2-Dimethoxymethyl-5-methyl-hexa-1,4-diene | 250736-06-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Dimethoxymethyl-5-methyl-hexa-1,4-diene
• 英文别名: 2-(Dimethoxymethyl)-5-methylhexa-1,4-diene
• CAS: 250736-06-2
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: VNVZJKLKYOHZEQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Dimethoxymethyl-5-methyl-hexa-1,4-diene 在 baker's yeast 、 蔗糖 作用下， 以 乙醇 为溶剂， 生成 (R)-2,5-dimethylhex-4-en-1-ol 、 4-己烯-1-醇,2,5-二甲基-,(2S)-
  参考文献：
  名称：

  Baker's yeast mediated biohydrogenation of unsaturated compounds containing a methylene group: enantioselective preparation of 2-methyl alkanols from 2-substituted acrolein acetals

  摘要：

  The baker's yeast mediated biohydrogenation of unsaturated compounds containing a methylene group may constitute an enantioselective biocatalytic approach to the preparation of 2-methyl-1-alkanols, as exemplified by the reduction of the compounds 8a-d to 90-98% enantiomerically pure alcohols 2a-d. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(99)00256-6
• 作为产物：
  描述：

  5-methyl-2-methylenehex-4-en-1-ol 在 manganese(IV) oxide 、 氯化铵 作用下， 以 甲醇 、 氯仿 为溶剂， 反应 16.0h， 生成 2-Dimethoxymethyl-5-methyl-hexa-1,4-diene
  参考文献：
  名称：

  Baker's yeast mediated biohydrogenation of unsaturated compounds containing a methylene group: enantioselective preparation of 2-methyl alkanols from 2-substituted acrolein acetals

  摘要：

  The baker's yeast mediated biohydrogenation of unsaturated compounds containing a methylene group may constitute an enantioselective biocatalytic approach to the preparation of 2-methyl-1-alkanols, as exemplified by the reduction of the compounds 8a-d to 90-98% enantiomerically pure alcohols 2a-d. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(99)00256-6

文献信息

• Baker's yeast mediated biohydrogenation of unsaturated compounds containing a methylene group: enantioselective preparation of 2-methyl alkanols from 2-substituted acrolein acetals
  作者：Patrizia Ferraboschi、Shahrzad Reza-Elahi、Elisa Verza、Enzo Santaniello

  DOI：10.1016/s0957-4166(99)00256-6

  日期：1999.7

  The baker's yeast mediated biohydrogenation of unsaturated compounds containing a methylene group may constitute an enantioselective biocatalytic approach to the preparation of 2-methyl-1-alkanols, as exemplified by the reduction of the compounds 8a-d to 90-98% enantiomerically pure alcohols 2a-d. (C) 1999 Elsevier Science Ltd. All rights reserved.