十三烷醇硫酸酯钠 | 3026-63-9

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 中文名称: 十三烷醇硫酸酯钠
• 英文名称: sodium tridecyl sulfate
• 英文别名: sodium tridecyl ether sulfate；sodium;tridecyl sulfate
• CAS: 3026-63-9
• 化学式: C₁₃H₂₇O₄S*Na
• 分子量: 302.411
• InChiKey: HQCFDOOSGDZRII-UHFFFAOYSA-M

物化性质

• 熔点：
  185-189℃

计算性质

• 辛醇/水分配系数(LogP)：
  0.78
• 重原子数：
  19
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

ADMET

毒理性

• 人类毒性摘录

ME(CH2)NSO3NA（其中N=5, 7, 9-17）导致胆固醇从培养的人类细胞中洗脱的潜力随着碳原子数增加至N=12而增加，十二烷基硫酸钠。

THE POTENTIAL OF ME(CH2)NSO3NA (WHERE N= 5, 7, 9-17) TO CAUSE CHOLESTEROL-ELUTION FROM CULTURED HUMAN CELLS INCR WITH THE NUMBER OF CARBONS UP TO N= 12, SODIUM TRIDECYL SULFATE.

来源:Hazardous Substances Data Bank (HSDB)

毒理性

• 非人类毒性摘录

ME(CH2)NSO3NA（其中N=5, 7, 9-17）对兔子和豚鼠皮肤的潜在刺激性，随着碳数增加至N=12，蛋白质从皮肤中洗脱和细胞毒性增加，十二烷基硫酸钠。

THE POTENTIAL OF ME(CH2)NSO3NA (WHERE N= 5, 7, 9-17) TO CAUSE SKIN IRRITATION ON RABBITS & GUINEA PIGS, PROTEIN-ELUTION FROM SKIN & CELL TOXICITY INCR WITH THE NUMBER OF CARBONS UP TO N= 12, SODIUM TRIDECYL SULFATE.

来源:Hazardous Substances Data Bank (HSDB)

安全信息

• 危险类别码：
  R36/37/38
• 海关编码：
  2920909090
• 安全说明：
  S26,S36
• 储存条件：
  室温

SDS

---

Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : Tridecyl sulfate, sodium salt
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

---

Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Eye irritation (Category 2)
Classification according to EU Directives 67/548/EEC or 1999/45/EC
Irritating to eyes.
Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Warning
Hazard statement(s)
H319 Causes serious eye irritation.
Precautionary statement(s)
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard none
Statements
According to European Directive 67/548/EEC as amended.
Hazard symbol(s)
R-phrase(s)
R36 Irritating to eyes.
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
Other hazards - none

---

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : C13H28O4S
Molecular Weight : 302,41 g/mol
Component Concentration
Tridecyl sulfate, sodium salt
-

---

Section 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available

---

Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Sulphur oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

---

Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Avoid breathing dust.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

---

Section 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire
protection.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Specific end uses
no data available

---

Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).

---

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing no data available
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- no data available
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

---

Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available

---

Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin
May be harmful if absorbed through skin. May cause skin irritation.
Eyes Causes serious eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: Not available

---

Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
no data available

---

Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

---

Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

---

---

SECTION 15 - REGULATORY INFORMATION
N/A

---

SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  manganese (II) acetate tetrahydrate 、 十三烷醇硫酸酯钠 、 2-(2-benzimidazolyl)-4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  基于层状结构中的二维Mn（II）-亚硝酰基氮氧化物骨架的分子磁体

  摘要：

  摘要一系列分子式为{[Mn 2 II（NITBzIm）3]（X）} n [X = ClO4（1）或CnH2n + 1SO4的层状化合物，n = 10（2），11（3），12（ 4），13（5），14（6），18（7）]通过2-（2-苯并咪唑基）-4,4,5,5-四甲基咪唑啉基-1-氧-3-氧化物的反应而获得通过在甲醇中加入乙酸锰（II）并依次加入高氯酸钠或正烷基硫酸盐来制备亚硝基硝基氧自由基（NITBzImH）。所有化合物的晶体结构已通过Rietveld对其X射线粉末衍射图进行了细化处理，使用先前报道的由2-（2-咪唑基）获得的类似化合物{[Mn 2 II（NITIm）3]（ClO 4）} n来建立。 ）-4,4,5,5-四甲基咪唑啉基-1-氧-3-氧化物（NITImH）作为模型。因此，所有化合物均包含式{[Mn 2 II（NITBzIm）3] +} n的2D阳离子骨架，表现出具有交替的锰

  DOI：

  10.1016/j.ica.2008.03.109
• 作为产物：
  描述：

  十三烷醇 在 氯磺酸 、 sodium hydroxide 作用下， 生成 十三烷醇硫酸酯钠
  参考文献：
  名称：

  烷基硫酸盐胶束中链长对球-杆过渡的影响

  摘要：

  DOI：

  10.1021/j100230a032
• 作为试剂：
  描述：

  1-氢过氧基乙基苯 在 十三烷醇硫酸酯钠 作用下， 以87%的产率得到苯酚
  参考文献：
  名称：

  Method of phenol and carbonyl production

  摘要：

  本发明描述了一种高产率和简化的方法，通过芳香族过氧化物的催化分解来制备酚和羰基化合物，如乙醛。合成过程通常包括在正气氛下和高温（80至100°C）下，在存在催化剂量（0.01-0.8质量百分比（%））的情况下，分解过氧化物，催化剂为具有以下结构的阴离子表面活性剂R—OSO3M或R—OP3Z2，其中“M”为Na或K，“Z”为Na、K或含有十至十四个碳（C10-C14）的烷基基团，而“R”为由十至十四个碳（C10-C14）组成的烷基基团。

  公开号：

  US20040082817A1

文献信息

• BITTER TASTE MODIFIERS INCLUDING SUBSTITUTED 1-BENZYL-3-(1-(ISOXAZOL-4-YLMETHYL)-1H-PYRAZOL-4-YL)IMIDAZOLIDINE-2,4-DIONES AND COMPOSITIONS THEREOF
  申请人：SENOMYX, INC.

  公开号：US20160376263A1

  公开（公告）日：2016-12-29

  The present invention includes compounds and compositions known to modify the perception of bitter taste, and combinations of said compositions and compounds with additional compositions, compounds, and products. Exemplary compositions comprise one or more of the following: cooling agents; inactive drug ingredients; active pharmaceutical ingredients; food additives or foodstuffs; flavorants, or flavor enhancers; food or beverage products; bitter compounds; sweeteners; bitterants; sour flavorants; salty flavorants; umami flavorants; plant or animal products; compounds known to be used in pet care products; compounds known to be used in personal care products; compounds known to be used in home products; pharmaceutical preparations; topical preparations; cannabis-derived or cannabis-related products; compounds known to be used in oral care products; beverages; scents, perfumes, or odorants; compounds known to be used in consumer products; silicone compounds; abrasives; surfactants; warming agents; smoking articles; fats, oils, or emulsions; and/or probiotic bacteria or supplements.

  本发明涵盖已知用于改变苦味感知的化合物和组合物，以及所述组合物和化合物与额外的组合物、化合物和产品的组合。示例组合物包括以下一种或多种：冷却剂；无活性药物成分；活性药用成分；食品添加剂或食品；调味剂或调味增强剂；食品或饮料产品；苦味化合物；甜味剂；苦味剂；酸味调味剂；咸味调味剂；鲜味调味剂；植物或动物产品；已知用于宠物护理产品中的化合物；已知用于个人护理产品中的化合物；已知用于家用产品中的化合物；制药制剂；局部制剂；大麻衍生或与大麻相关的产品；已知用于口腔护理产品中的化合物；饮料；香味、香水或除臭剂；已知用于消费品中的化合物；硅化合物；磨料；表面活性剂；发热剂；吸烟物品；脂肪、油脂或乳化剂；和/或益生菌或补充剂。
• Method of hydrocarbon stabilization
  申请人：NEUROK LLC

  公开号：US20040082823A1

  公开（公告）日：2004-04-29

  The present invention is directed to a method of providing enhanced molecular stability to hydrocarbons, such as the various oils, lubricants, fuel and rubbers typically used in internal combustion engines. The invention generally comprises inhibiting the liquid phase oxidation of hydrocarbons by atmospheric oxygen at elevated temperatures through the micro-addition of non-toxic of alkyl organic additives. The alkyl organic additives are anionic surface active agents (ASAAs) of the general formula R—OSO 3 M or R—OP 3 Z 2 , where “M” is Na or K, where “Z” is Na, K or an alkyl group containing between ten and fourteen carbons and where “R” is an alkyl group consisting of between six and sixteen carbons. The additives are generally used in quantities from 0.01 to 10 mass percent, at temperatures between 70°-170° C. and in the presence of an aromatic solvent.

  本发明涉及一种提高烃类分子稳定性的方法，例如通常用于内燃机中的各种油、润滑剂、燃料和橡胶。该发明一般包括通过微量添加非毒性的烷基有机添加剂来抑制在高温下烃类液相氧化与大气氧气的反应。这些烷基有机添加剂是一般化学式为R—OSO3M或R—OP3Z2的阴离子表面活性剂(ASAAs)，其中“M”为Na或K，“Z”为Na、K或含有十至十四个碳原子的烷基基团，而“R”是由六至十六个碳原子组成的烷基基团。这些添加剂通常以0.01至10质量百分比的量使用，在70°-170° C温度范围内，并在芳香性溶剂存在的情况下使用。
• COMPOUNDS USEFUL AS MODULATORS OF TRPM8
  申请人：Senomyx, Inc.

  公开号：US20170096418A1

  公开（公告）日：2017-04-06

  The present disclosure relates to compounds which are useful as cooling sensation compounds.

  本公开涉及作为冷感化合物有用的化合物。
• [EN] COMPOSITION FOR INHIBITING MICRO-ORGANISMS<br/>[FR] COMPOSITION D'INHIBITION DE MICRO-ORGANISMES
  申请人：CLARIANT INT LTD

  公开号：WO2019115478A1

  公开（公告）日：2019-06-20

  The present invention relates to a composition for inhibiting micro-organisms, as well as related processes, formulations, concentrates and uses. The composition comprises at least 30 wt.-% compound X, wherein compound X is according to Formula (I) wherein R is an unsaturated hydrocarbon chain having 5 to 13 carbon atoms; and wherein R1 is -H or a C1-6 unsubstituted alkyl moiety, preferably R1 is methyl.

  本发明涉及一种用于抑制微生物的组合物，以及相关的工艺、配方、浓缩物和用途。该组合物包括至少30重量％的化合物X，其中化合物X符合以下化学式(I)，其中R是具有5至13个碳原子的不饱和碳氢链；R1为-H或C1-6未取代烷基基团，最好R1为甲基。
• [EN] COMPOSITION FOR INHIBITING MICRO-ORGANISMS<br/>[FR] COMPOSITION POUR L'INHIBITION DE MICRO-ORGANISMES
  申请人：CLARIANT INT LTD

  公开号：WO2018002100A1

  公开（公告）日：2018-01-04

  The present invention relates to a composition for inhibiting micro-organisms, as well as related processes, formulations, concentrates and uses. The composition comprises at least 30 wt.-% compound X, wherein compound X is according to Formula (I): wherein R is a saturated or unsaturated hydrocarbon chain having seven or nine carbon atoms, or a mixture thereof.

  本发明涉及一种抑制微生物的组合物，以及相关的过程、配方、浓缩物和用途。该组合物包含至少30重量％的化合物X，其中化合物X符合公式（I）：其中R是具有七个或九个碳原子的饱和或不饱和碳氢链，或其混合物。