7,7,13,13-tetramethyl-5-phenyl-7,13-dihydro-5H-indeno[1,2-b]acridin

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7,7,13,13-tetramethyl-5-phenyl-7,13-dihydro-5H-indeno[1,2-b]acridin
• 英文别名: 10,10,21,21-tetramethyl-14-phenyl-14-azapentacyclo[11.8.0.03,11.04,9.015,20]henicosa-1(13),2,4,6,8,11,15,17,19-nonaene
• 化学式: C₃₀H₂₇N
• 分子量: 401.551
• InChiKey: FYPQEUGWVMQCOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  31
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  7,7,13,13-tetramethyl-5-phenyl-7,13-dihydro-5H-indeno[1,2-b]acridin 在 N-溴代丁二酰亚胺(NBS) 、 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 乙醇 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 4.0h， 生成 7,7,13,13-tetramethyl-5-phenyl-2-(9-phenyl-9H-carbazol-3-yl)-7,13-dihydro-5H-indeno[1,2-b]acridin
  参考文献：
  名称：

  COMPOUND HAVING INDENO ACRIDAN RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENCE ELEMENT

  摘要：

  公开号：

  EP2894155B1
• 作为产物：
  描述：

  2-碘-9,9-二甲基芴 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 叔丁基膦 、 磷酸 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 5,5-dimethyl-1,3-cyclohexadiene 、 甲苯 为溶剂， 反应 10.0h， 生成 7,7,13,13-tetramethyl-5-phenyl-7,13-dihydro-5H-indeno[1,2-b]acridin
  参考文献：
  名称：

  COMPOUND HAVING INDENO ACRIDAN RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENCE ELEMENT

  摘要：

  公开号：

  EP2894155B1

文献信息

• 一种以咔唑为核心的化合物及其在有机电致发光器件上的应用
  申请人：江苏三月光电科技有限公司

  公开号：CN110577488A

  公开（公告）日：2019-12-17

  本发明涉及一种以咔唑为核心的化合物及其制备方法与应用，所述化合物的结构以咔唑与三苯胺结构以碳氮键相连，碳氮键连接避免了活泼位置裸露；咔唑与二苯并五元环通过碳碳键相连，提高了材料化学稳定性，而且整个分子是一个较大的刚性结构，具有高的三线态能级(T1)；且空间位阻大，不易转动，立体空间结构更稳定，因此化合物具有较高的玻璃化温度和分子热稳定性；另外，本发明化合物的HOMO和LUMO分布位置相互分开，使其具有了合适的HOMO和LUMO能级；因此，本发明化合物应用于OLED器件后，可有效提升器件的发光效率及使用寿命。
• COMPOUND HAVING INDENOACRIDAN RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：US20150249218A1

  公开（公告）日：2015-09-03

  An organic compound with excellent characteristics excelling in hole injecting and transporting performance and having an electron-blocking ability, high stability in a thin film state and excellent heat resistance is provided as a material for an organic electroluminescent device of high efficiency and high durability, and the organic electroluminescent device of high luminous efficiency and high durability is provided using this compound. The compound of a general formula (1) having an indenoacridan ring structure is used as a constituent material of at least one organic layer in the organic electroluminescent device that includes a pair of electrodes and one or more organic layers sandwiched between the pair of electrodes.

  提供一种具有出色的孔注入和传输性能、具有阻挡电子的能力、在薄膜状态下具有高稳定性和优异的耐热性的有机化合物，作为高效和高耐久性的有机电致发光器件的材料，并且使用该化合物提供具有高发光效率和高耐久性的有机电致发光器件。所述通式（1）的化合物具有茚并蒽环结构，作为至少一个有机层的组成材料，用于包括一对电极和一对电极之间夹有一个或多个有机层的有机电致发光器件。
• Photoelectric conversion material, film containing the material, photoelectric conversion device, method for preparing photoelectric conversion device, method for using photoelectric conversion device, photosensor and imaging device
  申请人：FUJIFILM CORPORATION

  公开号：US09349965B2

  公开（公告）日：2016-05-24

  There is provided a compound represented by a specific formula, which has an absorption maximum at 400 nm or more and less than 720 nm in a UV-visible absorption spectrum, wherein a molar extinction coefficient is 10,000 mol−1·l·cm−1 or more at the absorption maximum wavelength, and a difference between a melting point and a deposition temperature (a melting point−a deposition temperature) is 31° C. or more.

  提供一种化合物，其具有特定的化学式，其在紫外可见吸收光谱中在400纳米或更长波长处具有最大吸收，但小于720纳米，其中在最大吸收波长处的摩尔消光系数为10,000 mol−1·l·cm−1或更高，熔点与沉积温度之间的差值（熔点−沉积温度）为31°C或更高。
• PHOTOELECTRIC CONVERSION MATERIAL, FILM CONTAINING THE MATERIAL, PHOTOELECTRIC CONVERSION DEVICE, METHOD FOR PREPARING PHOTOELECTRIC CONVERSION DEVICE, METHOD FOR USING PHOTOELECTRIC CONVERSION DEVICE, PHOTOSENSOR AND IMAGING DEVICE
  申请人：FUJIFILM CORPORATION

  公开号：US20130181202A1

  公开（公告）日：2013-07-18

  There is provided a compound represented by a specific formula, which has an absorption maximum at 400 nm or more and less than 720 nm in a UV-visible absorption spectrum, wherein a molar extinction coefficient is 10,000 mol −1 ·l·cm −1 or more at the absorption maximum wavelength, and a difference between a melting point and a deposition temperature (a melting point−a deposition temperature) is 31° C. or more.
• PHOTOELECTRIC CONVERSION ELEMENT, METHOD FOR USING THE SAME, IMAGING DEVICE, PHOTOSENSOR, AND COMPOUND
  申请人：FUJIFILM Corporation

  公开号：US20140374733A1

  公开（公告）日：2014-12-25

  An object of the present invention is to provide a photoelectric conversion element having a photoelectric conversion film which exhibits heat resistance, a high photoelectric conversion efficiency, a low level of dark currents, rapid response, and sensitivity characteristics to red and can be produced by a vapor deposition processing that is continuously performed under a high-temperature condition. The photoelectric conversion element of the present invention is a photoelectric conversion element in which a conductive film, a photoelectric conversion film containing a photoelectric conversion material, and a transparent conductive film are laminated on one another in this order, wherein the photoelectric conversion material includes a compound represented by Formula (1).