9,10-bis(4-bromophenyl)-2-tert-butyl-9,10-dihydroxy-9,10-dihydroanthracene | 869850-20-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 9,10-bis(4-bromophenyl)-2-tert-butyl-9,10-dihydroxy-9,10-dihydroanthracene
• 英文别名: 9,10-bis(4-bromophenyl)2-tert-butyl-9,10-dihydroxy-9,10-dihydroanthracene；9,10-Bis(4-bromophenyl)-2-tert-butylanthracene-9,10-diol
• CAS: 869850-20-4
• 化学式: C₃₀H₂₆Br₂O₂
• 分子量: 578.343
• InChiKey: UVJNUGADMQMZGK-UHFFFAOYSA-N

物化性质

• 沸点：
  620.6±55.0 °C(Predicted)
• 密度：
  1.504±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  34
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,10-bis(4-bromophenyl)-2-tert-butyl-9,10-dihydroxy-9,10-dihydroanthracene 在 sodium hypophosphite 、 溶剂黄146 、 potassium iodide 作用下， 反应 2.0h， 以82%的产率得到9,10-双(4-溴苯基)-2-叔丁基蒽
  参考文献：
  名称：

  [EN] ANTHRACENE DERIVATIVE, AND LIGHT-EMITTING MATERIAL, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING THE SAME
  [FR] DÉRIVÉ D'ANTHRACÈNE ET MATÉRIAU ÉLECTROLUMINESCENT, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT ET DISPOSITIF ÉLECTRONIQUE UTILISANT CEUX-CI

  摘要：

  提供了新型蒽衍生物，新型材料能够发出高纯度蓝光，并使用这些新型材料制造了发光元件、发光装置和电子设备。提供了通式（1）所表示的蒽衍生物。使用该蒽衍生物，可以提供高发射效率的发光元件。使用该蒽衍生物，可以提供发出高纯度蓝光的发光元件。在该通式中，A1表示取代或未取代的苯基，B1表示具有1至4个碳原子的烷基或取代或未取代的苯基之一，表示取代或未取代的苯基亚甲基或取代或未取代的联苯-4,4'-二基基团之一，R1至R9分别表示氢、具有1至4个碳原子的烷基或取代或未取代的苯基之一。

  公开号：

  WO2009081800A1
• 作为产物：
  描述：

  2-叔丁基蒽醌 在 正丁基锂 作用下， 以 乙醚 为溶剂， 反应 13.0h， 生成 9,10-bis(4-bromophenyl)-2-tert-butyl-9,10-dihydroxy-9,10-dihydroanthracene
  参考文献：
  名称：

  WO2007/7885

  摘要：

  公开号：

文献信息

• ANTHRACENE DERIVATIVE, AND LIGHT-EMITTING MATERIAL, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING THE SAME
  申请人：OSAKA Harue

  公开号：US20090174321A1

  公开（公告）日：2009-07-09

  Novel anthracene derivatives, novel materials capable of blue light emission with high color purity, and a light-emitting element, a light-emitting device, and an electronic device using any of the novel materials. The anthracene derivative represented by general formula (1) is provided. With the anthracene derivative, a light-emitting element with high emission efficiency can be provided. With the anthracene derivative, a light-emitting element emitting blue light with high color purity can be provided. In the formula, A 1 represents a substituted or unsubstituted phenyl group, B 1 represents any of an alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted phenyl group, α represents any of a substituted or unsubstituted phenylene group or a substituted or unsubstituted biphenyl-4,4′-diyl group, and R 1 to R 9 individually represent any of hydrogen, an alkyl group having 1 to 4 carbon atoms, or a substituted or unsubstituted phenyl group.

  新型蒽衍生物，能够发出高色纯度蓝光的新材料，以及使用任何新材料的发光元件、发光装置和电子装置。提供了通式（1）所代表的蒽衍生物。利用这种蒽衍生物可以提供具有高发射效率的发光元件。利用这种蒽衍生物可以提供发出高色纯度蓝光的发光元件。在该通式中，A1代表取代或未取代的苯基，B1代表具有1至4个碳原子的烷基或取代或未取代的苯基之一，α代表取代或未取代的苯基或取代或未取代的联苯基-4,4'-二基基团之一，R1至R9分别代表氢、具有1至4个碳原子的烷基，或取代或未取代的苯基之一。
• [EN] ANTHRACENE DERIVATIVE, AND LIGHT-EMITTING MATERIAL, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING THE SAME<br/>[FR] DÉRIVÉ D'ANTHRACÈNE ET MATÉRIAU ÉLECTROLUMINESCENT, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT ET DISPOSITIF ÉLECTRONIQUE UTILISANT CEUX-CI
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2009081800A1

  公开（公告）日：2009-07-02

  Novel anthracene derivatives, novel materials capable of blue light emission with high color purity, and a light-emitting element, a light-emitting device, and an electronic device using any of the novel materials. The anthracene derivative represented by general formula (1) is provided. With the anthracene derivative, a light-emitting element with high emission efficiency can be provided. With the anthracene derivative, a light-emitting element emitting blue light with high color purity can be provided. In the formula, A1 represents a substituted or unsubstituted phenyl group, B1 represents any of an alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted phenyl group, represents any of a substituted or unsubstituted phenylene group or a substituted or unsubstituted biphenyl-4,4'-diyl group, and R1 to R9 individually represent any of hydrogen, an alkyl group having 1 to 4 carbon atoms, or a substituted or unsubstituted phenyl group.

  提供了新型蒽衍生物，新型材料能够发出高纯度蓝光，并使用这些新型材料制造了发光元件、发光装置和电子设备。提供了通式（1）所表示的蒽衍生物。使用该蒽衍生物，可以提供高发射效率的发光元件。使用该蒽衍生物，可以提供发出高纯度蓝光的发光元件。在该通式中，A1表示取代或未取代的苯基，B1表示具有1至4个碳原子的烷基或取代或未取代的苯基之一，表示取代或未取代的苯基亚甲基或取代或未取代的联苯-4,4'-二基基团之一，R1至R9分别表示氢、具有1至4个碳原子的烷基或取代或未取代的苯基之一。
• Carbazole derivative, light-emitting element material obtained by using carbazole derivative, light-emitting element, and electronic device
  申请人：Nakashima Harue

  公开号：US20070031701A1

  公开（公告）日：2007-02-08

  It is an object to provide a carbazole derivative which is useful as a raw material for forming a light-emitting element material which has resistance to repeated oxidation reactions. It is an object to provide a carbazole derivative represented by a general formula (G-1). In the general formula (G-1), each of Ar 1 and Ar 2 represents an aryl group having 1 to 12 carbon atoms such as phenyl, biphenyl, or naphthyl. Also, R 1 represents any one of hydrogen, an alkyl group having 1 to 4 carbon atoms such as methyl, ethyl, or tert-butyl, and an aryl group having 6 to 12 carbon atoms such as phenyl, biphenyl, or naphthyl. Further, the aryl group may have a substituent, or is not required to have a substituent.

  本发明旨在提供一种卡巴唑衍生物，其可用作形成耐受重复氧化反应的发光元素材料的原材料。本发明旨在提供一种由通式（G-1）表示的卡巴唑衍生物。在通式（G-1）中，Ar1和Ar2各自表示具有1至12个碳原子的芳基基团，例如苯基、联苯基或萘基。此外，R1表示氢、具有1至4个碳原子的烷基基团，例如甲基、乙基或叔丁基，以及具有6至12个碳原子的芳基基团，例如苯基、联苯基或萘基。此外，芳基基团可以具有取代基，也可以不需要取代基。
• Composition, Method for Manufacturing Thin Film, and Method for Manufacturing Light-Emitting Element
  申请人：Shitagaki Satoko

  公开号：US20090317539A1

  公开（公告）日：2009-12-24

  It is an object to provide a composition in which an anthracene derivative is dissolved and a technique in which a thin film that has a favorable film quality is formed by a wet process using the composition. In addition, it is another object to manufacture a highly reliable light-emitting element using the composition at low cost with high productivity. A composition having a solvent and an anthracene derivative having one anthracene structure and one carbazolyl group which is bonded to the anthracene structure directly or through a phenyl group is formed. A thin film with a favorable film quality can be formed by a wet process using the composition. Accordingly, a highly reliable light-emitting element can be manufactured using such a thin film.

  本发明的目的是提供一种含有蒽衍生物溶解的组合物和一种利用该组合物通过湿法工艺形成具有良好薄膜质量的薄膜的技术。此外，另一个目的是使用该组合物以低成本和高生产率制造高可靠性的发光元件。所述组合物包含溶剂和具有一个蒽结构和一个咔唑基固定于蒽结构上，直接或通过苯基结构连接的蒽衍生物。使用该组合物可以通过湿法工艺形成具有良好薄膜质量的薄膜。因此，可以使用这样的薄膜制造高可靠性的发光元件。
• Anthracene Derivative, Light Emitting Element Using the Same, and Light Emitting Device Using the Same
  申请人：Nakashima Harue

  公开号：US20070267969A1

  公开（公告）日：2007-11-22

  It is an object of the present invention to provide a light emitting element, which is resistant to repetition of an oxidation reaction. It is another object of the invention to provide a light emitting element, which is resistant to repetition of a reduction reaction. An anthracene derivative is represented by a general formula (1). In the general formula (1), R1 represents hydrogen or an alkyl group having 1 to 4 carbon atoms, R2 represents any one of hydrogen, an alkyl group having 1 to 4 carbon atoms and an aryl group having 6 to 12 carbon atoms, R3 represents any one of hydrogen, an alkyl group having 1 to 4 carbon atoms, and an aryl group having 6 to 12 carbon atoms, Ph1 represents a phenyl group, and X1 represents an arylene group having 6 to 15 carbon atoms.

  本发明旨在提供一种耐受氧化反应重复的发光元件。另一个目标是提供一种耐受还原反应重复的发光元件。蒽衍生物由通式（1）表示。在通式（1）中，R1代表氢或具有1至4个碳原子的烷基；R2代表氢、具有1至4个碳原子的烷基或具有6至12个碳原子的芳基；R3代表氢、具有1至4个碳原子的烷基或具有6至12个碳原子的芳基；Ph1代表苯基；X1代表具有6至15个碳原子的芳烃基。