beta-氟乙基乙酸酯 | 462-26-0

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: beta-氟乙基乙酸酯
• 中文别名: 2-氟-1-乙醇乙酸酯
• 英文名称: 2-fluoroethyl acetate
• 英文别名: 2-fluoroetyl acetate；fluoroethyl acetate；acetic acid-(2-fluoro-ethyl ester)；Essigsaeure-(2-fluor-aethylester)；Essigsaeure-<2-fluor-aethylester>；(2-Fluor-aethyl)-acetat
• CAS: 462-26-0
• 化学式: C₄H₇FO₂
• 分子量: 106.097
• InChiKey: PVDYNYCZGYOXAF-UHFFFAOYSA-N

物化性质

• 沸点：
  119.3 °C(Press: 763 Torr)
• 密度：
  1.0982 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2915390090
• 储存条件：
  室温

反应信息

• 作为反应物：
  描述：

  beta-氟乙基乙酸酯 生成 氟化乙烯
  参考文献：
  名称：

  极性β-取代基在乙酸乙酯酯气相热解中的作用

  摘要：

  DOI：

  10.1021/j100446a002
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 potassium fluoride 作用下， 生成 beta-氟乙基乙酸酯
  参考文献：
  名称：

  Gryszkiewicz-Trochimowski; Sporzynski; Wnuk, Recueil des Travaux Chimiques des Pays-Bas, 1947, vol. 66, p. 424

  摘要：

  DOI：

文献信息

• ALIPHATIC VICINAL FLUOROBROMIDES SOME PREPARATIONS AND REACTIONS
  作者：F. L. M. Pattison、D. A. V. Peters、F. H. Dean

  DOI：10.1139/v65-223

  日期：1965.6.1

  The addition of "BrF", using N-bromoamides in anhydrous hydrogen fluoride, to a number of aliphatic alkenes has been studied. As expected, the bromine atom in the resultant vicinal fluorobromides exhibited relatively low reactivity in nucleophilic and hydrogenolytic reactions.

  已经研究了在无水氟化氢中使用 N-溴酰胺将“BrF”添加到许多脂肪族烯烃中。正如预期的那样，所得邻位氟溴化物中的溴原子在亲核和氢解反应中表现出相对较低的反应性。
• Block ethylenic copolymers comprising a vinyllactam block, cosmetic or pharmaceutical compositions comprising them and cosmetic use of these copolymers
  申请人：Mougin Nathalie

  公开号：US20050238594A1

  公开（公告）日：2005-10-27

  The present disclosure relates to linear block ethylenic copolymers that have reduced tack and thus do not leave a tacky feel, and to cosmetic and pharmaceutical compositions comprising the linear block ethylenic copolymer. Further disclosed herein is a cosmetic process for making up or caring for keratin materials, comprising the application to the keratin materials of such a composition, and also discloses herein are various cosmetic uses of such a composition. The tack of the copolymers disclosed herein is even reduced under conditions of high humidity, for example for RH values ranging from 50% to 100%.

  本公开涉及具有降低粘性的线性块状乙烯共聚物，因此不会留下粘性感觉，以及包含线性块状乙烯共聚物的化妆品和药品组合物。此外，本公开还涉及用于化妆或护理角蛋白质材料的化妆过程，包括将此类组合物应用于角蛋白质材料，并且还公开了此类组合物的各种化妆用途。本公开所公开的共聚物的粘性甚至在高湿度条件下也降低，例如在相对湿度范围为50％至100％的情况下。
• Block ethylenic copolymers comprising a vinyllactam block, cosmetic or pharmaceutical compositions containing them and cosmetic use of these copolymers
  申请人：Mougin Nathalie

  公开号：US20060088487A1

  公开（公告）日：2006-04-27

  Disclosed herein are a linear block ethylenic copolymer comprising: at least one block A obtained from monomers comprising from 52% to 99% by weight of at least one ethylenic monomer comprising a lactam ring, of formula (I): and from 1% to 48% by weight of at least one ionic hydrophilic monomer; and at least one block B obtained from monomers not comprising an ethylenic monomer comprising a lactam ring of formula (I), or comprising a minor proportion thereof; a cosmetic or pharmaceutical composition, such as a hair composition, comprising the copolymer; a cosmetic process for making up or caring for keratin materials, comprising applying to the keratin materials the composition; and other uses of the copolymer.

  本发明涉及一种线性块状乙烯共聚物，包括：至少一种A块，由单体组成，其中单体组成包括52%至99%重量的至少一种乳环内乙烯单体，其化学式为(I)，以及1%至48%重量的至少一种离子性亲水单体；以及至少一种B块，由不包括化学式(I)的乙烯单体或含有少量乙烯单体(I)的单体组成；还包括一种化妆品或制药组合物，例如一种头发组合物，其中包括该共聚物；一种用于化妆或护理角蛋白质材料的化妆过程，包括将该组合物涂抹于角蛋白质材料上；以及该共聚物的其他用途。
• Block ethylenic copolymers comprising a vinyllactam block, cosmetic compositions containing them and cosmetic use of these copolymers
  申请人：Mougin Nathalie

  公开号：US20050101740A1

  公开（公告）日：2005-05-12

  Linear block ethylenic copolymer comprising: at least one block A derived from monomers comprising from 52 to 100% by weight of an ethylenic monomer containing a lactam ring corresponding to formula (I) below: and at least one block B derived from monomers not comprising an ethylenic monomer containing a lactam ring of formula (I), or comprising a minor proportion thereof, the at least one block B having a glass transition temperature Tg ranging from −55° C. to +55° C. Compositions and processes using the compound are also disclosed.

  线性块状乙烯共聚物，包括：至少一个A块，由含有内酰胺环的乙烯单体组成，其重量占52％至100％，对应于以下公式（I）：以及至少一个B块，由不含有公式（I）中所述内酰胺环的乙烯单体组成或含有其中少量的乙烯单体组成，所述至少一个B块的玻璃转移温度Tg范围为-55℃至+55℃。还公开了使用该化合物的组合物和工艺。
• BLOCK ETHYLENIC COPOLYMERS COMPRISING A VINYLLACTAM BLOCK, COSMETIC COMPOSITIONS CONTAINING THEM AND COSMETIC USE OF THESE COPOLYMERS
  申请人：Mougin Nathalie

  公开号：US20100040572A1

  公开（公告）日：2010-02-18

  Linear block ethylenic copolymer comprising: at least one block A derived from monomers comprising from 52 to 100 % by weight of an ethylenic monomer containing a lactam ring corresponding to formula (I) below: and at least one block B derived from monomers not comprising an ethylenic monomer containing a lactam ring of formula (I), or comprising a minor proportion thereof, the at least one block B having a glass transition temperature Tg ranging from −55° C. to +55° C. Compositions and processes using the compound are also disclosed.

  线性块状乙烯共聚物，包括：至少一个A块，由含有内酰胺环的乙烯单体，其重量占52-100％，对应于以下公式（I）的单体组成；以及至少一个B块，由不含有公式（I）中所述内酰胺环的乙烯单体或其中含有少量乙烯单体，该至少一个B块的玻璃化转变温度Tg范围为-55℃至+55℃。还公开了使用该化合物的组合物和工艺。