10-[4-(4,6-Diphenylpyrimidin-2-yl)phenyl]-14,14-dimethyl-21-phenyl-10,21-diazapentacyclo[11.8.0.03,11.04,9.015,20]henicosa-1(13),2,4,6,8,11,15,17,19-nonaene | 1357066-14-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 10-[4-(4,6-Diphenylpyrimidin-2-yl)phenyl]-14,14-dimethyl-21-phenyl-10,21-diazapentacyclo[11.8.0.03,11.04,9.015,20]henicosa-1(13),2,4,6,8,11,15,17,19-nonaene
• 英文别名: 10-[4-(4,6-diphenylpyrimidin-2-yl)phenyl]-14,14-dimethyl-21-phenyl-10,21-diazapentacyclo[11.8.0.03,11.04,9.015,20]henicosa-1(13),2,4,6,8,11,15,17,19-nonaene
• CAS: 1357066-14-8
• 化学式: C₄₉H₃₆N₄
• 分子量: 680.852
• InChiKey: VDPJUFNLMLSUEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.4
• 重原子数：
  53
• 可旋转键数：
  5
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  34
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-苯基邻氨基苯甲酸 在 四(三苯基膦)钯 、 palladium diacetate N-溴代丁二酰亚胺(NBS) 、 正丁基锂 、 18-冠醚-6 、 三叔丁基膦 、 di-tert-butyl(methyl)phosphonium tetrafluoroborate salt 、 磷酸 、 铜 、 potassium carbonate 、 caesium carbonate 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 乙醇 、 异丁酰胺 、 N,N-二甲基甲酰胺 、 邻二氯苯 、 甲苯 为溶剂， 反应 115.34h， 生成 10-[4-(4,6-Diphenylpyrimidin-2-yl)phenyl]-14,14-dimethyl-21-phenyl-10,21-diazapentacyclo[11.8.0.03,11.04,9.015,20]henicosa-1(13),2,4,6,8,11,15,17,19-nonaene
  参考文献：
  名称：

  [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  [FR] NOUVEAUX COMPOSÉS ÉLECTROLUMINESCENTS ORGANIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LES UTILISANT

  摘要：

  提供了一种具有一般式I的融合五环结构的有机电致发光化合物，以及使用该化合物的有机电致发光器件。由于这些有机电致发光化合物表现出良好的发光效率和寿命，它们可以用于制造具有优越运行寿命并且由于化合物的提高功率效率而具有低功耗的OLED器件。

  公开号：

  WO2011093609A1

文献信息

• Organic electroluminescent device employing organic light emitting compound as light emitting material
  申请人：Rohm And Haas Electronic Materials Korea Ltd.

  公开号：EP2857395A1

  公开（公告）日：2015-04-08

  Provided is an organic electroluminescent device that exhibits an efficient host-dopant energy transfer mechanism, and thus, expresses a certain high-efficiency electroluminescent performance, based on improved electron density distribution. The organic electroluminescent device also overcomes low initial efficiency and short operation life property, and secures high-performance electroluminescent performance with high efficiency and long life property for each color.

  提供一个有机发光二极管，它表现出一个有效的主体-掺杂能量转移机制，因此，表现出一定的高效电致发光性能，基于改进的电子密度分布。这种有机发光二极管还克服了初始效率低和操作寿命短的问题，并为每种颜色确保了具有高效率和长寿命属性的高性能电致发光性能。
• Metal complex organic electroluminescent material and organic electroluminescent device
  申请人：SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.

  公开号：US11424418B2

  公开（公告）日：2022-08-23

  The present invention relates to an organic electroluminescent material, an organic electroluminescent device, and a method for preparing the organic electroluminescent device. Due to comprising an organic compound A with 3.0 eV>ET≥2.0 eV and a compound B of M(LA)x(LB)y(LC)z, the organic electroluminescent material of the present invention has the advantages of an increased luminescence lifetime and/or a reduced operating voltage on the basis of maintaining other electronic properties at a certain level.

  本发明涉及一种有机电致发光材料、一种有机电致发光器件和一种制备有机电致发光器件的方法。由于包含 3.0 eV>ET≥2.0 eV 的有机化合物 A 和 M(LA)x(LB)y(LC)z 的化合物 B，本发明的有机电致发光材料具有在保持其他电子特性在一定水平的基础上提高发光寿命和/或降低工作电压的优点。
• ELECTROLUMINESCENT DEVICE USING ELECTROLUMINESCENT COMPOUND AS LUMINESCENT MATERIAL
  申请人：Kim Chi-Sik

  公开号：US20140054564A1

  公开（公告）日：2014-02-27

  Provided is an organic electroluminescent device that exhibits an efficient host-dopant energy transfer mechanism, and thus, expresses a certain high-efficiency electroluminescent performance, based on improved electron density distribution. The organic electroluminescent device also overcomes low initial efficiency and short operation life property, and secures high-performance electroluminescent performance with high efficiency and long life property for each color.
• ORGANIC ELECTROLUMINESCENT MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.

  公开号：US20200381633A1

  公开（公告）日：2020-12-03

  The present invention relates to an organic electroluminescent material, an organic electroluminescent device, and a method for preparing the organic electroluminescent device. Due to comprising an organic compound A with 3.0 eV>ET≥2.0 eV and a compound B of M(LA)x(LB)y(LC)z, the organic electroluminescent material of the present invention has the advantages of an increased luminescence lifetime and/or a reduced operating voltage on the basis of maintaining other electronic properties at a certain level.
• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ÉLECTROLUMINESCENTS ORGANIQUES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LES UTILISANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2011093609A1

  公开（公告）日：2011-08-04

  Provided are organic electroluminescent compounds of a fused pentacyclic structure of general formula I, and an organic electroluminescent device using said compounds. Since the organic electroluminescent compounds exhibit good luminous efficiency and lifespan, they may be used to manufacture OLED devices which have a superior operational lifetime and also have low power consumption due to the improved power efficiency of the compounds.

  提供了一种具有一般式I的融合五环结构的有机电致发光化合物，以及使用该化合物的有机电致发光器件。由于这些有机电致发光化合物表现出良好的发光效率和寿命，它们可以用于制造具有优越运行寿命并且由于化合物的提高功率效率而具有低功耗的OLED器件。