全氟己基乙基氯代丙烯酸酯 | 96383-55-0

• 物质功能分类: 有机原料 - 有机氟化合物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 全氟己基乙基氯代丙烯酸酯
• 英文名称: perfluorohexylethyl 2-chloroacrylate
• 英文别名: ((Perfluorohexyl)ethyl)-2-chloropropenoate；3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-chloroprop-2-enoate
• CAS: 96383-55-0
• 化学式: C₁₁H₆ClF₁₃O₂
• 分子量: 452.6
• InChiKey: HIRPFUWZIZCTAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  27
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  15

文献信息

• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• STAIN-PROOFING AGENT COMPOSITION, METHOD FOR PRODUCING THE SAME AND ARTICLE PROCESSED WITH THE SAME
  申请人：Asahi Glass Company, Limited

  公开号：EP2149591A1

  公开（公告）日：2010-02-03

  To provide an antifouling composition which is an fluorine-type antifouling composition using a short chain perfluoroalkyl group and which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has excellent soil release properties. An antifouling composition comprising a fluorocopolymer which comprises from 30 to 70 mass% of polymerized units (a') having a C1-6 perfluoroalkyl group, from 20 to 69 mass% of polymerized units (b') having an alkylene oxide chain and from 1 to 10 mass% of polymerized units (c') having an amino group, and which has anionic groups at its main chain terminals.

  提供一种防污组合物，它是一种使用短链全氟烷基的氟型防污组合物，可以以水分散液的形式制成，基本上不含挥发性有机溶剂，并具有优异的土壤释放性能。 一种由含氟聚合物组成的防污组合物，该聚合物包含 30 至 70 质量％的具有 C1-6 全氟烷基的聚合单元 (a')、20 至 69 质量％的具有环氧乙烷链的聚合单元 (b')以及 1 至 10 质量％的具有氨基的聚合单元 (c')，并且在其主链末端具有阴离子基团。
• STAIN-PROOFING AGENT COMPOSITION, METHOD FOR PRODUCING THE SAME, AND ARTICLE PROCESSED WITH THE SAME
  申请人：Asahi Glass Company, Limited

  公开号：EP2147961A1

  公开（公告）日：2010-01-27

  To provide an antifouling composition which is a fluorine-type antifouling composition using a short chain perfluoroalkyl group and which is excellent in antifouling properties and water/oil repellency and presents good durability against washing. An antifouling composition comprising a fluorocopolymer which comprises from 30 to 65 mass% of polymerized units (a) having a C1-6 perfluoroalkyl group, from 1 to 67 mass% of polymerized units (b1) having -(C2H4O)- and from 3 to 34 mass% of polymerized units (b2) having -(C4H8O)-, wherein the content of -(C2H4O)- is from 20 to 65 mass%, and the content of -(C4H8O)- is from 2 to 13 mass%.

  提供一种防污组合物，它是一种使用短链全氟烷基的氟型防污组合物，具有优异的防污性能和拒水/拒油性能，并具有良好的耐洗持久性。 一种由含氟聚合物组成的防污组合物，其包含 30 至 65 质量％的具有 C1-6 全氟烷基的聚合单元 (a)、1 至 67 质量％的具有-(C2H4O)-的聚合单元 (b1) 以及 3 至 34 质量％的具有-(C4H8O)-的聚合单元 (b2)，其中-( )-的含量为 20 至 65 质量％，而-( )-的含量为 2 至 13 质量％。
• POLYMER, POSITIVE RESIST COMPOSITION, AND RESIST PATTERN FORMING METHOD
  申请人：Zeon Corporation

  公开号：EP3409700A1

  公开（公告）日：2018-12-05

  A polymer includes a monomer unit (A) represented by general formula (I), shown below, and a monomer unit (B) represented by general formula (II), shown below, wherein at least one of the monomer unit (A) and the monomer unit (B) includes at least one fluorine atom. In the formulae, R1 is a chlorine atom, a fluorine atom, or a fluorine atom-substituted alkyl group, R2 is an unsubstituted alkyl group or a fluorine atom-substituted alkyl group, R3 to R6, R8, and R9 are each a hydrogen atom, a fluorine atom, an unsubstituted alkyl group, or a fluorine atom-substituted alkyl group, R7 is a hydrogen atom, an unsubstituted alkyl group, or a fluorine atom-substituted alkyl group, p and q are each an integer of at least 0 and not more than 5, and p + q = 5.

  聚合物包括下图所示通式(I)代表的单体单元(A)和下图所示通式(II)代表的单体单元(B)，其中单体单元(A)和单体单元(B)中至少有一个包括至少一个氟原子。式中，R1 是氯原子、氟原子或氟原子取代的烷基，R2 是未取代的烷基或氟原子取代的烷基，R3 至 R6、R8 和 R9 分别是氢原子、氟原子、未取代的烷基、氟原子或氟原子取代的烷基、R7 是氢原子、未取代的烷基或氟原子取代的烷基，p 和 q 分别是至少 0 但不超过 5 的整数，且 p + q = 5。
• CURABLE COMPOSITION, METHOD FOR PRODUCING SAME, AND ARTICLE PRODUCED THEREWITH
  申请人：Daikin Industries, Ltd.

  公开号：EP3483193A1

  公开（公告）日：2019-05-15

  The present invention provides a curable composition comprising a compound having a perfluoropolyether group and a curable moiety, and a curable resin and/or a curable monomer, wherein an organic solvent having no radical reactive group is not substantially contained. The present invention provides a curable composition capable of forming a surface-treating layer that is in a lower clouded state.

  本发明提供了一种可固化组合物，该组合物包含具有全氟聚醚基团和可固化分子的化合物，以及可固化树脂和/或可固化单体，其中基本不含不含自由基反应基团的有机溶剂。本发明提供了一种可固化组合物，该组合物能够形成处于较低混浊状态的表面处理层。