过氧化二碳酸二(2-苯氧乙基)酯 | 41935-39-1

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物 - 羧酸酯及其衍生物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 过氧化二碳酸二(2-苯氧乙基)酯
• 中文别名: 引发剂BPPD
• 英文名称: di(2-phenoxyethyl) peroxydicarbonate
• 英文别名: Bis(2-phenoxyethyl) peroxydicarbonate；2-phenoxyethoxycarbonyloxy 2-phenoxyethyl carbonate
• CAS: 41935-39-1
• 化学式: C₁₈H₁₈O₈
• 分子量: 362.336
• InChiKey: YMOIBQNMVPBEEZ-UHFFFAOYSA-N

物化性质

• 熔点：
  97~100℃
• 沸点：
  473.9±55.0 °C(Predicted)
• 密度：
  1.275±0.06 g/cm3(Predicted)
• 稳定性/保质期：
  对冲击和摩擦都不敏感，不会自燃，无爆炸危险。然而，纯度低于85%、水分含量高或含有铁铜等金属时，会加速其分解。其毒性与有机过氧化合物相似，可能对皮肤和眼睛造成刺激。

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  26
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  89.5
• 氢给体数：
  0
• 氢受体数：
  8

安全信息

• 危险等级：
  5.2
• 海关编码：
  2909600000
• 包装等级：
  II
• 危险类别：
  5.2

制备方法与用途

化学性质
白色或微黄色粉末，不溶于苯、甲苯和乙醚，易溶于氯仿。

用途
用作聚氯乙烯悬浮聚合的引发剂。此外，它也是一种高效聚合物引发剂，并用于橡胶硫化促进剂。

生产方法
通过将苯酚与烧碱配制成苯酚钠，再与氯乙醇反应生成2-苯氧基乙醇；然后与光气合成氯甲酸2-苯氧基乙酯，最后与过氧化钠反应制得引发剂BPPD。工业品中BPPD含量≥85%。

生产方法
通过将苯酚与烧碱配制成苯酚钠，再与氯乙醇反应生成2-苯氧基乙醇；然后与光气合成氯甲酸2-苯氧基乙酯，最后与过氧化钠反应制得引发剂BPPD。工业品中BPPD含量≥85%。

原料消耗（kg/t）
苯酚：760
氯乙醇（30%浓度）：2700
双氧水（30%浓度）：580

反应信息

• 作为反应物：
  描述：

  过氧化二碳酸二(2-苯氧乙基)酯 以 苯 为溶剂， 生成
  参考文献：
  名称：

  Etlis, I.V.; Fomin, V.A.; Nozrina, F.D., Journal of Organic Chemistry USSR (English Translation), 1991, vol. 27, # 11.1, p. 2010 - 2015

  摘要：

  DOI：
• 作为产物：
  描述：

  2-phenoxyethyl chloroformate 在 sodium peroxide 作用下， 以 氯仿 、 水 为溶剂， 反应 1.5h， 以92%的产率得到过氧化二碳酸二(2-苯氧乙基)酯
  参考文献：
  名称：

  Etlis, I.V.; Fomin, V.A.; Nozrina, F.D., Journal of Organic Chemistry USSR (English Translation), 1991, vol. 27, # 11.1, p. 2010 - 2015

  摘要：

  DOI：

文献信息

• [EN] MULTIFUNCTIONAL FLUORINATED COMPOUND, FLUORINATED POLYMERS MADE FROM THE COMPOUND, AND RELATED METHODS<br/>[FR] COMPOSÉ FLUORÉ MULTIFONCTIONNEL, POLYMÈRES FLUORÉS FABRIQUÉS À PARTIR DU COMPOSÉ, ET PROCÉDÉS ASSOCIÉS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2020245724A1

  公开（公告）日：2020-12-10

  The multifunctional compound is represented by formula X-C(R)RF-Y, in which X and Y are each independently -C(O)-O-M, -C(O)-HAL, -C(O)-NR1 2, -C≡N, -C(O)NR1-SO2-Rf 1-W, or a fluorinated alkenyl group that is optionally interrupted by one or more -O- groups. HAL is -F, -Cl, or -Br. Rf 1 is a fluorinated alkylene group that is optionally interrupted by one or more -O- groups. W is -F, -SO2Z, -CF=CF2, -O-CF=CF2, or -O-CF2-CF=CF2. Z is -F, - Cl, -NR1 2, or -OM. Each R1 is a hydrogen atom or alkyl having up to four carbon atoms. M is an alkyl group, a trimethylsilyl group, a hydrogen atom, a metallic cation, or a quaternary ammonium cation. R is a bromine, chloride, fluorine or hydrogen atom; and RF is a fluorinated alkenyl group that is unsubstituted or substituted by at least one chlorine atom, aryl group, or a combination thereof or RF is a fluorinated alkyl group or arylalkylenyl group that is substituted by bromine or iodine and uninterrupted or interrupted by at least one -O- group. A process for making the compound is also disclosed. A fluoropolymer made from the compound and a method of making the fluoropolymer are also disclosed.

  多功能化合物由公式X-C（R）RF-Y表示，其中X和Y分别独立为-C（O）-O-M，-C（O）-HAL，-C（O）-NR1 2，-C≡N，-C（O）NR1-SO2-Rf1-W或者是一种可选地由一个或多个-O-组分隔的氟代烯基。HAL为-F，-Cl或-Br。Rf1是一种可选地由一个或多个-O-组分隔的氟代烷基。W为-F，-SO2Z，-CF=CF2，-O-CF=CF2或-O-CF2-CF=CF2。Z为-F，-Cl，-NR1 2或-OM。每个R1是一个氢原子或具有最多四个碳原子的烷基。M是一种烷基，三甲基硅基，氢原子，金属阳离子或季铵阳离子。R是溴，氯，氟或氢原子；RF是一种未被取代或被至少一个氯原子，芳基或两者的组合所取代的氟代烯基，或者RF是一种被溴或碘取代并且被至少一个-O-组所中断或未中断的氟代烷基或芳基烷基。还公开了制备该化合物的方法。还公开了由该化合物制成的氟聚合物以及制备氟聚合物的方法。
• Peroxy dicarbonates, polymerization method and curing process
  申请人：Argus Chemical Corporation

  公开号：EP0032526A1

  公开（公告）日：1981-07-29

  Novel peroxydicarbonates are provided in which the alkyl carbonate moiety is 2-alkyl-2-phenyl substituted. The compounds are useful as polymerization initiators of ethylenically unsaturated monomers, such as vinyl chloride, and as catalysts of unsaturated polyester resins. The subject peroxydicarbonates are characterized in that they are solid at room temperature, have ambient temperature stability in spite of a low 10 hour half-life temperature, and can normally be transported and stored without refrigeration.

  本发明提供了新型过氧化二碳酸盐，其中的碳酸烷基被 2-烷基-2-苯基取代。这些化合物可用作乙烯基不饱和单体（如氯乙烯）的聚合引发剂和不饱和聚酯树脂的催化剂。所述过氧化二碳酸盐的特点是在室温下为固体，尽管半衰期低至 10 小时，但在环境温度下具有稳定性，通常无需冷藏即可运输和储存。
• Reaction of t-alkylhydrazinium salts and organic peroxides to foam unsaturated polyester resins
  申请人：PENNWALT CORPORATION

  公开号：EP0106938A2

  公开（公告）日：1984-05-02

  @ Low density foams are prepared from an admixture which comprises a medium which is polymerizable and/or crosslinkable by free radical initiation, a t-alkylhydrazinium salt blowing agent, a peroxide curing agent, a suitable surfactant, and at least one transition metal salt promoter wherein at least one of the metal salts is a compound of iron or copper. The t-alkylhydrazinium salt blowing agent in the presence of an effective amount of the transitional metal salt promoter improves the efficiency of the process.

  低密度泡沫由一种混合物制备而成，该混合物包括可通过自由基引发聚合和/或交联的介质、t-烷基肼盐发泡剂、过氧化物固化剂、适当的表面活性剂和至少一种过渡金属盐促进剂，其中至少一种金属盐是铁或铜的化合物。t-烷基肼盐发泡剂在有效量的过渡金属盐促进剂存在下可提高工艺的效率。
• Aqueous suspension polymerization process
  申请人：XEROX CORPORATION

  公开号：EP0115704A1

  公开（公告）日：1984-08-15

  A process for forming a copolymer of styrene and butadiene in which an aqueous mixture comprising water, styrene monomer, butadiene monomer, a suspension stabilizing agent, and a chain-propagating amount of a free radical polymerization initiator insoluble in water, soluble in the styrene monomer and soluble in the butadiene monomer is heated in an inert atmosphere to a temperature between about 50°C and about 130°C in the absence of redox initiators and mercaptan compounds until the monomers form an aqueous suspension of discrete copolymer particles having a Tg value of between about 45°C and 65°C and a weight average molecular weight of between about 10,000 and about 250,000. Increased molecular weight distribution of the final copolymer may be achieved by introducing additional styrene monomer, butadiene monomer, suspension stabilizing agent and initiator to the aqueous mixture at least once during the heating step. Optimum yields are achieved by heating the aqueous mixture with at least two different initiators in accordance with a predetermined multistage heating profile.

  一种形成苯乙烯和丁二烯共聚物的工艺，其中包括水、苯乙烯单体、丁二烯单体、悬浮稳定剂和一定量的不溶于水的自由基聚合引发剂的水性混合物、在没有氧化还原引发剂和硫醇化合物的情况下，在惰性气氛中加热至约 50°C 至约 130°C 的温度，直到单体形成离散共聚物颗粒的水悬浮液，其 Tg 值在约 45°C 至 65°C 之间，重量平均分子量在约 10,000 至约 250,000 之间。通过在加热步骤中至少一次向水性混合物中引入额外的苯乙烯单体、丁二烯单体、悬浮稳定剂和引发剂，可以增加最终共聚物的分子量分布。按照预定的多级加热曲线，用至少两种不同的引发剂加热水性混合物，可获得最佳产量。
• Lens composition, articles and method of manufacture
  申请人：PARAGON OPTICAL INC

  公开号：EP0184924A2

  公开（公告）日：1986-06-18

  A copolymer composition, especially suited for fabricating optical lenses comprising a copolymer of copolymerized comonomers which include about one to about forty percent by weight of an acryloxyalkylsilanol; about one to about seventy five percent by weight of a polyacryloxyalkylpolysiloxane; about one to about seventy five percent by weight of an siloxy substituted ester of acrylic or methacrylic acid; and from about one to about 35 percent by weight of an alkyl or cycloalkyl acrylate or methacrylate having from one to twenty carbon atoms. Contact lenses and contact lens buttons are formed of such copolymer of copolymerized comonomers by conventional techniques, by injection molding, and by compression molding.

  一种共聚物组合物，特别适用于制造光学镜片，它由共聚单体的共聚物组成，共聚单体包括约 1%至约 40%（按重量计）的丙烯酰氧基烷基硅醇；约 1%至约 75%（按重量计）的聚丙烯酰氧基烷基聚硅氧烷；约 1%至约 75%（按重量计）的丙烯酸或甲基丙烯酸的硅氧基取代酯；以及约 1%至约 35%（按重量计）的具有 1 至 20 个碳原子的丙烯酸酯或甲基丙烯酸酯烷基或环烷基。 隐形眼镜和隐形眼镜钮扣是由这种共聚单体的共聚物通过常规技术、注射成型和压缩成型形成的。