冰染重氮组分 1 | 27165-25-9

• 物质功能分类: 有机原料 - 重氮、偶氮或氧化偶氮化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 冰染重氮组分 1
• 中文别名: 4-甲氧基-2-硝基重氮苯；耐晒枣红GP；冰染重氮组分1
• 英文名称: 2-Nitro-4-methoxybenzendiazonium
• 英文别名: 4-Methoxy-2-nitrobenzoldiazonium；2-Nitro-4-methoxybenzoldiazonium；4-methoxy-2-nitrobenzenediazonium
• CAS: 27165-25-9
• 化学式: C₇H₆N₃O₃
• 分子量: 180.143
• InChiKey: JKIJZOTYFAEPKB-UHFFFAOYSA-N

物化性质

• LogP：
  3.38

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  83.2
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 危险品标志：
  T+
• 海关编码：
  2927000090
• 危险品运输编号：
  UN 2811 6

反应信息

• 作为反应物：
  描述：

  冰染重氮组分 1 、 10-甲氧基双环[4.4.1]十一碳-1,3,5,7,9-五烯 在 硫酸 作用下， 以 乙醚 、 溶剂黄146 为溶剂， 以27%的产率得到5-[(4-Methoxy-2-nitro-phenyl)-hydrazono]-bicyclo[4.4.1]undeca-1(10),3,6,8-tetraen-2-one
  参考文献：
  名称：

  一类新的重氮盐与 2- 和 3-烷氧基-1,6-甲氧基-[10]-环烯的染料偶联反应的合成

  摘要：

  2-和3-烷氧基-1,6-甲氧基-[10]-环烯与芳基重氮盐偶联，产生相应的醌腙作为环庚三烯衍生物。讨论了分析数据。

  DOI：

  10.1246/cl.1983.653
• 作为产物：
  描述：

  syn-2-Nitro-4-methoxyphenylazoethylether 以 乙醇 为溶剂， 生成 1-羟乙基自由基 、 冰染重氮组分 1
  参考文献：
  名称：

  Broxton, Trevor J.; McLeish, Michael J., Australian Journal of Chemistry, 1982, vol. 35, # 2, p. 319 - 330

  摘要：

  DOI：

文献信息

• Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones
  作者：Lorenzo Di Terlizzi、Simone Scaringi、Carlotta Raviola、Riccardo Pedrazzani、Marco Bandini、Maurizio Fagnoni、Stefano Protti

  DOI：10.1021/acs.joc.2c00225

  日期：2022.4.1

  The preparation of symmetrical (hetero)biaryls via arylazo sulfones has been successfully carried out upon visible light irradiation in the presence of PPh3AuCl as the catalyst. The present protocol led to the efficient synthesis of a wide range of target compounds in an organic-aqueous solvent under photocatalyst-free conditions.

  在PPh 3 AuCl作为催化剂的情况下，在可见光照射下成功地通过芳基偶氮砜制备了对称（杂）联芳基化合物。本方案可以在无光催化剂的条件下在有机水溶剂中有效合成多种目标化合物。
• Method of applying nanoparticles
  申请人：——

  公开号：US20020150678A1

  公开（公告）日：2002-10-17

  Coating compositions, methods and articles of manufacture comprising a nanoparticle system employing same to impart surface modifying benefits for all types of soft surfaces, and in some cases, hard surfaces, are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of coating compositions, methods and articles of manufacture that create multi-use benefits to the modified surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that, in some embodiments, may include at least one of the following improved surface properties: cleaning, wettability, liquid strike-through, comfort, stain resistance, soil removal, malodor control, modification of surface friction, reduced damage to abrasion and color enhancement, relative to the surfaces unmodified with such nanoparticle systems.

  本发明公开了包含纳米粒子系统的涂料组合物、方法和制品，采用纳米粒子系统可为所有类型的软表面以及某些情况下的硬表面带来表面改性效果。在某些实施例中，将纳米粒子分散在合适的载体介质中，可制成涂层组合物、方法和制造品，为改性表面带来多种用途的益处。这些表面改性可产生长期或半永久性的多用途益处，在某些实施例中，可包括以下至少一种改进的表面特性：相对于未使用此类纳米粒子系统改性的表面，具有清洁、润湿、液体渗透、舒适、抗污、去污、恶臭控制、表面摩擦改性、减少磨损损伤和增色等特性。
• Coating compositions for modifying surfaces
  申请人：——

  公开号：US20020151634A1

  公开（公告）日：2002-10-17

  Coating compositions, methods and articles of manufacture comprising a nanoparticle system employing same to impart surface modifying benefits for all types of soft surfaces, and in some cases, hard surfaces, are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of coating compositions, methods and articles of manufacture that create multi-use benefits to the modified surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that, in some embodiments, may include at least one of the following improved surface properties: cleaning, wettability, liquid strike-through, comfort, stain resistance, soil removal, malodor control, modification of surface friction, reduced damage to abrasion and color enhancement, relative to the surfaces unmodified with such nanoparticle systems.

  本发明公开了包含纳米粒子系统的涂料组合物、方法和制品，采用纳米粒子系统可为所有类型的软表面以及某些情况下的硬表面带来表面改性效果。在某些实施例中，将纳米粒子分散在合适的载体介质中，可制成涂层组合物、方法和制造品，为改性表面带来多种用途的益处。这些表面改性可产生长期或半永久性的多用途益处，在某些实施例中，可包括以下至少一种改进的表面特性：相对于未使用此类纳米粒子系统改性的表面，具有清洁、润湿、液体渗透、舒适、抗污、去污、恶臭控制、表面摩擦改性、减少磨损损伤和增色等特性。
• Enhancement of color on surfaces
  申请人：The Procter & Gamble Company

  公开号：US20020160159A1

  公开（公告）日：2002-10-31

  Coating compositions, methods and articles of manufacture comprising a nanoparticle system employing same to impart surface modifying benefits for all types of soft surfaces, and in some cases, hard surfaces, are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of coating compositions, methods and articles of manufacture that create multi-use benefits to the modified surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that, in some embodiments, may include at least one of the following improved surface properties: cleaning, wettability, liquid strike-through, comfort, stain resistance, soil removal, malodor control, modification of surface friction, reduced damage to abrasion and color enhancement, relative to the surfaces unmodified with such nanoparticle systems.

  本发明公开了包含纳米粒子系统的涂料组合物、方法和制品，采用纳米粒子系统可为所有类型的软表面以及某些情况下的硬表面带来表面改性效果。在某些实施例中，将纳米粒子分散在合适的载体介质中，可制成涂层组合物、方法和制造品，为改性表面带来多种用途的益处。这些表面改性可产生长期或半永久性的多用途益处，在某些实施例中，可包括以下至少一种改进的表面特性：相对于未使用此类纳米粒子系统改性的表面，具有清洁、润湿、液体渗透、舒适、抗污、去污、恶臭控制、表面摩擦改性、减少磨损损伤和增色等特性。
• Method of hydrophilizing materials
  申请人：——

  公开号：US20020192366A1

  公开（公告）日：2002-12-19

  Coating compositions, methods and articles of manufacture comprising a nanoparticle system employing same to impart surface modifying benefits for all types of soft surfaces, and in some cases, hard surfaces, are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of coating compositions, methods and articles of manufacture that create multi-use benefits to the modified surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that, in some embodiments, may include at least one of the following improved surface properties: cleaning, wettability, liquid strike-through, comfort, stain resistance, soil removal, malodor control, modification of surface friction, reduced damage to abrasion and color enhancement, relative to the surfaces unmodified with such nanoparticle systems.

  本发明公开了包含纳米粒子系统的涂料组合物、方法和制品，采用纳米粒子系统可为所有类型的软表面以及某些情况下的硬表面带来表面改性效果。在某些实施例中，将纳米粒子分散在合适的载体介质中，可制成涂层组合物、方法和制造品，为改性表面带来多种用途的益处。这些表面改性可产生长期或半永久性的多用途益处，在某些实施例中，可包括以下至少一种改进的表面特性：相对于未使用此类纳米粒子系统改性的表面，具有清洁、润湿、液体渗透、舒适、抗污、去污、恶臭控制、表面摩擦改性、减少磨损损伤和增色等特性。