tris(acetylacetonato)thulium(III)

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tris(acetylacetonato)thulium(III)
• 英文别名: thulium triacetylacetonate；Tm(III)(acetylacetonate)3；thulium acetylacetonate；Tm(acetylacetonate)₃；Tm(acac)₃；Thulium-2,4-Pentanedionate；(Z)-4-oxopent-2-en-2-olate;thulium(3+)
• 化学式: C₁₅H₂₁O₆Tm
• 分子量: 466.262
• InChiKey: ASFMKHGVRGERPB-LNTINUHCSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -0.48
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  120
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  tris(acetylacetonato)thulium(III) 、 2,3-二氰基-5,6-二苯基吡嗪 在 sodium methylate 、 尿素 作用下， 以 苯甲腈 为溶剂， 以87%的产率得到acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)thulium(III)
  参考文献：
  名称：

  Synthesis and properties of lanthanide complexes with tetrapyrazinoporphyrazine and its substituted derivatives

  摘要：

  Reactions of dicyanopyrazine and its tert-butyl-, diphenyl-, and dipyridyl-substituted derivatives with erbium, thulium, ytterbium, and lutetium chlorides, acetates, and acetylacetonates gave the corresponding tetrapyrazinoporphyrazine metal complexes which were characterized by elemental analyses, and IR, H-1 NMR, and electronic absorption spectra. The stability of the complexes to thermooxidative decomposition in air was also studied.

  DOI：

  10.1134/s1070363207110175
• 作为产物：
  描述：

  tris(acetylacetonato)thulium(III) trihydrate 在 乙酰丙酮 作用下， 以 neat (no solvent) 为溶剂， 生成 tris(acetylacetonato)thulium(III)
  参考文献：
  名称：

  Production of volatile trisacetylacetonates of rare-earth elements by heating their hydrates

  摘要：

  DOI：

  10.1007/bf00948969

文献信息

• Electrochemistry of lanthanoid(III) complexes in dimethyl sulfoxide in the presence of n-Bu4N(acac) and n-Bu4N(dibm)
  作者：Akio Iwase、Yoshinori Araki、Reiko Takahashi

  DOI：10.1016/0013-4686(90)87070-i

  日期：1990.11

  lanthanoid Ln(III) complexes was investigated in Me2SO including n-Bu4N(acac) and n-Bu4N(dibm) as ligands (where acac is the acetylacetonate anion and dibm is the diisobutrylmethanate anion). Reversible one electron reduction waves corresponding to Ln(III) complexes→Ln(II) complexes were observed in the concentration range of 5–20 mM of the ligands, including 1 mM lanthanoid perchlorates and 0.1 M TEAP

  镧系LN（III）络合物的电化学行为在我研究了2 SO包括Ñ -Bu 4 N（ACAC）和Ñ -Bu 4 N（dibm）作为配体（其中ACAC是乙酰丙酮化物阴离子和dibm是diisobutrylmethanate阴离子） 。在5–20 mM的配体浓度范围内观察到了对应于Ln（III）配合物→Ln（II）配合物的可逆的一个电子还原波，包括1 mM镧系高氯酸盐和0.1 M TEAP。在存在5 mM配体的情况下，在0.1 M TEAP中，镧系元素络合物的半波电势为sce -1.66至-2.61 V ，具体取决于镧系元素（III）离子。
• 一种二茂铁修饰的稀土金属卟啉光催化剂、制备方法及其应用
  申请人：西安石油大学

  公开号：CN116731086A

  公开（公告）日：2023-09-12

  本发明公开了一种二茂铁修饰的稀土金属卟啉光催化剂、制备方法及其应用。本发明首先通过以四羟基卟啉、二茂铁甲酸为原料，苯为溶剂，进行酯化反应，得到二茂铁酯基卟啉配体；接着以稀土乙酰丙酮配合物和二茂铁酯基卟啉配体为原料，1,2,4‑三氯苯为溶剂，在保护性气体氛围下进行配位反应，制备了二茂铁修饰的稀土金属卟啉光催化剂；该二茂铁修饰的稀土金属卟啉光催化剂应用于催化二氧化碳和环氧化物进行环加成反应时表现出优异的催化效果，同时获得了较高产率的环状碳酸酯。
• Synergism by sublimation of volatile lanthanide β-diketonates
  作者：Natalia P Kuzmina、Larissa I Martynenko、Nikolai V Chugarov、Irina G Zaitseva、Andrei N Grigoriev、Andrei N Yakushevich

  DOI：10.1016/s0925-8388(00)01047-1

  日期：2000.8

  The synergistic effect by sublimation manifests itself in an increase in the volatility of nonvolatile or slightly volatile compounds in the presence of highly volatile agents. In this study, manifestations of the synergistic effect are demonstrated by the evaporation of mixed ligand complexes, derivatives of lanthanide acetylacetonates and neutral organic ligands, and by evaporation of the following mixtures: yttrium and zirconium acetylacetonates, lanthanum and nickel dipivaloylmethanates and acetylacetonates, and lanthanum and aluminum acetylacetonates. (C) 2000 Elsevier Science S.A. All rights reserved.
• LANTHANIDE COMPLEXES WITH ACETYLACETONATE AND 5,10,15,20-TETRA[<i>PARA</i>-(4-FLUOROBENZOYLOXY)-<i>META</i>-METHOXY]PHENYLPORPHYRIN
  作者：Zhi Xin Zhao、Guo Fa Liu

  DOI：10.1081/sim-120003789

  日期：2002.4.29

  Lanthanide complexes of acetylacetonate and 5,10,15,20-tetra [para-(4-fluorobenzoyloxy)-meta-methoxy]phenylporphyrin having the general formula Ln[(FBOMP)(4)P](acac) (where Ln=Er, Tm, Yb; FBOMP=[para-(4-fluorobenzoyloxy)meta-methoxy]phenyl; acac=acetylacetone; P=porphyrin) have been prepared and characterized. A structure is proposed in which one 5,10,15,20-tetra[para-(4-fluorobenzoyloxy)meta-methoxy]porphyrin molecule is coordinated to a rare earth ion in a tetradentate fashion, while one acetylacetonate molecule is coordinated to the same metal ion in a bidentate fashion.
• Synthesis and properties of lanthanide complexes with tetrapyrazinoporphyrazine and its substituted derivatives
  作者：T. A. Lebedeva、V. P. Kulinich、G. P. Shaposhnikov、S. V. Efimova、A. B. Korzhenevskii、O. I. Koifman

  DOI：10.1134/s1070363207110175

  日期：2007.11

  Reactions of dicyanopyrazine and its tert-butyl-, diphenyl-, and dipyridyl-substituted derivatives with erbium, thulium, ytterbium, and lutetium chlorides, acetates, and acetylacetonates gave the corresponding tetrapyrazinoporphyrazine metal complexes which were characterized by elemental analyses, and IR, H-1 NMR, and electronic absorption spectra. The stability of the complexes to thermooxidative decomposition in air was also studied.