1-乙基-1-甲基吡咯烷鎓双(三氟甲基磺酰基)亚胺 | 223436-99-5

• 物质功能分类: 有机原料 - 杂环化合物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 中文名称: 1-乙基-1-甲基吡咯烷鎓双(三氟甲基磺酰基)亚胺
• 中文别名: N-甲基,乙基吡咯烷双三氟甲磺酰亚胺盐
• 英文名称: 1-Ethyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide salt
• 英文别名: 1-ethyl-1-methylpyrrolidinium bis(tri-fluoromethanesulfonyl)amide；1-ethyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide；1-ethyl-1-methylpyrrolidiniumbis[(trifluoromethyl)sulfonyl]imide；N-ethyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)amide；N-methyl-N-ethylpyrrolidinium bis(trifluoromethanesulfonyl)amide；[Empy][Tf2N]；1-Ethyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide；bis(trifluoromethylsulfonyl)azanide;1-ethyl-1-methylpyrrolidin-1-ium
• CAS: 223436-99-5
• 化学式: C₂F₆NO₄S₂*C₇H₁₆N
• 分子量: 394.359
• InChiKey: BRVHCCPVIILNPA-UHFFFAOYSA-N

物化性质

• 熔点：
  90.1 °C

计算性质

• 辛醇/水分配系数(LogP)：
  2.31
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86
• 氢给体数：
  0
• 氢受体数：
  11

SDS

N-甲基,乙基吡咯烷双三氟甲磺酰亚胺盐MSDS英文版

反应信息

• 作为产物：
  描述：

  1-甲基吡咯烷 在 水 作用下， 以 乙腈 为溶剂， 反应 3.0h， 生成 1-乙基-1-甲基吡咯烷鎓双(三氟甲基磺酰基)亚胺
  参考文献：
  名称：

  Pyrrolidinium Imides:  A New Family of Molten Salts and Conductive Plastic Crystal Phases

  摘要：

  A new family of molten salts is reported, based on the N-alkyl, N-alkyl pyrrolidinium cation and the bis-(trifluoromethane sulfonyl)imide anion. Some of the members of the family are molten at room temperature, while the smaller and more symmetrical members have melting points around 100 degrees C. Of the room-temperature molten salt examples, the methyl butyl derivative exhibits the highest conductivity; at 2 x 10(-3) S/cm this is the highest molten salt conductivity observed to date at room temperature among the ammonium salts. This highly conductive behavior is rationalized in terms of the role of cation planarity. The salts also exhibit multiple crystalline phase behavior below their melting points and exhibit significant conductivity in at least their higher temperature crystal phase. For example, the methyl propyl derivative (mp = 12 degrees C) shows ion conductivity of 1 x 10(-6) S/cm at 0 degrees C in its higher temperature crystalline phase.

  DOI：

  10.1021/jp984145s

文献信息

• Organic ionic plastic crystal-based electrolytes for solid-state dye-sensitized solar cells
  作者：Qing Li、Xiaojian Chen、Jie Zhao、Lihua Qiu、Yueguang Zhang、Baoquan Sun、Feng Yan

  DOI：10.1039/c2jm16850b

  日期：——

  An organic ionic plastic crystal, 1-ethyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (P12TFSI), was synthesized and doped with a room temperature ionic liquid, 1-propyl-3-methylimidazolium iodide (PMII). The prepared PMII/P12TFSI solid-state electrolytes were employed for dye-sensitized solar cells (DSSCs), without using any volatile organic solvent. The fabricated solid-state DSSCs yielded a power conversion efficiency of 5.12% under simulated air mass 1.5 solar spectrum illuminations at 50 mW cm−2. The superior long-term stability of the fabricated solid-state DSSCs indicated that the synthesized PMII/P12TFSI solid-state electrolytes could overcome the drawbacks of cells containing volatile solvents.

  合成了一种有机离子塑料晶体--1-乙基-1-甲基吡咯烷鎓双(三氟甲磺酰基)亚胺（P12TFSI），并在其中掺杂了一种室温离子液体--1-丙基-3-甲基碘化咪唑鎓（PMII）。制备的 PMII/P12TFSI 固态电解质被用于染料敏化太阳能电池（DSSC），无需使用任何挥发性有机溶剂。所制备的固态 DSSC 在 50 mW cm-2 的模拟空气质量 1.5 太阳光谱照射下的功率转换效率为 5.12%。所制备的固态 DSSC 具有优异的长期稳定性，这表明合成的 PMII/P12TFSI 固态电解质可以克服含有挥发性溶剂的电池的缺点。
• PROCEDE D'HYDROFORMYLATION METTANT EN OEUVRE UN CATALYSEUR A BASE DE COBALT DANS UN LIQUIDE IONIQUE NON-AQUEUX
  申请人：IFP Energies nouvelles

  公开号：EP2043991B1

  公开（公告）日：2011-08-31
• DERMATOLOGISCHE, PHARMAZEUTISCHE ZUSAMMENSETZUNG GEEIGNET FÜR OLIGONUKLEOTIDE
  申请人：Sterna Biologicals GmbH & Co. Kg

  公开号：EP2533763A2

  公开（公告）日：2012-12-19
• [DE] DERMATOLOGISCHE, PHARMAZEUTISCHE ZUSAMMENSETZUNG GEEIGNET FÜR OLIGONUKLEOTIDE<br/>[EN] DERMATOLOGICAL, PHARMACEUTICAL COMPOSITION SUITABLE FOR OLIGONUCLEOTIDES<br/>[FR] COMPOSITION PHARMACEUTIQUE DERMATOLOGIQUE ADAPTÉE AUX OLIGONUCLÉOTIDES
  申请人：STERNA BIOLOG GMBH & CO KG

  公开号：WO2011098285A2

  公开（公告）日：2011-08-18

  Die vorliegende Erfindung betrifft eine kosmetische und/oder dermatologische und oder pharmazeutische Zusammensetzung für die topische Anwendung und Applikation von Oligonukleotiden, insbesondere Antisense-Oligonukleotiden wie DNAzyme, siRNAs, asDNAs oder Ribozyme zur Verwendung als Mittel gegen entzündliche Erkrankungen durch Emulsionen mit dispergierter, innenliegender, diskontinuierlicher Wasserphase.
• Pyrrolidinium Imides:  A New Family of Molten Salts and Conductive Plastic Crystal Phases
  作者：D. R. MacFarlane、P. Meakin、J. Sun、N. Amini、M. Forsyth

  DOI：10.1021/jp984145s

  日期：1999.5.1

  A new family of molten salts is reported, based on the N-alkyl, N-alkyl pyrrolidinium cation and the bis-(trifluoromethane sulfonyl)imide anion. Some of the members of the family are molten at room temperature, while the smaller and more symmetrical members have melting points around 100 degrees C. Of the room-temperature molten salt examples, the methyl butyl derivative exhibits the highest conductivity; at 2 x 10(-3) S/cm this is the highest molten salt conductivity observed to date at room temperature among the ammonium salts. This highly conductive behavior is rationalized in terms of the role of cation planarity. The salts also exhibit multiple crystalline phase behavior below their melting points and exhibit significant conductivity in at least their higher temperature crystal phase. For example, the methyl propyl derivative (mp = 12 degrees C) shows ion conductivity of 1 x 10(-6) S/cm at 0 degrees C in its higher temperature crystalline phase.