4-(tert-butyl)-1-(3-triphenylstannylpropyl)-1,3-cyclopentadiene | 799278-90-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 4-(tert-butyl)-1-(3-triphenylstannylpropyl)-1,3-cyclopentadiene
• CAS: 799278-90-3
• 化学式: C₃₀H₃₄Sn
• 分子量: 513.31
• InChiKey: CNRFWFXMCITYNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.98
• 重原子数：
  31
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  zirconium tetrachloride bis(tetrahydrofuran) complex 、 4-(tert-butyl)-1-(3-triphenylstannylpropyl)-1,3-cyclopentadiene 在 苯基锂 作用下， 以 四氢呋喃 、 乙醚 、 环己烷 为溶剂， 以39%的产率得到bis[η5-1-(tert-butyl)-3-(3-triphenylstannylpropyl)cyclopentadienyl]dichlorozirconium(IV)
  参考文献：
  名称：

  Synthesis of a tin-functionalized cyclopentadiene derivative

  摘要：

  A 3-tert-butyl-1-(stannylpropyl)-functionalized cyclopentadienyl ligand precursor 6 is readily available in 64% overall yield from allylic alcohol 1 by a three-step reaction sequence including Pd-catalyzed hydrostannylation with Ph3SnH. Treatment with FeCl2 and ZrCl4 (.) 2THF afforded corresponding ferrocene and zirconocene derivatives. Transmetallation of Sn-Ph with Li-Bu was observed under these reaction conditions by using BuLi as a base. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.065
• 作为产物：
  描述：

  3-(triphenylstannyl)propyl 4-methylbenzenesulfonate 、 1-叔丁基-1,3-环戊二烯 在 sodium hydride 作用下， 以 四氢呋喃 、 paraffin 为溶剂， 以92%的产率得到4-(tert-butyl)-1-(3-triphenylstannylpropyl)-1,3-cyclopentadiene
  参考文献：
  名称：

  Synthesis of a tin-functionalized cyclopentadiene derivative

  摘要：

  A 3-tert-butyl-1-(stannylpropyl)-functionalized cyclopentadienyl ligand precursor 6 is readily available in 64% overall yield from allylic alcohol 1 by a three-step reaction sequence including Pd-catalyzed hydrostannylation with Ph3SnH. Treatment with FeCl2 and ZrCl4 (.) 2THF afforded corresponding ferrocene and zirconocene derivatives. Transmetallation of Sn-Ph with Li-Bu was observed under these reaction conditions by using BuLi as a base. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.065

文献信息

• Synthesis of a tin-functionalized cyclopentadiene derivative
  作者：Jens Christoffers、Thomas Werner、Angelika Baro、Peter Fischer

  DOI：10.1016/j.jorganchem.2004.06.065

  日期：2004.11

  A 3-tert-butyl-1-(stannylpropyl)-functionalized cyclopentadienyl ligand precursor 6 is readily available in 64% overall yield from allylic alcohol 1 by a three-step reaction sequence including Pd-catalyzed hydrostannylation with Ph3SnH. Treatment with FeCl2 and ZrCl4 (.) 2THF afforded corresponding ferrocene and zirconocene derivatives. Transmetallation of Sn-Ph with Li-Bu was observed under these reaction conditions by using BuLi as a base. (C) 2004 Elsevier B.V. All rights reserved.