2-methyl-5-(2-propenyl)-3-(phenylthio)-2-cyclohexenone | 75717-30-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-methyl-5-(2-propenyl)-3-(phenylthio)-2-cyclohexenone
• 英文别名: (5S)-2-methyl-3-phenylsulfanyl-5-prop-1-en-2-ylcyclohex-2-en-1-one
• CAS: 75717-30-5
• 化学式: C₁₆H₁₈OS
• 分子量: 258.384
• InChiKey: WBOMWIGPXPERAX-ZDUSSCGKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  42.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (R)-Carvone 在 对甲苯磺酸 N-氯代丁二酰亚胺 作用下， 以 四氯化碳 、 苯 为溶剂， 反应 16.0h， 生成 2-methyl-5-(2-propenyl)-3-(phenylthio)-2-cyclohexenone
  参考文献：
  名称：

  Oxidative functionalization of the .beta.-carbon in .alpha.,.beta.-unsaturated systems. Preparation of 3-phenylthio enones, acrylates, and other vinyl derivatives

  摘要：

  DOI：

  10.1021/jo00315a002

文献信息

• Insecticidal compositions and methods of using the same
  申请人：CLARKE MOSQUITO CONTROL PRODUCTS, INC.

  公开号：US10349662B2

  公开（公告）日：2019-07-16

  Insecticidal compositions have at least one active agent and at least one insecticide. The active agent can include perilla oil, a component found in perilla oil, or a perillaldehyde or carvone analog. The insecticide can include a pyrethrum, pyrethrin, pyrethroid, neonicotinoid, chlofenapyr, ethiprole, sulfoxoflor, carbamate, organophosphate, or organochlorine. Methods for controlling insects include contacting an insect with an effective amount of a composition described in this specification. Modified plants that produce an active agent can be contacted with an insecticide.

  杀虫组合物含有至少一种活性剂和至少一种杀虫剂。活性剂可包括紫苏油、紫苏油中的一种成分或紫苏醛或香芹酮类似物。杀虫剂可包括除虫菊酯、除虫菊酯、拟除虫菊酯、新烟碱类、氯虫苯甲酰胺、乙基吡咯、磺胺草醚、氨基甲酸酯、有机磷酸酯或有机氯。控制昆虫的方法包括使昆虫与有效量的本说明书所述组合物接触。可将产生活性剂的改良植物与杀虫剂接触。
• INSECTICIDAL COMPOSITIONS AND METHODS OF USING THE SAME
  申请人：Willis Michael Dean

  公开号：US20130101687A1

  公开（公告）日：2013-04-25

  Insecticidal compositions have at least one active agent and at least one insecticide. The active agent can include perilla oil, a component found in perilla oil, or a perillaldehyde or carvone analog. The insecticide can include a pyrethrum, pyrethrin, pyrethroid, neonicotinoid, chlofenapyr, ethiprole, sulfoxoflor, carbamate, organophosphate, or organochlorine. Methods for controlling insects include contacting an insect with an effective amount of a composition described in this specification. Modified plants that produce an active agent can be contacted with an insecticide.
• US8658223B2
  申请人：——

  公开号：US8658223B2

  公开（公告）日：2014-02-25
• [EN] INSECTICIDAL COMPOSITIONS AND METHODS OF USING THE SAME<br/>[FR] COMPOSITIONS INSECTICIDES ET LEURS PROCÉDÉS D'UTILISATION
  申请人：CLARKE MOSQUITO CONTROL PRODUCTS INC

  公开号：WO2013010099A1

  公开（公告）日：2013-01-17

  Insecticidal compositions have at least one active agent and at least one insecticide. The active agent can include perilla oil, a component found in perilla oil, or a perillaldehyde or carvone analog. The insecticide can include a pyrethrum, pyrethrin, pyrethroid, neonicotinoid, chlofenapyr, ethiprole, sulfoxoflor, carbamate, organophosphate, or organochlorine. Methods for controlling insects include contacting an insect with an effective amount of a composition described in this specification. Modified plants that produce an active agent can be contacted with an insecticide.