3-N-乙基氨基苯基(beta-乙基硫酸酯)砜 | 83574-63-4

• 物质功能分类: 有机原料 - 氨基化合物 - 磺酸类氨基化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3-N-乙基氨基苯基(beta-乙基硫酸酯)砜
• 中文别名: 3-N-乙基氨基苯基(2-磺酸氧乙基)砜；3-N-乙基氨基苯基(beta-磺酸乙基)砜；N-乙基间位酯
• 英文名称: sulfuric acid mono-[2-(3-ethylamino-benzenesulfonyl)-ethyl] ester
• 英文别名: 1-N-ethylaminobenzene-3-β-sulfatoethylsulfone；N-ethylaminophenyl-3-(β-sulfatoethylsulfone)；N-ethylaminophenyl-3-(beta-sulfatoethylsulfone)；3-ethylamino-phenyl 2'-sulphatoethyl sulphone；2-[3-(Ethylamino)phenyl]sulfonylethyl hydrogen sulfate
• CAS: 83574-63-4
• 化学式: C₁₀H₁₅NO₆S₂
• 分子量: 309.364
• InChiKey: BMCYONWPAXGKRH-UHFFFAOYSA-N

物化性质

• 密度：
  1.483±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  19
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  127
• 氢给体数：
  2
• 氢受体数：
  7

安全信息

• 危险类别码：
  R34
• 海关编码：
  2922199090
• 安全说明：
  S26,S36/37/39,S45
• 危险品标志：
  C

SDS

Name:	3-N-Ethyl-Aminophenyl(beta-Sulfatoethyl)Sulfone Material Safety Data Sheet
Synonym:	None Known
CAS:	83574-63-4

Section 1 - Chemical Product MSDS Name:3-N-Ethyl-Aminophenyl(beta-Sulfatoethyl)Sulfone Material Safety Data Sheet
Synonym:None Known

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
83574-63-4	3-N-Ethyl-Aminophenyl(beta-Sulfatoethy	ca. 100	unlisted

Hazard Symbols: C
Risk Phrases: 34

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.

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Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Use only in a well-ventilated area. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Corrosives area.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 83574-63-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H15NO6S2
Molecular Weight: 309.35

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Acid anhydrides, acids, acetic anhydride, acid chlorides, carbon dioxide, oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 83574-63-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-N-Ethyl-Aminophenyl(beta-Sulfatoethyl)Sulfone - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Pseudomonas putida:

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 83574-63-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 83574-63-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 83574-63-4 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  3-N-乙基氨基苯基(beta-乙基硫酸酯)砜 在 盐酸 、 碳酸氢钠 、 sodium carbonate 作用下， 以 水 为溶剂， 反应 3.5h， 生成
  参考文献：
  名称：

  一种活性蓝染料及其制备和应用

  摘要：

  本发明公开了一种活性蓝染料及其制备和应用，所述活性蓝染料的结构如通式(Ⅰ)所示。本发明的活性蓝染料结构新颖、性能优异，具有良好的固色率、色牢度，能有效的减少资源的消耗，染色后有很好的稳定性，色光鲜艳，能广泛应用于涤棉、麻、人造棉等棉纤维制品的浸染、轧染、喷墨印花等染色工艺，而且生产成本低，可以大规模推广应用。

  公开号：

  CN106590026B
• 作为产物：
  描述：

  间-β-羟乙基砜硫酸酯苯胺 、 乙醛 在 氢气 、 镍 作用下， 以 乙醇 为溶剂， 60.0~80.0 ℃ 、10.0 MPa 条件下， 反应 12.0h， 生成 3-N-乙基氨基苯基(beta-乙基硫酸酯)砜
  参考文献：
  名称：

  一种活性深蓝染料及其制备方法

  摘要：

  本发明公开了一种活性深蓝染料及其制备方法，其中活性深蓝染料具有式(I)所示结构，与现有技术相比，本发明的活性深蓝染料单体化合物结构新颖，性能优异，具有良好的色牢度，固色率高，染料稳定，耐洗、耐摩擦、耐日晒度好，与纤维结合稳定性好，成品具有优异的鲜艳度，适于大规模推广应用。

  公开号：

  CN106634038B

文献信息

• 艳蓝染料中间体、活性艳蓝染料及其制备方法和应用
  申请人：湖北丽源科技股份有限公司

  公开号：CN112778172B

  公开（公告）日：2023-03-17

  本申请公开了一种艳蓝染料中间体、活性艳蓝染料及其制备方法和应用，涉及活性染料领域，该活性艳蓝染料的制备方法包括以下步骤：a.乌尔曼缩合、b.酯化、c.缩合。本申请所制备的活性艳蓝染料产品溶解度高，反应性强，固色率高，适用于浸染、轧染、冷堆染色，且可减少环境污染。
• 一种活性深红染料及其制备和应用
  申请人：泰兴锦云染料有限公司

  公开号：CN106833013A

  公开（公告）日：2017-06-13

  本发明公开了一种活性深红染料及其制备和应用，其中活性深红染料具有式(I)所示结构，本发明的活性深蓝染料结构新颖、性能优异，具有良好的固色率、色牢度，能有效的减少资源的消耗，染色后有很好的稳定性，色光鲜艳，能广泛应用于涤棉、麻、人造棉等棉纤维制品的浸染、轧染、喷墨印花等染色工艺，而且生产成本低，可以大规模推广应用。
• Reactive dyestuffs with alkylthio group and beta-sulfatoethysulfone group
  申请人：Chen Wen-Jang

  公开号：US20090018317A1

  公开（公告）日：2009-01-15

  The present invention provides a reactive dyestuff with an alkylthio group and a β-sulfatoethylsulfone group, which is represented by formula (I), wherein D, R, R 1 , R 2 , R 3 , R 4 , Q, x, and y are defined the same as the specification. The reactive dyestuffs of the present invention not only have characteristics of high solubility, high alkali solubility, and easily being washed off for dyeing cellulose fiber, but also are suitably applied in cold-pad-batch dyeing, continuous-dyeing, printing, and digital printing.

  本发明提供了一种具有烷基硫基和β-磺酸乙基磺酰基的反应染料，其由公式（I）表示，其中D，R，R1，R2，R3，R4，Q，x和y的定义与说明书相同。本发明的反应染料不仅具有高溶解度，高碱溶解度，易于洗掉以染色纤维素纤维的特性，而且适用于冷垫批染色、连续染色、印刷和数字印刷。
• Reactive dyestuffs with alkylthio group and beta-sulfatoethylsulfone group
  申请人：Everlight USA, Inc.

  公开号：EP2009065A1

  公开（公告）日：2008-12-31

  The present invention provides a reactive dyestuff with an alkylthio group and a β-sulfatoethylsulfone group, which is represented by formula (I), wherein D, R, R1, R2, R3, R4, Q, x, and y are defined the same as the specification. The reactive dyestuffs of the present invention not only have characteristics of high solubility, high alkali solubility, and easily being washed off for dyeing cellulose fiber, but also are suitably applied in cold-pad-batch dyeing, continuous-dyeing, printing, and digital printing.

  本发明提供一种具有烷基硫基和β-磺酸乙基磺酰基的反应性染料，其由式(I)表示，其中D、R、R1、R2、R3、R4、Q、x和y的定义与规范相同。本发明的反应染料不仅具有高溶解度、高碱溶解度和易于洗去的特性，用于染色纤维素纤维，而且适用于冷垫批染、连续染色、印花和数字印花。
• 一种红色活性染料混合物及其应用
  申请人：湖北丽源科技股份有限公司

  公开号：CN108148446A

  公开（公告）日：2018-06-12

  本发明公开了一种红色活性染料混合物及其应用，所述的染料混合物包括质量比为50‑60：5‑15：15‑25:10‑20的染料一：染料二：染料三和染料四，所述染料一为通式Ⅰ所示化合物和/或其盐；染料二为通式Ⅱ所示化合物和/或其盐；染料三为通式Ⅲ所示化合物和/或其盐；染料四为通式Ⅳ所示化合物和/或其盐。本发明的染料混合物的各组份相互之间具有协同增效的作用，其很多应用性能明显高于任意一支单色品种或其他配比的混合物，且具有耐日晒、耐汗渍、耐摩擦、耐水洗的优良性能。通式Ⅰ：通式Ⅱ：通式Ⅲ：通式Ⅳ：