异丙醇铒 | 14814-07-4

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机铋、钴、镨、钆、镓、铱、铼、钇、铽等
• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 异丙醇铒
• 中文别名: 异丙醇铒(III)；异丙氧化铒；异丙氧基铒
• 英文名称: Erbium(Iii) Isopropoxide
• 英文别名: erbium(3+);propan-2-olate
• CAS: 14814-07-4
• 化学式: C9H21ErO3
• 分子量: 344.52
• InChiKey: VOCNVTAXVORJBI-UHFFFAOYSA-N

物化性质

• 熔点：
  325 °C
• 闪点：
  58 °C
• 稳定性/保质期：
  在常温常压下稳定，应避免接触水分、潮湿以及氧化物。

计算性质

• 辛醇/水分配系数(LogP)：
  -0.73
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  69.2
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• TSCA：
  Yes
• 危险等级：
  4.1
• 危险品标志：
  C
• 安全说明：
  S16,S36/37/39,S45,S7/9
• 危险类别码：
  R11,R34
• 海关编码：
  28469000
• 包装等级：
  II
• 危险类别：
  4.1
• 危险品运输编号：
  UN 2925

SDS

Name:	Erbium isopropoxide Material Safety Data Sheet
Synonym:	Erbium triisopropoxide
CAS:	14814-07-4

Section 1 - Chemical Product MSDS Name:Erbium isopropoxide Material Safety Data Sheet
Synonym:Erbium triisopropoxide

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
14814-07-4	Erbium isopropoxide	100	unlisted

Hazard Symbols: F C
Risk Phrases: 11 34

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute exposure.

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Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Flammable solid.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Remove all sources of ignition. Use a spark-proof tool.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not breathe dust. Keep away from heat, sparks and flame.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Flammables-area. Store protected from moisture.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14814-07-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: pink
Odor: alcohol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 58 deg C ( 136.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 325 deg C
Solubility in water: Reacts.
Specific Gravity/Density:
Molecular Formula: C9H21ErO3
Molecular Weight: 344.52

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Ignition sources, dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, isopropanol.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 14814-07-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Erbium isopropoxide - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 34 Causes burns.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 14814-07-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 14814-07-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14814-07-4 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

文献信息

• Catalyst for conjugated diene polymerization, conjugated diene polymer, modified conjugated diene polymer, polybutadiene, and compositions comprising foregoing
  申请人：UBE INDUSTRIES, LTD.

  公开号：US10053526B2

  公开（公告）日：2018-08-21

  A catalyst for a conjugated diene polymerization including a metal compound (A) containing terbium, lanthanum, dysprosium, praseodymium, holmium, erbium, thulium, or gadolinium, an ionic compound (B) consisting of a non-coordinating anion and a cation, and an organic metal compound (C) of an element selected from the groups 2, 12 and 13 of the periodic table; a process for producing a conjugated diene polymer and a modified conjugated diene polymer using the same; a conjugated diene polymer; and a modified conjugated diene polymer.

  一种共轭二烯聚合催化剂，包括含有铽、镧、镝、镨、钬、铒、铥或钆的金属化合物（A），由非配位阴离子和阳离子组成的离子化合物（B），以及选自元素周期表第 2、12 和 13 族的元素的有机金属化合物（C）；用其生产共轭二烯聚合物和改性共轭二烯聚合物的工艺； 共轭二烯聚合物；以及改性共轭二烯聚合物。
• Fine Pattern Transfer Material
  申请人：Fujita Toshio

  公开号：US20100093907A1

  公开（公告）日：2010-04-15

  A transfer material that can favorably form a fine pattern by nanoimprinting. The nanoimprinting transfer material is a fine pattern resin composition that includes an organosilicon compound and a metal compound of a metal from groups 3 through 14 of the periodic table.
• CATALYST FOR CONJUGATED DIENE POLYMERIZATION, CONJUGATED DIENE POLYMER, MODIFIED CONJUGATED DIENE POLYMER, POLYBUTADIENE, AND COMPOSITIONS COMPRISING FOREGOING
  申请人：UBE INDUSTRIES, LTD.

  公开号：US20170158786A1

  公开（公告）日：2017-06-08

  A catalyst for a conjugated diene polymerization including a metal compound (A) containing terbium, lanthanum, dysprosium, praseodymium, holmium, erbium, thulium, or gadolinium, an ionic compound (B) consisting of a non-coordinating anion and a cation, and an organic metal compound (C) of an element selected from the groups 2, 12 and 13 of the periodic table; a process for producing a conjugated diene polymer and a modified conjugated diene polymer using the same; a conjugated diene polymer; and a modified conjugated diene polymer.
• US8476361B2
  申请人：——

  公开号：US8476361B2

  公开（公告）日：2013-07-02