4-isopropenyl-1-methylcyclohexane | 6252-33-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 4-isopropenyl-1-methylcyclohexane
• 英文别名: 4-isopropenyl-1-methyl-cyclohexane；1-methyl-4-(prop-1-en-2-yl)cyclohexane；1-isopropenyl-4-methyl-1-cyclohexane；1-isopropenyl-4-methyl-cyclohexane；4-isopropenylmethylcyclohexane；Δ8(9)-p-menthene；Cyclohexane, 1-methyl-4-(1-methylethenyl)-, cis-；1-methyl-4-prop-1-en-2-ylcyclohexane
• CAS: 6252-33-1
• 化学式: C₁₀H₁₈
• mdl: MFCD09038400
• 分子量: 138.253
• InChiKey: WPMKLOWQWIDOJN-UHFFFAOYSA-N

物化性质

• 沸点：
  750 °C
• 密度：
  0.8142 g/cm3
• 保留指数：
  974.1

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  4-isopropenyl-1-methylcyclohexane 在 氢溴酸 作用下， 生成 p-4(8)-menthene
  参考文献：
  名称：

  Kishner, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1911, vol. 43, p. 954

  摘要：

  DOI：
• 作为产物：
  描述：

  松油醇 在 水 、 镍 、 magnesium chloride 作用下， 60.0~240.0 ℃ 、9.81 MPa 条件下， 生成 4-isopropenyl-1-methylcyclohexane
  参考文献：
  名称：

  Studies in the Terpene Series. I. Dehydration of Alcohols in the Terpene Series Under Pressure and in the Presence of Dilute Aqueous Salt Solutions

  摘要：

  DOI：

  10.1021/ja01235a019

文献信息

• Mononuclear ruthenium complex and organic synthesis reaction using same
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US09884316B2

  公开（公告）日：2018-02-06

  A neutral or cationic mononuclear ruthenium divalent complex represented by formula (1) can actualize exceptional catalytic activity in at least one reaction among a hydrosilylation reaction, hydrogenation reaction, and carbonyl compound reduction reaction. (In the formula, R1-R6 each independently represent a hydrogen atom or an alkyl group, aryl group, aralkyl group, organooxy group, monoorganoamino group, diorganoamino group, monoorganophosphino group, diorganophosphino group, monoorganosilyl group, diorganosilyl group, triorganosilyl group, or organothio group optionally substituted by X; at least one pair comprising any of R1-R3 and any of R4-R6 together represents a crosslinkable substituent; X represents a halogen atom, organooxy group, monoorganoamino group, diorganoamino group, or organothio group; L each independently represent a two-electron ligand other than CO and thiourea ligands; two L may bond to each other; and m represents an integer of 3 or 4.)

  根据公式（1）表示的中性或阳离子单核钌二价配合物，可以在至少一个反应中实现卓越的催化活性，包括氢硅化反应、氢化反应和羰基化合物还原反应。 （在公式中，R1-R6每个独立地代表一个氢原子或一个烷基、芳基、芳烷基、有机氧基、单有机胺基、双有机胺基、单有机膦基、双有机膦基、单有机硅基、双有机硅基、三有机硅基或有机硫基，可由X取代；R1-R3和R4-R6中的至少一对共同代表一个可交联的取代基；X代表一个卤素原子、有机氧基、单有机胺基、双有机胺基或有机硫基；L各自独立地代表一个除CO和硫脲配体以外的双电子配体；两个L可以相互结合；m代表一个3或4的整数。）
• Mononuclear iron complex and organic synthesis reaction using same
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US10363551B2

  公开（公告）日：2019-07-30

  A mononuclear iron bivalent complex having iron-silicon bonds, which is represented by formula (1), can exhibit an excellent catalytic activity in at least one reaction selected from three reactions, i.e., a hydrosilylation reaction, a hydrogenation reaction and a reaction for reducing a carbonyl compound. (In the formula, R1 to R6 independently represent a hydrogen atom, an alkyl group which may be substituted by X, or the like; X represents a halogen atom, or the like; L1 represents at least one two-electron ligand selected from an isonitrile ligand, an amine ligand, an imine ligand, a nitrogenated heterocyclic ring, a phosphine ligand, a phosphite ligand and a sulfide ligand, wherein, when multiple L1's are present, two L1's may be bonded to each other; L2 represents a two-electron ligand that is different from a CO ligand or the above-mentioned L1, wherein, when multiple L2's are present, two L2's may be bonded to each other; and m1 represents an integer of 1 to 4 and m2 represents an integer of 0 to 3, wherein the sum total of m1 and m2 (i.e., m1+m2) satisfies 3 or 4.)

  具有铁-硅键的单核二价铁络合物，其由公式（1）表示，可以在三个反应中选择至少一个反应表现出优异的催化活性，即硅氢化反应、氢化反应和还原羰基化合物的反应。 （在公式中，R1至R6独立代表氢原子、可能被X取代的烷基团等；X代表卤素原子等；L1代表至少一种从异腈配体、胺配体、亚胺配体、氮杂环、膦配体、亚磷酸盐配体和硫化物配体中选择的两电子配体，其中，当存在多个L1时，两个L1可以相互连接；L2代表与CO配体或上述L1不同的两电子配体，其中，当存在多个L2时，两个L2可以相互连接；m1代表1至4的整数，m2代表0至3的整数，其中m1和m2的总和（即m1+m2）满足3或4。）
• Stereoselective synthesis of (6R)- and (6S)-diosphenol and Ψ-diosphenol
  作者：David F Schneider、Murray S Viljoen

  DOI：10.1016/s0040-4020(02)00492-1

  日期：2002.6

  Methods are discussed for the stereoselective synthesis of the (R)-and (S)-enantiomers of the diosphenols (5)–(8) by utilizing the commercially available stereoisomers (9), (12), (23) and (25) of carvone and limonene, respectively, as chiral starting materials.

  讨论了利用市售的立体异构体（9），（12），（23）和（25）对二酚（5）-（8）的（R）和（S）-对映异构体进行立体选择性合成的方法。香芹酮和柠檬烯分别作为手性原料。
• Colloidal and nanosized catalysts in organic synthesis: XV. Gas-phase hydrogenation of alkenes catalyzed by supported nickel nanoparticles
  作者：Yu. V. Popov、V. M. Mokhov、D. N. Nebykov、S. E. Latyshova、A. O. Panov、A. A. Dontsova、P. M. Shirkhanyan、K. V. Shcherbakova

  DOI：10.1134/s1070363216120033

  日期：2016.12

  Gas-phase hydrogenation of alkenes and their derivatives, catalyzed by nickel nanoparticles supported on zeolite or silica gel support occurs at 150–250°С and an atmospheric hydrogen pressure and results in a high conversion. The selectivity of the hydrogenation depends on the amount of hydrogen: at a low diene (triene)–hydrogen ratio, selective hydrogenation of one multiple bond in the substrate is

  在沸石或硅胶载体上负载的镍纳米颗粒催化的烯烃及其衍生物的气相加氢反应在150-250°С和大气压的氢气压力下进行，并导致高转化率。氢化的选择性取决于氢的量：在低的二烯（三烯）-氢比率下，可以对底物中的一个多重键进行选择性氢化。
• Comprehensive Kinetic and Mechanistic Considerations for the Gas-Phase Behaviour of Pinane-Type Compounds
  作者：Achim Stolle、Bernd Ondruschka、Werner Bonrath

  DOI：10.1002/ejoc.200601098

  日期：2007.5

  experimental evidence for the formation of pyrolysis products by a biradical pathway is discussed. In addition to these results a kinetic model describing the isomerisation of the bicyclic compounds to their acyclic and monocyclic isomers is presented. A good correlation between kinetic simulations and experimental data is revealed. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

  已经研究了选定的蒎烷类化合物 α-蒎烯 (1)、β-蒎烯 (2)、蒎烷 (3) 和诺品酮 (4) 的热行为。讨论了双环原料向其无环和单环异构体的转化以及无环主要异构化产物的连续反应。介绍了反应网络中 1-4 的转化，并讨论了通过双自由基途径形成热解产物的实验证据。除了这些结果之外，还提供了描述双环化合物异构化为其无环和单环异构体的动力学模型。揭示了动力学模拟和实验数据之间的良好相关性。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)