α-campholenic amide | 113375-35-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: α-campholenic amide
• 英文别名: ((R)-2,2,3-trimethyl-cyclopent-3-enyl)-acetic acid amide；((R)-2,2,3-Trimethyl-cyclopent-3-enyl)-essigsaeure-amid；(-)-α-Campholensaeure-amid；2-[(1R)-2,2,3-trimethylcyclopent-3-en-1-yl]acetamide
• CAS: 113375-35-2
• 化学式: C₁₀H₁₇NO
• 分子量: 167.251
• InChiKey: RXYMLUWIPZGBBR-MRVPVSSYSA-N

物化性质

• 沸点：
  297.2±9.0 °C(Predicted)
• 密度：
  0.946±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  盐酸 、 α-campholenic amide 生成 β-Campholensaeure-amid
  参考文献：
  名称：

  Behal, Bulletin de la Societe Chimique de France, 1895, vol. <3> 13, p. 836

  摘要：

  DOI：
• 作为产物：
  描述：

  (+)-10-溴樟脑 在 盐酸 、 氨 作用下， 生成 α-campholenic amide
  参考文献：
  名称：

  Space shuttle observations of terrestrial impact structures using SIR-C and X-SAR radars

  摘要：

  Abstract— Ten terrestrial impact structures were imaged during two flights of the 1994 space radar laboratory (SRL) experiment. These craters include Wolf Creek, Australia; Roter Kamm, Namibia; Zhamanshin, Kazakhstan; BP and Oasis, Libya; Aorounga, Chad; Amguid, Algeria; and Spider, Connolly Basin and Henbury, Australia. SRL contained two co‐registered instruments; the United States shuttle imaging radar‐C (SIR‐C) polarimetric radar system operating in L‐band (λ = 24 cm) and C‐band (λ = 5.6 cm), and the joint German/Italian synthetic aperture radar (X‐SAR) operating in vertically‐polarized X‐band (λ = 3 cm).Comparisons show SRL images to be complementary to, or in some cases superior to, corresponding optical images for evaluating size, location, and relative age of impact features. Regardless of wavelength or polarization, craters with significant relief appear prominently on radar as a result of slope and roughness effects. In desert regions, longer wavelengths penetrate dry sand mantles to reveal hidden crater dimensions or associated buried landforms. Radar polarities and wavelengths are particularly sensitive to vegetation, surface roughness, and soil moisture or electrical properties. In the more temperate environments of Kazakhstan and Australia, SRL images show detailed stream patterns that reveal the location and structure of otherwise obscured impact features.

  DOI：

  10.1111/j.1945-5100.2002.tb00824.x

文献信息

• Nitrogen insertion to bicyclo[2.2.1]heptanones; the photo-Beckmann rearrangement of oximes of (+)-fenchone and (+)-camphor1,2
  作者：Hiroshi Suginome、Kenji Furukawa、Kazuhiko Orito

  DOI：10.1039/c39870001004

  日期：——

  The major products of the photolysis of the oximes of two natural bicyclo[2.2.1]heptanones, (+)-fenchone and(+)-camphor, in methanol are nearly equal amounts of two isomeric lactams arising from the photo-Beckmann rearrangement and the corresponding ring-opened amides.

  在甲醇中，两种天然双环[2.2.1]庚酮（+）-去甲酮和（+）-樟脑肟的肟光解的主要产物是几乎相同数量的两种异构体内酰胺，它们是由光-贝克曼重排和相应的开环酰胺。
• Suginome, Hiroshi; Furukawa, Kenji; Orito, Kazuhiko, Journal of the Chemical Society. Perkin transactions I, 1991, # 4, p. 917 - 921
  作者：Suginome, Hiroshi、Furukawa, Kenji、Orito, Kazuhiko

  DOI：——

  日期：——
• Tiemann, Chemische Berichte, 1896, vol. 29, p. 3007
  作者：Tiemann

  DOI：——

  日期：——
• Goldschmidt; Zuerrer, Chemische Berichte, 1884, vol. 17, p. 2072
  作者：Goldschmidt、Zuerrer

  DOI：——

  日期：——
• Naegeli, Chemische Berichte, 1884, vol. 17, p. 806
  作者：Naegeli

  DOI：——

  日期：——