6-(2-methyl-6,6-dimethylcyclohex-1-en-1-yl)-3-methylhex-1-ene-5-yne-3-ol | 74352-11-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 6-(2-methyl-6,6-dimethylcyclohex-1-en-1-yl)-3-methylhex-1-ene-5-yne-3-ol
• 英文别名: 9-(2-propynyl)-β-ionol；(+/-)-3-methyl-1t-(2,6,6-trimethyl-cyclohex-1-enyl)-hex-1-en-5-yn-3-ol；(+/-)-3-Methyl-1t-(2,6,6-trimethyl-cyclohex-1-enyl)-hex-1-en-5-in-3-ol；(+/-)-3-Methyl-1t-(2,2,6-trimethyl-cyclohexen-(6)-yl)-hexen-(1)-in-(5)-ol-(3)；4-Hydroxy-4-methyl-6-(2,6,6-trimethyl-cyclohex-1-enyl)-hex-5-en-1-in；(E)-3-methyl-1-(2,6,6-trimethylcyclohexen-1-yl)hex-1-en-5-yn-3-ol
• CAS: 74352-11-7
• 化学式: C₁₆H₂₄O
• 分子量: 232.366
• InChiKey: OISIVHUKVJCYEN-FMIVXFBMSA-N

物化性质

• 沸点：
  345.5±22.0 °C(Predicted)
• 密度：
  0.978±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  6-(2-methyl-6,6-dimethylcyclohex-1-en-1-yl)-3-methylhex-1-ene-5-yne-3-ol 在 4-二甲氨基吡啶 、 1,5-二氮杂双环[4.3.0]壬-5-烯 、 sodium amide 作用下， 以 甲苯 为溶剂， 反应 1.42h， 生成 (3Z,5E)-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3,5-hexadien-1-yne
  参考文献：
  名称：

  Broek, A. D.; Lugtenburg, J., Recueil des Travaux Chimiques des Pays-Bas, 1980, vol. 99, # 11, p. 363 - 366

  摘要：

  DOI：
• 作为产物：
  描述：

  beta-紫罗酮 、 allenylmagnesium bromide 以 乙醚 为溶剂， 反应 2.0h， 以75%的产率得到6-(2-methyl-6,6-dimethylcyclohex-1-en-1-yl)-3-methylhex-1-ene-5-yne-3-ol
  参考文献：
  名称：

  氧杂环戊基亚铬和钼配合物的合成氧杂环戊烷和呋喃

  摘要：

  本发明描述了通过使用不稳定的五羰基铬和五羰基钼络合物的炔属醇的金属辅助环化来容易和方便地制备取代的氧杂环戊烷和呋喃。

  DOI：

  10.1016/0040-4020(95)00990-6

文献信息

• Assignment of the anomalous resonance Raman vibrations of bathorhodopsin
  作者：Gregory Eyring、Bostick Curry、Richard Mathies、Albert Broek、Johan Lugtenburg

  DOI：10.1021/ja00536a046

  日期：1980.7
• Rate of Change of Angular Bearing as the Relevant Property in a Horizontal Interception Task During Locomotion
  作者：Matthieu Lenoir、Ellane Musch、Evert Thiery、Geert J. P. Savelsbergh

  DOI：10.1080/00222890209601955

  日期：2002.12

  The authors ran 3 experiments to investigate how catchers deal with the horizontal component of the ball's trajectory in an interception task during locomotion. The experiments were built upon the finding that velocity adaptations are based upon changes in the horizontal angular position or velocity of the ball with respect to the observer (M. Lenoir, M. Janssens, E. Musch, E. Thiery, & J. Uyttenhove, 1999); a potential underlying information source for that strategy is described. In Experiment 1, actor (N = 10 participants) and ball approached each other along the legs of a V-shaped track. When the velocity and the initial angular bearing of the ball were varied, the observed behavior fitted with nulling the horizontal angular velocity of the ball: A positive or negative angular velocity was compensated by a velocity change. Evidence was obtained that those adaptations are modulated by a critical change in, rather than by a critical state of, the environment-actor system. In Experiment 2, the distance between the head and an artificial end-effector was varied. Irrespective of that distance, participants (N = 7) accelerated and decelerated in order to keep the angular velocity of the ball with respect to the end-effector close to constant. The ecological relevance of that constant bearing angle strategy was confirmed in Experiment 3: Participants (N = 7) in that experiment freely ran to catch fly balls. The present results support the concept that one can explain with a limited number of control variables an actor's behavior in an interception task during self-motion.
• CH258514
  申请人：——

  公开号：——

  公开（公告）日：——
• Isler, Chimia, 1949, vol. 3, p. 150
  作者：Isler

  DOI：——

  日期：——
• DE1110158
  申请人：——

  公开号：——

  公开（公告）日：——