by using the electrophotographic photoreceptor.