3-[(2-全氟己基)乙氧基]-1,2-环氧丙烷 | 122193-68-4

• 物质功能分类: 有机原料 - 有机氟化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 3-[(2-全氟己基)乙氧基]-1,2-环氧丙烷
• 中文别名: 3-(3,3,4,4,5,5,6,6,7,7,8,8,8-十三氟辛氧基)-1,2-环氧丙烷；3-[2-(五氟己烷基)乙氧基]-1,2-环乙氧基丙烷；3-(2-全氟己基乙氧基)-1,2-环氧丙烷；3-(3,3,4,4,5,5,6,6,7,7,8,8,8-三十氟辛氧基)-1,2-环氧丙烷
• 英文名称: 3-[2-(tridecafluorohexyl)ethoxy]-1,2-epoxypropane
• 英文别名: perfluorohexylethyl glycidyl ether；2-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctoxymethyl)oxirane
• CAS: 122193-68-4
• 化学式: C₁₁H₉F₁₃O₂
• 分子量: 420.17
• InChiKey: DRSDQADBHIDJCU-UHFFFAOYSA-N

物化性质

• 沸点：
  218.8±40.0 °C(Predicted)
• 密度：
  1.57

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  26
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  15

安全信息

• 海关编码：
  2910900090

SDS

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Section I.Chemical Product and Company Identification
Chemical Name 3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane
Portland OR
Synonym
Oxirane, [[(3,3,4,4,5,5,6,6,7,7,8,8,8-
tridecafluorooctyl)oxy]methyl]- (9 CI)
Chemical Formula
C 11 H 9 F 13 O 2
CAS Number
122193-68-4
(International)

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Section II. Composition and Information on Ingredients
Chemical Name CAS Number Percent (%) TLV/PEL Toxicology Data
3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane 122193-68-4 Min. 96.0 (GC) Not available. Not available.

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Section III. Hazards Identification
Acute Health Effects
N o specific inform ation is available in our data base regarding the toxic effects of this m aterial for hum ans. H ow ever,
exposure to any chem ical should be kept to a m inim u m . Skin and eye contact m ay result in irritation. M ay be harm ful if
inhaled or ingested. A lw ays follow safe industrial hygiene practices and w ear proper protective equipm ent w hen
handling this compound.
Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
Chronic Health Effects
CARCINOGENIC EFFECTS : Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY : Not available.
Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.

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Section IV. First Aid Measures
Eye Contact
C heck for and rem ove any contact lenses. In case of contact, im m ediately flush eyes w ith plenty of w ater for at least 15
minutes. Get medical attention.
Skin Contact
In case of contact, im m ediately flush skin w ith plenty of w ater. Rem ove contam inated clothing and shoes. W ash
clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation
If the victim is not breathing, perform m outh-to-m outh resuscitation. Loosen tight clothing such as a collar, tie, belt or
w aistband. If breathing is difficult, oxygen can be adm inistered. Seek m edical attention if respiration problem s do not
improve.
Ingestion
IN D U C E V O M ITIN G by sticking finger in throat. Low er the head so that the vom it w ill not reenter the m outh and throat.
Loosen tight clothing such as a collar, tie, belt or w aistband. If the victim is not breathing, perform m outh-to-m outh
resuscitation. Exam ine the lips and m outh to ascertain w hether the tissues are dam aged, a possible in dication that the
toxic material was ingested; the absence of such signs, however, is not conclusive.

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Section V. Fire and Explosion Data
Flammability Auto-Ignition Not available.
May be combustible at high temperature.
Flash Points Flammable Limits
Not available. Not available.
Combustion Products
These products are toxic carbon oxides (CO, CO 2), halogenated compounds.
WARNING: Highly toxic HF gas is produced during combustion.
Fire Hazards
Not available.
Explosion Hazards
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media
Combustible liquid.
and Instructions SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
Consult with local fire authorities before attempting large scale fire-fighting operations.
Continued on Next Page
3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane

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Section VI. Accidental Release Measures
Spill Cleanup
Combustible material.
Instructions K eep aw ay from heat. M echanical exhaust required. Stop leak if w ithout risk. Finish cleaning the spill by rinsing any
contam inated surfaces w ith copious am ounts of w ater. C onsult federal, state, and/or local authorities for assistance on
disposal.

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Section VII. Handling and Storage
Handling and Storage
C O M BU STIBLE. K eep aw ay from heat. M echanical exhaust required. A void excessive heat and light. D o not breathe
gas/fumes/ vapor/spray.
Information
Always store away from incompatible compounds such as oxidizing agents.

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Section VIII. Exposure Controls/Personal Protection
Engineering Controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location.
Personal Protection
Splash goggles. Lab coat. V apor respirator. Boots. G loves. Suggested protective clothing m ight not be sufficient;
consult a specialist BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent.
Exposure Limits
Not available.

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Section IX. Physical and Chemical Properties
Solubility
Physical state @ 20°C
Liquid. (Clear, colorless.) Not available.
Specific Gravity 1.57 (water=1)
Molecular Weight Partition Coefficient
420.17 Not available.
Boiling Point
Vapor Pressure
Not available. Not available.
Melting Point Vapor Density
Not available. Not available.
Refractive Index Volatility
1.338 - 1.341 Not available.
Critical Temperature Odor
Not available. Not available.
Viscosity Taste
Not available. Not available.

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Section X. Stability and Reactivity Data
Stability

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This material is stable if stored under proper conditions. (See Section VII for instructions)
Conditions of Instability
Avoid excessive heat and light.
Incompatibilities
Reactive with oxidizing agents.

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Section XI. Toxicological Information
RTECS Number
Not available.
Routes of Exposure Eye Contact. Ingestion. Inhalation.
Toxicity Data
Not available.
Chronic Toxic Effects CARCINOGENIC EFFECTS : Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY : Not available.
Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.
Acute Toxic Effects
N o specific inform ation is available in our data base regarding the toxic effects of this m aterial for hum ans. H ow ever,
exposure to any chem ical should be kept to a m inim u m . Skin and eye contact m ay result in irritation. M ay be harm ful if
inhaled or ingested. A lw ays follow safe industrial hygiene practices and w ear proper protective equipm ent w hen
handling this compound.
Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
Continued on Next Page
3-[2-(Perfluorohexyl)ethoxy]-1,2-epoxypropane

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Section XII. Ecological Information
Ecotoxicity
Not available.
Environmental Fate
Not available.

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Section XIII. Disposal Considerations
Waste Disposal Recycle to process, if possible. C onsult your local regional authorities. You m ay be able to dissolve or m ix m aterial w ith
a com bustible solvent and burn in a chem ical incinerator equipped w ith an afterburner and scrubber system . O bserve all
federal, state and local regulations when disposing of the substance.

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Section XIV. Transport Information
DOT Classification
Not a DOT controlled material (United States).
PIN Number
Not applicable.
Proper Shipping Name
Not applicable.
Packing Group (PG)
Not applicable.
DOT Pictograms

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Section XV. Other Regulatory Information and Pictograms
TSCA Chemical Inventory
T h is p r o d u c t is NOT o n t h e E P A T o x ic S u b s t a n c e s C o n t r o l A c t (T S C A ) in v e n t o r y . T h e f o llo w in g n o t ic e s a r e r e q u ir e d b y 4 0
(EPA) CFR 720.36 (C) for those products not on the inventory list:
(i) These products are supplied solely for use in research and developm ent by or under the supervision of a technically
qualified individual as defined in 40 CFR 720.0 et sec.
(ii) The health risks of these products have not been fully determ ined. A ny inform ation that is or becom es available w ill
be supplied on an MSDS sheet.
WHMIS Classification
CLASS B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F).
(Canada)
EINECS Number (EEC)
Not available.
EEC Risk Statements
Not available.
Japanese Regulatory Data
Not available.

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Section XVI.
Version 1.0
Validated on 1/2/2007.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  3-[(2-全氟己基)乙氧基]-1,2-环氧丙烷 以 异丙醇 为溶剂， 反应 13.0h， 生成
  参考文献：
  名称：

  一种环保型氟碳表面活性剂及其制备方法和 应用

  摘要：

  本发明涉及含氟新材料制备技术领域,特别涉及一种环保型氟碳表面活性剂，氟烷基醇与环氧氯丙烷反应得到含氟烷基缩水甘油醚；含氟烷基缩水甘油醚与含氨基类化合物进行反应得到的。合成不含PFOS/PFOA的绿色环保氟表面活性剂，保持氟表面活性剂的优异性能；生产过程基本无“三废”产生，符合国家环保政策；可替代同类进口产品，大大降低制造成本。

  公开号：

  CN107903180B
• 作为产物：
  描述：

  sodium perfluorohexylethanolate 、 环氧氯丙烷 反应 10.0h， 生成 3-[(2-全氟己基)乙氧基]-1,2-环氧丙烷
  参考文献：
  名称：

  一种环保型氟碳表面活性剂及其制备方法和 应用

  摘要：

  本发明涉及含氟新材料制备技术领域,特别涉及一种环保型氟碳表面活性剂，氟烷基醇与环氧氯丙烷反应得到含氟烷基缩水甘油醚；含氟烷基缩水甘油醚与含氨基类化合物进行反应得到的。合成不含PFOS/PFOA的绿色环保氟表面活性剂，保持氟表面活性剂的优异性能；生产过程基本无“三废”产生，符合国家环保政策；可替代同类进口产品，大大降低制造成本。

  公开号：

  CN107903180B

文献信息

• A simple and efficient intramolecular 1,3-dipolar azidoalkyne cycloaddition: Synthesis of 6-perfluoroalkylated fused exo -bicyclic 1,2,3-triazolo-1,4-oxazines
  作者：Nejib Hussein Mekni

  DOI：10.1016/j.jfluchem.2016.04.010

  日期：2016.6

  The synthesis of new 6-perfluoroalkylated 1,2,3-triazolo-1,4-oxazine ethers and thioethers as fused exo-heterobicyclic compounds was achieved from terminal perfluoroalkyl oxiranes by azide ion ring opening and propargylation reactions followed by a quick and spontaneous 1,3-dipolar intramolecular cycloaddition reaction.

  新的6-全氟烷基化的1,2,3-三唑-1,4-恶嗪醚和硫醚是稠合的外-杂环双环化合物，是通过叠氮离子开环和炔丙基化反应从末端的全氟烷基氧杂环戊烷中合成的，然后快速且自发地合成1 ，3-偶极分子内环加成反应。
• 一种全氟取代小分子端基二醇及其制备方法 和应用
  申请人：南京信息工程大学

  公开号：CN110028412B

  公开（公告）日：2021-11-30

  本发明公开了一种全氟取代小分子端基二醇，具有如结构式Ⅰ所示的分子结构：其中，结构式I为无色或略带淡黄色的透明液体；n为2～11中的任一自然数；m为1或2；R为甲基、乙基、丙基、丁基异丙基或异丁基的任一种。本发明制备的全氟取代小分子端基二醇纯度高，几乎没有副反应，制备方法简单，产物转化率高，可用于合成性能均一、可长时间存储的单组分常温自交联侧链含氟聚氨酯，由侧链含氟聚氨酯制备的超疏水疏油自清洁涂层具有与基材附着力强、表面耐磨、耐溶剂浸泡、耐化学腐蚀和耐候性能好等优点。
• Organic insulator composition, organic insulating layer including the composition, and organic thin film transistor including the same
  申请人：Lee Eun Kyung

  公开号：US20090206330A1

  公开（公告）日：2009-08-20

  An organic insulator composition according to example embodiments may include an organic insulating polymer and an epoxy-based crosslinking agent. The epoxy-based crosslinking agent may have an alkyl group or a fluorine-based side chain. The organic insulator composition may be used to form an organic insulating layer having increased chemical resistance. The organic insulating layer may be used in an organic thin film transistor as a gate insulating layer. Consequently, the occurrence of hysteresis may be reduced or prevented during the operation of the organic thin film transistor, thus resulting in relatively homogeneous properties.

  根据实施例，一种有机绝缘体组合物可能包括有机绝缘聚合物和基于环氧的交联剂。基于环氧的交联剂可能具有烷基或氟基侧链。有机绝缘体组合物可用于形成具有增加化学抗性的有机绝缘层。有机绝缘层可用作有机薄膜晶体管的栅绝缘层。因此，在有机薄膜晶体管的操作过程中，可以减少或防止滞后的发生，从而导致相对均匀的特性。
• Substantially non-swellable contact lens containing polyoxyalkylene backbone units
  申请人：CIBA-GEIGY AG

  公开号：EP0263061A2

  公开（公告）日：1988-04-06

  Contact lenses which are optically clear, wettable, flexible. of high oxygen permeability and substantially non-swellable in the aqueous ocular environment of use, of a polymer containing polyoxyalkylene backbone units are disclosed, as well as the preparation thereof and methods of treating vision defects therewith.

  本发明公开了由含有聚氧亚烷基骨架单元的聚合物制成的光学上透明、可湿润、柔韧、高透氧性且在使用的水性眼环境中基本不溶胀的隐形眼镜，以及其制备方法和用其治疗视力缺陷的方法。
• Wettable, rigid gas permeable, substantially non-swellable contact lens
  申请人：CIBA-GEIGY AG

  公开号：EP0330618A2

  公开（公告）日：1989-08-30

  This invention relates to ophthalmic devices, such as contact lenses and intraocular implants, and particularly contact lenses of a block copolymer containing polysiloxane and polyoxyalkylene oxide units possessing an advantageous blend of desirable properties including a) high oxygen permeability, b) good wettability, c) optical clarity and d) a substantially lack of aqueous swellability in the ocular environment of use. Even the preparation thereof and methods of treating vision defects therewith are disclosed as well as the polymers suitable for these ophthalmic devices.

  本发明涉及眼科设备，如隐形眼镜和眼内植入物，特别是含有聚硅氧烷和聚氧亚烷基环氧单元的嵌段共聚物的隐形眼镜，这种嵌段共聚物具有多种理想性能，包括 a) 高透氧性；b) 良好的润湿性；c) 光学清晰度；d) 在使用的眼部环境中基本无水膨胀性。此外，还公开了其制备方法和治疗视力缺陷的方法，以及适用于这些眼科设备的聚合物。

表征谱图