萘-1,8-二甲醇 | 15886-83-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 中文名称: 萘-1,8-二甲醇
• 英文名称: octane-1,14-diol dimesylate
• 英文别名: 1,8-Bis-(methansulfonoxy)-octan；1,8-Octanediol, dimethanesulfonate；8-methylsulfonyloxyoctyl methanesulfonate
• CAS: 15886-83-6
• 化学式: C₁₀H₂₂O₆S₂
• 分子量: 302.413
• InChiKey: ZMIHCVPWXMOTIF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  104
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  萘-1,8-二甲醇 在 magnesium 、 lithium bromide 作用下， 以 乙醚 、 丙酮 为溶剂， 生成 13-bromo-1-tridecene
  参考文献：
  名称：

  Synthesis of model long-chain ω-alkenyltrichlorosilanes and triethoxysilanes for the formation of self-assembled monolayers

  摘要：

  The synthesis of model long-chain hydrocarbons (C-13 and C-19) carrying a vinyl group and a trichloro- or a triethoxysilyl group at each end is reported. These compounds are suitable for linkage to a hydroxylate d silicon surface and at the other end with vinyl group for further functionalization and multilayer formation. (c) 2005 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2005.10.003
• 作为产物：
  描述：

  1,8-辛二醇 、 甲基磺酰氯 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以95%的产率得到萘-1,8-二甲醇
  参考文献：
  名称：

  Synthesis of model long-chain ω-alkenyltrichlorosilanes and triethoxysilanes for the formation of self-assembled monolayers

  摘要：

  The synthesis of model long-chain hydrocarbons (C-13 and C-19) carrying a vinyl group and a trichloro- or a triethoxysilyl group at each end is reported. These compounds are suitable for linkage to a hydroxylate d silicon surface and at the other end with vinyl group for further functionalization and multilayer formation. (c) 2005 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2005.10.003

文献信息

• Cheng, P.; Blumstein, A.; Subramanyam, S., Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 1995, vol. 269, p. 1 - 38
  作者：Cheng, P.、Blumstein, A.、Subramanyam, S.

  DOI：——

  日期：——
• Synthesis of model long-chain ω-alkenyltrichlorosilanes and triethoxysilanes for the formation of self-assembled monolayers
  作者：Thanh Binh Nguyen、Anne-Sophie Castanet、Thi-Huu Nguyen、Kim Phi Phung Nguyen、Jean-François Bardeau、Alain Gibaud、Jacques Mortier

  DOI：10.1016/j.tet.2005.10.003

  日期：2006.1

  The synthesis of model long-chain hydrocarbons (C-13 and C-19) carrying a vinyl group and a trichloro- or a triethoxysilyl group at each end is reported. These compounds are suitable for linkage to a hydroxylate d silicon surface and at the other end with vinyl group for further functionalization and multilayer formation. (c) 2005 Published by Elsevier Ltd.