[1S-(1a,3a,6a)]-3,7,7-三甲基-二环[4.1.0]-4-庚烯-3-醇 | 4017-82-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: [1S-(1a,3a,6a)]-3,7,7-三甲基-二环[4.1.0]-4-庚烯-3-醇
• 英文名称: trans-2-caren-4-ol
• 英文别名: cis-caren-4-ol；2-carene-4-ol；car-2-en-4-ol；4,7,7-trimethylbicyclo[4.1.0]hept-4-en-3-ol
• CAS: 4017-82-7；52153-53-4；62532-46-1；88390-12-9；103063-10-1；6617-35-2
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: XCIZLAMMPDJKRZ-UHFFFAOYSA-N

物化性质

• 保留指数：
  1153.61;1178;1222;1181.2

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-Chlor-caren-4 在 potassium acetate 、 溶剂黄146 作用下， 生成 [1S-(1a,3a,6a)]-3,7,7-三甲基-二环[4.1.0]-4-庚烯-3-醇
  参考文献：
  名称：

  Tischtschenko et al., Zhurnal Obshchei Khimii, 1952, vol. 22, p. 803,808; engl. Ausg. S. 865, 868

  摘要：

  DOI：

文献信息

• Influence of the Brönsted and Lewis acid sites on the catalytic activity and selectivity of Fe/MCM-41 system
  作者：N.A. Fellenz、J.F. Bengoa、S.G. Marchetti、A. Gervasini

  DOI：10.1016/j.apcata.2012.06.003

  日期：2012.9

  spectroscopy. The influence of the structural changes of the nanoclusters and the effect of the simultaneous presence of Lewis and Brönsted acid sites were evaluated studying the product distribution from the α-pinene oxide isomerization reaction. It was determined that the Brönsted acidity of the Fe/MCM-41 system has not the sufficient acid strength to modify the product distribution which is mainly governed

  合成具有高铁分散性的系统Fe 2 O 3 / MCM-41，以将路易斯酸位引入MCM-41结构中。两种煅烧气氛（惰性和氧化剂）用于生产具有不同结构特性的铁纳米团簇。此外，在两种固体上均实现了甲硅烷基化处理，目的是中和与MCM-41硅烷醇基团相关的布朗斯台德酸度。通过原子吸收光谱，低角度X射线衍射，N 2吸附，程序升温还原，傅里叶变换红外光谱，29个核磁共振对样品进行表征Si和Mössbauer光谱。研究了α-pine烯氧化物异构化反应的产物分布，评估了纳米团簇的结构变化的影响以及路易斯和布朗斯台德酸位点同时存在的影响。已经确定，Fe / MCM-41系统的布朗斯台德酸度没有足够的酸强度来改变主要由路易斯位点控制的产物分布。
• Metal-Catalyzed Oxidations with Pinane Hydroperoxide:  A Mechanistic Probe To Distinguish between Oxometal and Peroxometal Pathways
  作者：H. E. B. Lempers、A. Ripollès i Garcia、R. A. Sheldon

  DOI：10.1021/jo971270b

  日期：1998.3.1

  The relative reactivities of tert-butyl hydroperoxide (TBHP) and pinane hydroperoxide (PHP) in metal (Cr, Mo, Ru, Se, V, and Zr)-catalyzed oxidations were compared. When these oxidations involve rate-limiting oxygen transfer from a peroxometal species to the substrate huge differences between TBHP and PHP were observed, e.g., molybdenum-catalyzed epoxidation of cyclohexene with TBHP gave a 98% yield while PHP gave 0%. When the reaction involves reaction of an oxometal species with the substrate as the rate-limiting step, little or no difference is observed, e.g., the selenium-catalyzed allylic oxidation of beta-pinene gave a 96% and 99% yield with TBHP and PHP, respectively. Small but significant differences are observed when reoxidation of the catalyst by the hydroperoxide to the active oxometal species is the rate-limiting step; e.g., the chromium-catalyzed oxidation of carveol gave carvone in 89% and 24% yield with TBHP and PHP, respectively. Hence, the effect of RO2H structure on rate is dependent on the rate-limiting step.
• KURATA, TAKEO;KOBAYASHI, NOBUYUKI;MASUDA, ATSUSHI, YUKAGAKU, 39,(1990) N, S. 414-416
  作者：KURATA, TAKEO、KOBAYASHI, NOBUYUKI、MASUDA, ATSUSHI

  DOI：——

  日期：——
• COMPOSITION OF LEMON PEEL ESSENTIAL OIL AS A GROWTH PROMOTER IN THE POULTRY INDUSTRY
  申请人：Universidad Peruana Cayetano Heredia

  公开号：EP2820958B1

  公开（公告）日：2018-10-24
• US4222964A
  申请人：——

  公开号：US4222964A

  公开（公告）日：1980-09-16