2-甲基-1-[1-(2-甲基丙氧基)丙氧基]丙烷 | 13002-11-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-甲基-1-[1-(2-甲基丙氧基)丙氧基]丙烷
• 英文名称: propionaldehyde diisobutyl acetal
• 英文别名: 1,1-diisobutoxy-propane；1,1-Bis-isobutyloxy-propan；1,1-Bis(2-methylpropoxy)propane；2-methyl-1-[1-(2-methylpropoxy)propoxy]propane
• CAS: 13002-11-4
• 化学式: C₁₁H₂₄O₂
• mdl: MFCD00059351
• 分子量: 188.31
• InChiKey: USYFLBOYMYXIBN-UHFFFAOYSA-N

物化性质

• LogP：
  3.434 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2909199090

反应信息

• 作为产物：
  描述：

  异丁醇 在 一氧化碳 、 氢气 、 cobalt(II) carbonate 作用下， 140.0 ℃ 、30.0 MPa 条件下， 反应 6.0h， 生成 异戊酸 、 1,1-二异丁氧基-2-甲基丙烷 、 2-甲基-1-丙氧基-丙烷 、 异丁醚 、 2-甲基-1-[1-(2-甲基丙氧基)丙氧基]丙烷 、 异丁醛 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Del'nik; Kagna; Katsnel'son, Journal of applied chemistry of the USSR, 1986, vol. 59, # 10 pt 2, p. 2183 - 2188

  摘要：

  DOI：

文献信息

• Components and catalysts for the polymerization of olefins
  申请人：MONTELL NORTH AMERICA INC.

  公开号：EP0361494A2

  公开（公告）日：1990-04-04

  Diethers of general formula: where R, RI, RII, RIII, RIV and RV, same or different, are H or linear or branched alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl radicals with 1-18 carbon atoms, provided that R and RI are not both H or CH3 or are not CH3 and n-propyl; RVI and RVII the same or different, are linear or branched alkyl, cycloaliphatic, aryl, or arylalkyl radicals having 1-18 carbon atoms; one or more of R to RVII may be bonded to form a cyclic structure. The diethers are particularly useful in the preparation of Ziegler-Natta catalysts. Solid catalyst components for the polymerization of olefins modified with electron-donor compounds, comprising a titanium halide supported on a magnesium dihalide in active form and containing as an electron-donor compound a di- or polyether having specific reactivity characteristics towards MgCl2 and TiCl4.

  通式如下的二乙基化合物 其中 R、RI、RII、RIII、RIV 和 RV 相同或不同，均为 H 或具有 1-18 个碳原子的直链或支链烷基、环烷基、芳基、烷芳基或芳烷基自由基，但 R 和 RI 不能同时为 H 或 CH3 或不能同时为 CH3 和正丙基；RVI 和 RVII 相同或不同，均为具有 1-18 个碳原子的直链或支链烷基、环烷基、芳基或芳烷基自由基；R 至 RVII 中的一个或多个可以键合形成环状结构。 二乙醚在制备齐格勒-纳塔催化剂中特别有用。 用电子供体化合物改性的烯烃聚合用固体催化剂组分，包括以活性形式支撑在二卤化镁上的卤化钛，并含有作为电子供体化合物的对氯化镁和氯化钛具有特定反应特性的二元或多元醚。
• POLYVINYL ETHER COMPOUND AND LUBRICATING OIL
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0644175A1

  公开（公告）日：1995-03-22

  A polyvinyl ether compound (including one having a specified terminal group) having constitutional units each represented by general formula (I) wherein R₃, R₄ and R₅ represent each H or alkyl; R⁶ represents alkylen; R⁷ represents alkyl; and k represents 0 to 10; and a process for producing the same by polymerizing a vinyl ether monomer in the presence of a specified initiator comprising a combination of a Brönsted acid, Lewis acid or organometallic compound with an adduct of a carboxylic acid with water, alcohol, phenol, acetal or vinyl ether. The compound is useful as lubricating oil, etc. A process for producing an ether compound by the reaction of an acetal or ketal represented by general formula (II) with hydrogen in the presence of an acidic substance and a solid catalyst having a hydrogenating ability to convert the group R³³O- or R³⁴O- into a hydrogen atom.

  一种聚乙烯醇醚化合物（包括具有特定末端基团的聚乙烯醇醚化合物），其每个构 成单元均由通式(I)表示，其中 R₃、R₄ 和 R₅ 分别代表 H 或烷基；R⁶ 代表亚烷基；R⁷ 代表烷基；以及 k 代表 0 至 10；以及一种生产该化合物的工艺，其方法是在指定的引发剂存在下，使乙烯基醚单体聚合，该引发剂包括布氏酸、路易斯酸或有机金属化合物与羧酸与水、醇、苯酚、缩醛或乙烯基醚的加合物的组合。这种化合物可用作润滑油等。在酸性物质和具有氢化能力的固体催化剂存在下，通式 (II) 所代表的缩醛或缩酮与氢发生反应，将基团 R³³O- 或 R³⁴O- 转化为氢原子，从而生产醚化合物的工艺。
• Polyvinyl ether compound and method of preperation
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1059279B1

  公开（公告）日：2005-08-17
• PROCESS FOR THE GENERATION OF 2,5-DIMETHYLHEXENE FROM ISOBUTENE
  申请人：UOP LLC

  公开号：EP2931691A1

  公开（公告）日：2015-10-21
• SOLID CATALYST FOR OLEFIN POLYMERIZATION AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20130072648A1

  公开（公告）日：2013-03-21

  A solid catalyst for olefin polymerization and a process for producing an olefin polymer are provided. The polymer has a small content of a component which is dissolved out into a low temperature organic solvent, such as a low-molecular weight component and an amorphous component. The solid catalyst is obtained by bringing a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and an aliphatic carboxylate; an organoaluminum compound; and a compound represented by formula (I) into contact with each other: wherein R 1 is a hydrocarbyl group having 1 to 10 carbon atoms, R 2 is a hydrogen atom, a halogen atom or a hydrocarbyl group having 1 to 16 carbon atoms, and the R 1 the R 2 groups are independently the same or different, and the respective R 1 groups and R 2 groups may be joined with each other to form a ring.

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