2,2,2-Trichloro-acetimidic acid (2Z,6Z,10Z,14Z,18Z,22Z,26Z,30Z,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl ester | 875782-35-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2,2,2-Trichloro-acetimidic acid (2Z,6Z,10Z,14Z,18Z,22Z,26Z,30Z,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl ester
• CAS: 875782-35-7
• 化学式: C₅₂H₈₂Cl₃NO
• 分子量: 843.588
• InChiKey: MUWXCXZKCYVDMA-ONMWMHGASA-N

物化性质

• 沸点：
  780.9±70.0 °C(Predicted)
• 密度：
  0.94±0.1 g/cm3(Predicted)

反应信息

• 作为反应物：
  描述：

  2,2,2-Trichloro-acetimidic acid (2Z,6Z,10Z,14Z,18Z,22Z,26Z,30Z,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl ester 在 ammonium hydroxide 、 氟化铵 作用下， 以 甲醇 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 6.0h， 生成 decaprenylphosphoryl β-D-arabinofuranose
  参考文献：
  名称：

  Stereoselective synthesis of decaprenylphosphoryl β-d-arabinofuranose

  摘要：

  Decaprenylphosphoryl beta-D-arabinofuranose (DPA) is known to be a key arabinose donor in mycobacteria. In order to study the biosynthesis of the major polysaccharides from the mycobacterial cell wall, it was necessary to develop a practical and stereoselective synthetic scheme for DPA. This goal was achieved by Coupling of a suitably protected beta-D-arabinofuranosyl phosphate intermediate with an activated form of decaprenol and subsequent deprotection. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.11.068
• 作为产物：
  描述：

  三氯乙腈 、 decaprenol 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 二氯甲烷 为溶剂， 反应 0.33h， 生成 2,2,2-Trichloro-acetimidic acid (2Z,6Z,10Z,14Z,18Z,22Z,26Z,30Z,34E)-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl ester
  参考文献：
  名称：

  Stereoselective synthesis of decaprenylphosphoryl β-d-arabinofuranose

  摘要：

  Decaprenylphosphoryl beta-D-arabinofuranose (DPA) is known to be a key arabinose donor in mycobacteria. In order to study the biosynthesis of the major polysaccharides from the mycobacterial cell wall, it was necessary to develop a practical and stereoselective synthetic scheme for DPA. This goal was achieved by Coupling of a suitably protected beta-D-arabinofuranosyl phosphate intermediate with an activated form of decaprenol and subsequent deprotection. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.11.068