3a,4,5,6,7,7a-Hexahydro-4,7-methano-1H-inden-6-yl 2-methyl-2-propenoate | 46502-72-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3a,4,5,6,7,7a-Hexahydro-4,7-methano-1H-inden-6-yl 2-methyl-2-propenoate
• 英文别名: 8-tricyclo[5.2.1.02,6]dec-3-enyl 2-methylprop-2-enoate
• CAS: 46502-72-1
• 化学式: C₁₄H₁₈O₂
• 分子量: 218.29
• InChiKey: PXPQLEHKQLUZLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3a,4,5,6,7,7a-Hexahydro-4,7-methano-1H-inden-6-yl 2-methyl-2-propenoate 、 双氧水 生成 4-Oxatetracyclo[6.2.1.02,7.03,5]undecan-9-yl 2-methylprop-2-enoate
  参考文献：
  名称：

  TESHIGAHARA, SATOSHI;KANO, YOSHIAKI, TOSO KEHNKYU XOKOKU, 35,(1991) N, S. 47-56

  摘要：

  DOI：
• 作为产物：
  描述：

  甲基丙烯酸 、 二聚环戊二烯 以60%的产率得到
  参考文献：
  名称：

  ZEJNALOV B. K.; ISKENDEROVA S. A.; DZHAFAROVA A. A.; ALESKEROVA O. M., AZEHRB. KIMJA ZH., AZERB. XIM. ZH., 1979, HO 5, 74-79

  摘要：

  DOI：

文献信息

• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• TESHIGAHARA, SATOSHI;KANO, YOSHIAKI, TOSO KEHNKYU XOKOKU, 35,(1991) N, S. 47-56
  作者：TESHIGAHARA, SATOSHI、KANO, YOSHIAKI

  DOI：——

  日期：——
• PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL, AND MOLDED PRINTED MATERIAL
  申请人：HAYATA Yuuichi

  公开号：US20080075882A1

  公开（公告）日：2008-03-27

  A process for producing a molded printed material is provided that includes (A) a step of forming an image by discharging an ink composition on a support by an inkjet method, the ink composition comprising at least 60 wt % relative to the entire ink composition of at least one monofunctional radically polymerizable monomer having only one unsaturated double bond group selected from the group consisting of an acrylate group, a methacrylate group, an acrylamide group, a methacrylamide group, and an N-vinyl group and having at least one cyclic structure-containing group, (B) a step of curing the ink composition by irradiating with actinic radiation the image obtained so as to obtain a printed material having the image cured on the support, and (C) a step of molding the printed material. There is also provided a molded printed material obtained by the process for producing a molded printed material.
• WHITE INK COMPOSITION, INKJET RECORDING METHOD, AND PRINTED MATERIAL
  申请人：WATANABE Kotaro

  公开号：US20090087627A1

  公开（公告）日：2009-04-02

  A white ink composition for inkjet recording is provided that includes an acylphosphine-based photopolymerization initiator, a monomer having a heterocyclic skeleton, and a white colorant, the acylphosphine-based photopolymerization initiator having a content of 10 to 18 wt % relative to the ink composition. There are also provided an inkjet recording method that includes a step of discharging the white ink composition for inkjet recording onto a recording medium and a step of curing the white ink composition by irradiating the discharged white ink composition with actinic radiation, and a printed material formed by the inkjet recording method.
• INK COMPOSITION, INKJET RECORDING METHOD, PRINTED MATERIAL, AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：HAYATA Yuuichi

  公开号：US20090087626A1

  公开（公告）日：2009-04-02

  An ink composition is provided that includes a perfluoroalkyl group-containing polymer, a polymerizable monomer, and a radical polymerization initiator, in which at least 80 wt % of the polymerizable monomer is a monofunctional polymerizable monomer selected from the group consisting of a monofunctional acrylate, a monofunctional methacrylate, a monofunctional vinyloxy compound, a monofunctional N-vinyl compound, a monofunctional acrylamide, and a monofunctional methacrylamide. There are also provided an inkjet recording method that includes a step of discharging the ink composition onto a recording medium and a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation, a printed material obtained by the inkjet recording method, and a process for producing a molded printed material that includes a step of forming an image by discharging the ink composition onto a support by an inkjet method, a step of irradiating the image thus obtained with actinic radiation so as to cure the ink composition and obtain a printed material having the image cured on the support, and a step of molding the printed material.