3-(2,3-环氧丙氧基)-N,N-二(2,3-环氧丙基)苯胺 | 71604-74-5

• 物质功能分类: 有机原料 - 醇、酚、酚醇类化合物及衍生物 - 酚及其卤化、磺化、硝化或亚硝化衍生物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 3-(2,3-环氧丙氧基)-N,N-二(2,3-环氧丙基)苯胺
• 中文别名: 三缩水甘油基间氨基苯酚；2-[6-({2-[5'-(1,5-二羟基-2,4-二甲基己基)-2,3'-二甲基八氢-2,2'-联呋喃-5-基]-9-甲氧基-2,4,10-三甲基-1,6-二氧杂螺[4.5]癸-7-基}甲基)-3-甲基四氢-2H-吡喃-2-基]丙酸
• 英文名称: 3-(oxiran-2-ylmethoxy)-N,N-bis(oxiran-2-ylmethyl)aniline
• 英文别名: 3-(2,3-epoxypropoxy)N,N-di(2,3-epoxypropaneyl)aniline；m-(2,3-epoxypropoxy)-N,N-bis(2,3-epoxypropyl)aniline；3-(2,3-epoxypropoxy)N,N-bis(2,3-epoxypropyl)aniline；3-(2,3-epoxypropoxy)N,N-di(2,3-epoxypropyl)aniline；meta-N,N-diglycidylaminophenyl glycidyl ether；m-N,N-diglycidylaminophenylglycidylether；N,N-diglycidyl-meta-glycidyloxyaniline；[3-(glycidyloxy)phenyl]diglycidylamine；N,N-diglycidyl-3-(glycidyloxy)aniline；m-(Glycidyloxy)-N,N-diglycidylanilin；m-(glycidyloxy)N,N-diglycidylaniline；3-glycidyloxy-N,N-diglycidylaniline
• CAS: 71604-74-5
• 化学式: C₁₅H₁₉NO₄
• 分子量: 277.32
• InChiKey: VAGOJLCWTUPBKD-UHFFFAOYSA-N

物化性质

• 沸点：
  435.3±15.0 °C(Predicted)
• 密度：
  1.305±0.06 g/cm3(Predicted)
• LogP：
  1.6
• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  20
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  50.1
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3-(2,3-环氧丙氧基)-N,N-二(2,3-环氧丙基)苯胺 、 4-羟基-二苯甲酮 在 四丁基溴化铵 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 14.08h， 生成
  参考文献：
  名称：

  三官能度单组分二苯甲酮夺氢型光引发剂及制备方法

  摘要：

  本发明属于感光高分子材料领域。本发明基于羟基二苯甲酮和三缩水甘油基间氨基苯酚反应制备了三官能度单组分二苯甲酮夺氢型光引发剂。通过光引发剂分子结构中羟基与三缩水甘油基间氨基苯酚的环氧基团开环反应，使得一个三缩水甘油基间氨基苯酚结构中连接三个吸光基团，在保证其光引发活性的同时提高分子量，且三缩水甘油基间氨基苯酚结构中与N相连的碳还能在光照过程中供氢，减少胺助引发剂的使用。本发明的合成步骤简单，制备成本低，产物迁移率较低，在紫外光固化领域有广泛的应用前景。

  公开号：

  CN110452128A

文献信息

• [EN] PHOSPHORUS-CONTAINING COMPOUNDS AND POLYMERIC COMPOSITIONS COMPRISING SAME<br/>[FR] COMPOSÉS CONTENANT DU PHOSPHORE ET COMPOSITIONS POLYMÈRES LES COMPRENANT
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2010025165A1

  公开（公告）日：2010-03-04

  Phosphorus-containing compounds of formula (I): (I) wherein m, n, R, R1 and R2 are as set forth in the claims. The compounds of formula (I) can be used to provide polymers with flame retardant properties.

  式(I)中含有磷的化合物：其中m、n、R、R1和R2如权利要求书中所述。式(I)中的化合物可用于制备具有阻燃性能的聚合物。
• INSULATING COMPOSITES FOR POWER TRANSMISSION AND DISTRIBUTION
  申请人：Li Yong Jiang

  公开号：US20150162110A1

  公开（公告）日：2015-06-11

  An insulating composite for powder transmission and distribution containing a continuous reinforcing fiber embedded in a thermoset resin, wherein the thermoset resin is a reaction product of a curable epoxy resin composition comprising (a) at least one bisphenol A-type epoxy resin, (b) at least one oxazolidone ring containing epoxy resin, and (c) at least one anhydride hardener and wherein the curable epoxy resin composition has a viscosity of 6,000 millipascals·second or less at 25° C.; and a process for preparing the insulating composite.

  一种用于粉末传输和分配的绝缘复合材料，其中包含嵌入热固性树脂中的连续增强纤维，其中热固性树脂是可固化环氧树脂组合物的反应产物，该组合物包括（a）至少一种双酚A型环氧树脂，（b）至少一种含氧杂环环氧树脂和（c）至少一种酸酐硬化剂，并且可固化环氧树脂组合物在25°C下的粘度为6,000毫帕秒或以下；以及制备该绝缘复合材料的过程。
• Thermosetting epoxy resin compositions and thermosets therefrom
  申请人：HERCULES INCORPORATED

  公开号：EP0193082A1

  公开（公告）日：1986-09-03

  Described are novel thermosetting epoxy resin compositions suitable for making cured resins, prepregs and stiff, tough thermoset composites. The thermosetting compositions comprise a polyepoxide component, an amine hardener and a specified amount of certain aromatic oligomers containing functional groups which are reactive with the polyepoxide and/or hardener under curing conditions for the composition. The cured resins have a multiphase morphology which comprises at least one glassy continuous phase and at least one glassy discontinuous phase and have a fracture toughness, Kic, of at least 1.0 MPam½.

  所述的是新型热固性环氧树脂组合物，适用于制造固化树脂、预浸料和硬质坚韧的热固性复合材料。这些热固性组合物包括一种聚环氧化物成分、一种胺固化剂和一定量的某些芳香族低聚物，这些芳香族低聚物含有在组合物固化条件下与聚环氧化物和/或固化剂反应的官能团。固化后的树脂具有多相形态，包括至少一个玻璃状连续相和至少一个玻璃状不连续相，断裂韧性 Kic 至少为 1.0 MPam½。
• Damage tolerant composites containing infusible particles
  申请人：HERCULES INCORPORATED

  公开号：EP0252725A2

  公开（公告）日：1988-01-13

  Damage tolerant composites comprising high strength filaments in the form of bundles or tows of continuous fiber and a tough phase separated, crosslinked epoxy resin matrix are disclosed. The crosslinked epoxy resin matrix comprises infusible particles that reside primarily between plies of the composite and critically have a median particle size between 10 - 75 microns. Prepregs for making the damage tolerant composites and methods of making such prepregs and the epoxy resin compositions thereof are also disclosed. The epoxy resin compositions comprise the infusible particles which become segregated as to size on a surface layer of the prepreg during the process of combining the high strength filaments of the prepreg and the resin containing the epoxy resin composition. Alternatively, the infusible particles may be disposed directly on the epoxy resin surface of the prepreg.

  本发明公开了由连续纤维束或纤维束形式的高强度长丝和坚韧的相分离交联环氧树脂基体组成的耐损伤复合材料。交联环氧树脂基体包括可注入颗粒，这些颗粒主要位于复合材料的层间，中值粒径介于 10 - 75 微米之间。此外，还公开了用于制造耐损伤复合材料的预浸料、制造此类预浸料的方法及其环氧树脂组合物。环氧树脂组合物包括可渗透颗粒，在将预浸料的高强度长丝与含有环氧树脂组合物的树脂结合的过程中，这些颗粒会在预浸料的表层上按尺寸分离。或者，可注入颗粒可以直接放置在预浸料的环氧树脂表面。
• Modified conjugated diene polymer and rubber composition comprising it
  申请人：JSR Corporation

  公开号：EP1099710A1

  公开（公告）日：2001-05-16

  A conjugated diene polymer is produced by continuously polymerizing a conjugated diene monomer with a catalyst consisting essentially of specified components (a) to (c) and reacting with at least one of specified components (d) and (e) and has a content of cis-1,4-bond of not less than 85%, a content of 1,2-vinyl bond of not more than 2.0% and a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) of not more than 5, and contains at least one functional group selected from epoxy group and hydroxyl group in its molecule. And also, a rubber composition comprises 10-200 parts by weight of silica based on 100 parts by weight of rubber ingredient consisting of 10-100% by weight of the above conjugated diene polymer and 90-0% by weight of the other diene polymer or natural rubber.

  共轭二烯聚合物是由共轭二烯单体与主要由指定组分(a)至(c)组成的催化剂连续聚合，并与指定组分(d)和(e)中的至少一种反应而制得，其顺式-1,4-键的含量不低于 85%，1,2-乙烯基键的含量不超过 2.0%，重量平均分子量（Mw）与数量平均分子量（Mn）之比不大于 5，且其分子中至少含有一个选自环氧基和羟基的官能团。此外，一种橡胶组合物包含 10-200 份（重量）白炭黑，基于 100 份（重量）橡胶配料，其中包括 10-100% （重量）上述共轭二烯聚合物和 90-0% （重量）其他二烯聚合物或天然橡胶。