p-mentha-1,8-dien-2-ol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: p-mentha-1,8-dien-2-ol
• 英文别名: 1,8-Menthadien-2-ol；2-methyl-5-prop-1-en-2-ylcyclohexen-1-ol
• 化学式: C₁₀H₁₆O
• mdl: MFCD11500563
• 分子量: 152.236
• InChiKey: MZJVVSSFVFMRTM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  甜橙提取物 在 ammonium acetate 、 双氧水 作用下， 以 甲醇 、 丙酮 为溶剂， 生成 1-甲基-4-丙-1-烯-2-基-环己-2-烯-1-醇 、 p-mentha-1,8-dien-2-ol 、 (3R,6S)-3-methyl-6-prop-1-en-2-ylcyclohexen-1-ol
  参考文献：
  名称：

  Activated vs. pyrolytic carbon as support matrix for chemical functionalization: Efficient heterogeneous non-heme Mn(II) catalysts for alkene oxidation with H2O2

  摘要：

  Two types of heterogeneous catalytic materials, Mn-II-L(3)imid@Cox and Mn-II-L(3)imid@PCox, have been synthesized and compared by covalent grafting of a catalytically active [Mn-II-L(3)imid] complex on the surface of an oxidized activated carbon (Cox) and an oxidized pyrolytic carbon from recycled-tire char (PCox). Both hybrids are non-porous bearing graphitic layers intermixed with disordered sp(2)/sp(3) carbon units. Raman spectra show that (I-D/I-G)(activatedcarbon) > (I-D/I-G)(pyrolyticcarbon) revealing that oxidized activated carbon(Cox) is less graphitized than oxidized pyrolytic carbon (PCox). The Mn-II-L(3)imid@Cox and Mn-II-L(3)imid@PCox catalysts were evaluated for alkene oxidation with H2O2 in the presence of CH3COONH4. Both showed high selectivity towards epoxides and comparing the achieved yields and TONs, they appear equivalent. However, Mn-II-L(3)imid@PCox catalyst is kinetically faster than the Mn-II-L(3)imid@Cox (accomplishing the catalytic runs in 1.5 h vs. 5 h). Thus, despite the similarity in TONs Mn-II-L(3)imid@PCox achieved extremely higher TOFs vs. Mn-II-L(3)imid@Cox. Intriguingly, in terms of recyclability, Mn-II-L(3)imid@Cox could be reused for a 2th run showing a similar to 20% loss of its catalytic activity, while Mn-II-L(3)imid@PCox practically no recyclable. This phenomenon is discussed in a mechanistic context; interlinking oxidative destruction of the Mn-complex with high TOF5 for Mn-II-L(3)imid@PCox, while the low-TOFs of Mn-II-L(3)imid@Cox are preventive for the oxidative destruction of the Mn-complex. (C) 2016 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2016.08.033

文献信息

• MICROBICIDAL COMPOSITION
  申请人：Unilever N.V.

  公开号：EP2787827B2

  公开（公告）日：2021-11-10
• ANTIMICROBIAL COMPOSITION
  申请人：Unilever N.V.

  公开号：EP2787828A1

  公开（公告）日：2014-10-15
• MICROBIAL COMPOSITION
  申请人：Rohm and Haas Company

  公开号：US20140323585A1

  公开（公告）日：2014-10-30

  A synergistic microbicidal composition containing synergistic combinations of a phenolic compound selected the class consisting of chlorinated phenols, monosubstituted phenols, fused bicyclic phenols, isopropyl methyl catechols and monosubstituted catechols and an antimicrobial alcohol selected from the class consisting of propen- 2 yl-methyl-cyclohexanols, menthadiene alcohols and substituted cyclohexyl propyl- 1,3 -diols.
• US9271492B2
  申请人：——

  公开号：US9271492B2

  公开（公告）日：2016-03-01
• US9832995B2
  申请人：——

  公开号：US9832995B2

  公开（公告）日：2017-12-05