methyl 4-methyltetracyclo[6.2.1.13,6.02,7]dodec-9-ene-4-carboxylate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: methyl 4-methyltetracyclo[6.2.1.13,6.02,7]dodec-9-ene-4-carboxylate
• 英文别名: 8-methyl-8-methoxycarbonyltetracyclo[4.4.0.1(2,5).1(7,10)]-3-dodecene；8-methoxycarbonyl-8-methyltetracyclo[4.4.0.1 2,5 .1 7,10]-3-dodecene；8-Methyl-8-methoxycarbonyltetracyclo[4.4.0.12,5.17,10]dodec-3-ene
• 化学式: C₁₅H₂₀O₂
• 分子量: 232.323
• InChiKey: UMCSHTKHXAMMQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  methyl 4-methyltetracyclo[6.2.1.13,6.02,7]dodec-9-ene-4-carboxylate 、 氢氰酸 在 C₆₀H₆₄O₆P₂ 、 bis(1,5-cyclooctadiene)nickel (0) zinc(II) chloride 作用下， 以 甲苯 、 乙腈 为溶剂， 反应 2.0h， 以85%的产率得到Methyl 9-cyano-4-methyltetracyclo[6.2.1.13,6.02,7]dodecane-4-carboxylate
  参考文献：
  名称：

  Norbornane based cycloaliphatic compounds containing nitrile groups

  摘要：

  这项发明涉及新颖的去甲杂环戊烷腈衍生物，以及利用氢氰化反应制备它们的相应方法。

  公开号：

  US20050159614A1
• 作为产物：
  描述：

  二聚环戊二烯 、 methyl 2-methylbicyclo[2.2.1]hept-5-ene-2-carboxylate 、 环戊二烯 、 4-甲氧基苯酚 在 raw materials 作用下， 以 甲基丙烯酸甲酯 为溶剂， 反应 8.0h， 生成 methyl 4-methyltetracyclo[6.2.1.13,6.02,7]dodec-9-ene-4-carboxylate
  参考文献：
  名称：

  US06180316B2

  摘要：

  公开号：

文献信息

• Norbornane based cycloaliphatic compounds containing nitrile groups
  申请人：Allgeier Martin Alan

  公开号：US20050159614A1

  公开（公告）日：2005-07-21

  This invention relates to novel norborane nitrile derivatives, and corresponding methods for making the same using hydrocyanation reactions.

  这项发明涉及新颖的去甲杂环戊烷腈衍生物，以及利用氢氰化反应制备它们的相应方法。
• Method for Producing (Co) Polymer Having Carboxyl Group
  申请人：Hayakawa Toshiyuki

  公开号：US20080051536A1

  公开（公告）日：2008-02-28

  A process for producing a carboxyl group-containing (co)polymer, which comprises a reaction step of (co)polymerizing, in the presence of a polymerization catalyst component, at least a particular, functional group-containing olefin compound represented by predetermined general formula and a reaction termination step of terminating the (co)polymerization. The process is simplified in production steps and can produce a carboxyl group-containing (co)polymer easily at a high yield.

  一种生产含羧基的（共）聚合物的方法，包括以下步骤：在聚合催化剂组分的存在下，聚合至少一个特定的、含有功能基团的烯烃化合物，该化合物符合预定的通式，并终止（共）聚合反应。该方法的生产步骤简化，可以轻松地高产地生产含羧基的（共）聚合物。
• Thermoplastic Resin Composition and Optical Films Made Therefrom
  申请人：Miyaki Nobuyuki

  公开号：US20080095955A1

  公开（公告）日：2008-04-24

  The thermoplastic resin composition of the present invention comprises (A) a cycloolefin-based polymer and (B) a vinyl-based polymer having a polar group, has a glass transition temperature of not lower than 100° C. and has a difference in glass transition temperature between the polymers (A) and (B) of less than 50° C. The optical film of the present invention comprises the thermoplastic resin composition of the invention. According to the present invention, it is possible to improve development of retardation at a low stress in the film stretching while retaining excellent heat resistance and optical properties and maintaining wavelength dispersion properties. The optical film of the invention exhibits properties that the dependence of retardation of a transmitted light on wavelength, said retardation being obtained by stretch orientation of the film, becomes larger as the wavelength becomes longer (positive wavelength dispersion properties), has low water absorption and low coefficient of photoelasticity, and is excellent in adhesion or bonding properties to other materials.

  本发明的热塑性树脂组合物包括(A)环烯基聚合物和(B)具有极性基团的乙烯基聚合物，具有不低于100℃的玻璃化转变温度，并且聚合物(A)和(B)之间的玻璃化转变温度差小于50℃。本发明的光学薄膜包括本发明的热塑性树脂组合物。根据本发明，可以在保持优异的耐热性和光学性能以及维持波长分散性能的同时，在薄膜拉伸时改善低应力下的减速度发展。本发明的光学薄膜表现出传输光的减速度对波长的依赖性随着波长的增加而增加（正波长分散性能），具有低吸水性和低光弹性系数，并且在与其他材料的黏附或粘结性方面表现出优异的性能。
• Thermoplastic Resin Composition, Optical Film And Oriented Film
  申请人：Miyamoto Yoshikazu

  公开号：US20070282077A1

  公开（公告）日：2007-12-06

  The present invention is intended to provide a thermoplastic resin composition which exhibits excellent compatibility while retaining low birefringence and is excellent in weathering resistance and heat resistance, an optical film which is obtained from the thermoplastic resin composition and a retardation film which is excellent in weathering resistance and heat resistance and has reciprocal wavelength dispersion properties. The thermoplastic resin composition comprises a vinyl-based polymer (A) having a unit represented by the following formula (I) and a cycloolefin-based polymer (B). wherein R 1 to R 3 are each a hydrogen atom, a halogen atom, a substituted or unsubstituted hydrocarbon group of 1 to 30 carbon atoms which may have a linkage containing an oxygen atom, a sulfur atom, a nitrogen atom or a silicon atom, or a polar group, and n is 0 or a positive integer.

  本发明旨在提供一种热塑性树脂组合物，该组合物在保持低双折射率的同时表现出优异的相容性，并具有优异的耐候性和耐热性；以及从该热塑性树脂组合物获得的光学薄膜和具有倒数波长色散特性、耐候性和耐热性优异的缓变膜。该热塑性树脂组合物包括具有下式（I）所表示的单元的乙烯基聚合物（A）和环氧烷基聚合物（B），其中R1至R3分别是氢原子、卤素原子、1至30个碳原子的取代或未取代的烃基，该烃基可能含有一个氧原子、硫原子、氮原子或硅原子的连接，或是一个极性基团，n为0或正整数。
• Retardation film and liquid crystal display device using the same
  申请人：Komatsu Shinichi

  公开号：US20090156770A1

  公开（公告）日：2009-06-18

  A retardation film, formed by stretching a film including a norbornene-based, ring-opening polymer containing a structural unit (A) represented by a formula (1), has high transparency, excellent wavelength dispersion characteristics in a single layer, is capable of providing specific retardation to broadband light, is extremely adhesive to other materials, is capable of attaining optical characteristics that are unique among negative birefringence characteristics, and is capable of providing a reverse dispersion of birefringence wavelength dispersion characteristics. The present invention also provides a liquid crystal display device using the foregoing film.

  由于拉伸包含环氧化诺博尔烯基聚合物的薄膜形成的延迟膜，包含一个由公式（1）表示的结构单元（A），具有高透明度，在单层中具有优异的波长色散特性，能够为宽带光提供特定的延迟，极易黏附于其他材料，能够获得负双折射特性中独特的光学特性，并能够提供双折射波长色散特性的反向色散。本发明还提供了使用上述膜的液晶显示器件。