(2-甲基-5-丙-2-基-环己基)乙酸酯 | 7460-78-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: (2-甲基-5-丙-2-基-环己基)乙酸酯
• 英文名称: 2-methyl-5-(propan-2-yl)cyclohexyl acetate
• 英文别名: adamantane；O-Acetyl-carvomenthol；dl-Carvomenthyl-acetat；acetic acid p-menthan-2-yl ester；Essigsaeure-p-menthan-2-ylester；(2-methyl-5-propan-2-ylcyclohexyl) acetate
• CAS: 7460-78-8
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: JAKFDYGDDRCJLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2-甲基-5-丙-2-基-环己基)乙酸酯 在 iron(III) chloride 、 胸腺嘧啶-1-乙酸 、 双氧水 作用下， 以 水 、 乙腈 为溶剂， 反应 10.0h， 以10%的产率得到adamantane
  参考文献：
  名称：

  From DNA to catalysis: a thymine-acetate ligated non-heme iron(iii) catalyst for oxidative activation of aliphatic C–H bonds

  摘要：

  一种非血红素、铁（III）/THA（胸腺嘧啶-1-醋酸酯）催化剂与H₂O₂作为氧化剂一起对烷烃进行氧化C-H活化效率高。

  DOI：

  10.1039/c5cc07597a
• 作为产物：
  描述：

  3-异丙基-6-甲基-2-环己烯-1-酮 在 4-二甲氨基吡啶 、 氢气 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 60.0~110.0 ℃ 、3.0 MPa 条件下， 反应 29.5h， 生成 (2-甲基-5-丙-2-基-环己基)乙酸酯
  参考文献：
  名称：

  ESTERS AND ETHERS OF 5-ISOPROPYL-2-METHYLCYCLOHEXAN-1-OL AS FRAGRANCE INGREDIENTS

  摘要：

  The present invention relates to the use of a compound of formula (I) or of its mixtures with a compound of formula (II) where R and the dotted line are as defined in the claims and the description, as aroma ingredient, to the use thereof to impart an aroma to a composition, and to a method of imparting an aroma to a composition. The present invention further relates to a composition comprising the compound of formula (I) or a mixture thereof with compound (II), to mixtures of the compound of formula (I) with the compound (II), and to specific compounds of formula (I).

  公开号：

  WO2024115760A1

文献信息

• A new ferrocene-based bulky pyridine as an efficient reusable homogeneous catalyst
  作者：Bishwapran Kashyap、Prodeep Phukan

  DOI：10.1039/c3ra41674g

  日期：——

  An effective approach to reusing a homogeneous catalyst has been demonstrated. A ferrocene-based bulky pyridine has been synthesized and utilized as a homogeneous catalyst for the synthesis of benzoylfumarates as well as for acetylation. After the reaction, the catalyst was separated by simple precipitation and reused without appreciable loss of activity.

  已经证明了一种有效的方法来重复使用均相催化剂。合成了基于二茂铁的大体积吡啶，并将其用作均相催化剂，用于合成苯甲酰富马酸酯以及乙酰化反应。反应后，催化剂通过简单的沉淀分离出来，并且可以重复使用而不会显著损失活性。
• Cycloalkylamides and their therapeutic applications
  申请人：——

  公开号：US20040209858A1

  公开（公告）日：2004-10-21

  The present invention relates to the use of compounds of formula (I) 1 for the treatment of a variety of disorders including, but not limited to, epilepsy, bipolar disorder, psychiatric disorders, migraine, pain, neuroprotection, and movement disorders.

  本发明涉及使用式(I)1的化合物治疗多种疾病，包括但不限于癫痫、双相情感障碍、精神障碍、偏头痛、疼痛、神经保护和运动障碍。
• Biomass derived β-cyclodextrin-SO₃H as a solid acid catalyst for esterification of carboxylic acids with alcohols
  作者：Raju S. Thombal、Amol R. Jadhav、Vrushali H. Jadhav

  DOI：10.1039/c4ra16699j

  日期：——

  A novel b-cyclodextrin-SO₃H carbon based solid acid catalyst was prepared and proved highly efficient in solvent free esterification of carboxylic acids with alcohols. The catalyst was easily recovered and reused without any impact on the yields.

  一种新型的基于b-环糊精-SO3H的碳固体酸催化剂被制备出来，并在无溶剂酯化反应中证明具有高效率。该催化剂容易回收和重复使用，不会对产率产生任何影响。
• Synthesis of Some Alkyl Acetates From Alcohols Catalyzed by H₅PW₁₀V₂O₄₀and H₅PMo₁₀V₂O₄₀Under Microwave Irradiation(Part 2)
  作者：Reza Tayebee、Farokhzad Mohammadi Zonoz

  DOI：10.5012/jkcs.2011.55.3.541

  日期：2011.6.20
• From DNA to catalysis: a thymine-acetate ligated non-heme iron(<scp>iii</scp>) catalyst for oxidative activation of aliphatic C–H bonds
  作者：Afnan Al-hunaiti、Minnä Räisänen、Timo Repo

  DOI：10.1039/c5cc07597a

  日期：——

  A non-heme, iron(iii)/THA(thymine-1-acetate) catalyst together with H₂O₂ as an oxidant is efficient in oxidative C–H activation of alkanes.

  一种非血红素、铁（III）/THA（胸腺嘧啶-1-醋酸酯）催化剂与H₂O₂作为氧化剂一起对烷烃进行氧化C-H活化效率高。