(2E,6E)-farnesyl butyrate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (2E,6E)-farnesyl butyrate
• 英文别名: Farnesyl butanoate；[(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trienyl] butanoate
• 化学式: C₁₉H₃₂O₂
• 分子量: 292.462
• InChiKey: GPNSLSVRBMEOCK-NXGXIAAHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  21
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  反式,反式-金合欢醇 、 丁酸 以 水 为溶剂， 反应 18.0h， 生成 (2E,6E)-farnesyl butyrate
  参考文献：
  名称：

  Iwai, Mieko; Okumura, Susumu; Tsujisaka, Yoshio, Agricultural and Biological Chemistry, 1980, vol. 44, # 11, p. 2731 - 2732

  摘要：

  DOI：

文献信息

• Enzyme reactions in apolar solvent. 6. The effect of double bond isomerism on the rate of PPL-catalyzed acylation of allylic alcohols
  作者：Brian Morgan、Allan C. Oehlschlager

  DOI：10.1016/s0957-4166(00)80130-5

  日期：1993.5

  (E)- and (Z)-isomers of allylic alcohols showed a difference in the rate of porcine pancreatic lipase (PPL) catalyzed acylation. Enzyme-catalyzed acylation was applied to the purification of two terpenic alcohols.

  (E)- 和 (Z)-邻位醇表现出猪胰脂肪酶（PPL）催化的脂肪酰化速率差异。酶催化的脂肪酰化被应用于两种萜烯醇的纯化。
• Host Cells and Methods for Producing Isoprenyl Alkanoates
  申请人：Lee Taek Soon

  公开号：US20100180491A1

  公开（公告）日：2010-07-22

  The invention provides for a method of producing an isoprenyl alkanoate in a genetically modified host cell. In one embodiment, the method comprises culturing a genetically modified host cell which expresses an enzyme capable of catalyzing the esterification of an isoprenol and a straight-chain fatty acid, such as an alcohol acetyltransferase (AAT), wax ester synthase/diacylglycerol acyltransferase (WS/DGAT) or lipase, under a suitable condition so that the isoprenyl alkanoate is produced.
• US5466718A
  申请人：——

  公开号：US5466718A

  公开（公告）日：1995-11-14
• US9200298B2
  申请人：——

  公开号：US9200298B2

  公开（公告）日：2015-12-01
• [EN] HOST CELLS AND METHODS FOR PRODUCING ISOPRENYL ALKANOATES<br/>[FR] CELLULES HÔTES ET PROCÉDÉS DE PRODUCTION D'ALCANOATES D'ISOPRÉNYLE
  申请人：UNIV CALIFORNIA

  公开号：WO2009006386A2

  公开（公告）日：2009-01-08

  The invention provides for a method of producing an isoprenyl alkanoate in a genetically modified host cell. In one embodiment, the method comprises culturing a genetically modified host cell which expresses an enzyme capable of catalyzing the esterification of an isoprenol and a straight-chain fatty acid, such as an alcohol acetyltransferase (AAT), wax ester synthase/diacylglycerol acyltransferase (WS/DGAT) or lipase, under a suitable condition so that the isoprenyl alkanoate is produced.