2,6-bis[(boronatediphenylphosphanyl)methyl]phenol | 1224868-03-4

• 英文名称: 2,6-bis[(boronatediphenylphosphanyl)methyl]phenol
• CAS: 1224868-03-4
• 化学式: C₃₂H₃₄B₂OP₂
• 分子量: 518.191
• InChiKey: ZUZIYQHXECZKEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2,6-bis[(boronatediphenylphosphanyl)methyl]phenol 在 三乙烯二胺 作用下， 以 二氯甲烷 为溶剂， 以78%的产率得到2,6-bis[(diphenylphosphanyl)methyl]phenol
  参考文献：
  名称：

  Synthesis of Oxygen- and Sulfur-Bridged Dirhodium Complexes and Their Use As Catalysts in the Chemoselective Hydrogenation of Alkenes

  摘要：

  Oxygen-bridged and sulfur-bridged rhodium homobimetallic complexes were synthesized as airstable crystals by using 2,6-bis(phosphanylmethyl)phenolate and -thiophenolate as the ligands, respectively. The oxygen-bridged dirhodium complex has a symmetrical structure where the carbon atom at the ipso position, oxygen, and two rhodium atoms are located in the same plane. It is thermally stable compared to the sulfur-bridged dirhodium complex and shows catalytic activity for hydrogenation of alkenes with high chemoselectivity.

  DOI：

  10.1021/om100067r
• 作为产物：
  描述：

  O-(t-butyldimethylsilyl)-2,6-bis(bromomethyl)phenol 、 diphenylphosphineborane 在 四丁基溴化铵 、 potassium hydroxide 作用下， 以 水 、 甲苯 为溶剂， 反应 7.0h， 生成 2,6-bis[(boronatediphenylphosphanyl)methyl]phenol
  参考文献：
  名称：

  Synthesis of Oxygen- and Sulfur-Bridged Dirhodium Complexes and Their Use As Catalysts in the Chemoselective Hydrogenation of Alkenes

  摘要：

  Oxygen-bridged and sulfur-bridged rhodium homobimetallic complexes were synthesized as airstable crystals by using 2,6-bis(phosphanylmethyl)phenolate and -thiophenolate as the ligands, respectively. The oxygen-bridged dirhodium complex has a symmetrical structure where the carbon atom at the ipso position, oxygen, and two rhodium atoms are located in the same plane. It is thermally stable compared to the sulfur-bridged dirhodium complex and shows catalytic activity for hydrogenation of alkenes with high chemoselectivity.

  DOI：

  10.1021/om100067r